Articles | Volume 11, issue 5
https://doi.org/10.5194/amt-11-2749-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-2749-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Characterization of a catalyst-based conversion technique to measure total particulate nitrogen and organic carbon and comparison to a particle mass measurement instrument
Chelsea E. Stockwell
CORRESPONDING AUTHOR
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Agnieszka Kupc
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Bartłomiej Witkowski
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Faculty of Chemistry, University of Warsaw, al. Żwirki i Wigury 101, 02-089, Warsaw, Poland
Ranajit K. Talukdar
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Yong Liu
Department of Chemistry, University of Colorado Denver, Denver, CO 80217, USA
Vanessa Selimovic
Department of Chemistry, University of Montana, Missoula, MT 59812, USA
Kyle J. Zarzana
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Kanako Sekimoto
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Carsten Warneke
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Rebecca A. Washenfelder
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Robert J. Yokelson
Department of Chemistry, University of Montana, Missoula, MT 59812, USA
Ann M. Middlebrook
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
James M. Roberts
CORRESPONDING AUTHOR
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Data sets
Fire Lab Study National Oceanic and Atmospheric Administration https://esrl.noaa.gov/csd/groups/csd7/measurements/2016firex/FireLab/DataDownload/index.php?page=/csd/groups/csd7/measurements/2016firex/FireLab/DataDownload/
Short summary
This work investigates the total conversion of particle-bound nitrogen and organic carbon across platinum and molybdenum catalysts followed by NO–O3 chemiluminescence and nondispersive infrared CO2 detection. We show the instrument is an accurate particle mass measurement method and demonstrate its ability to calibrate particle mass measurement instrumentation through comparisons with a calibrated particle-into-liquid sampler coupled to an electrospray ionization source of a mass spectrometer.
This work investigates the total conversion of particle-bound nitrogen and organic carbon across...