Articles | Volume 11, issue 5
https://doi.org/10.5194/amt-11-2749-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-2749-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 May 2018
Research article |
| 14 May 2018
| 14 May 2018
Characterization of a catalyst-based conversion technique to measure total particulate nitrogen and organic carbon and comparison to a particle mass measurement instrument
Chelsea E. Stockwell
CORRESPONDING AUTHOR
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Agnieszka Kupc
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Bartłomiej Witkowski
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Faculty of Chemistry, University of Warsaw, al. Żwirki i Wigury 101, 02-089, Warsaw, Poland
Ranajit K. Talukdar
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Yong Liu
Department of Chemistry, University of Colorado Denver, Denver, CO 80217, USA
Vanessa Selimovic
Department of Chemistry, University of Montana, Missoula, MT 59812, USA
Kyle J. Zarzana
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Kanako Sekimoto
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Carsten Warneke
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Rebecca A. Washenfelder
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Robert J. Yokelson
Department of Chemistry, University of Montana, Missoula, MT 59812, USA
Ann M. Middlebrook
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
James M. Roberts
CORRESPONDING AUTHOR
NOAA Earth System Research Laboratory (ESRL), Chemical Sciences Division, Boulder, CO 80305, USA
Viewed
Total article views: 3,174 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 02 Jan 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,092 | 997 | 85 | 3,174 | 370 | 78 | 112 |
- HTML: 2,092
- PDF: 997
- XML: 85
- Total: 3,174
- Supplement: 370
- BibTeX: 78
- EndNote: 112
Total article views: 2,486 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 14 May 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,665 | 751 | 70 | 2,486 | 212 | 73 | 98 |
- HTML: 1,665
- PDF: 751
- XML: 70
- Total: 2,486
- Supplement: 212
- BibTeX: 73
- EndNote: 98
Total article views: 688 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 02 Jan 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 427 | 246 | 15 | 688 | 158 | 5 | 14 |
- HTML: 427
- PDF: 246
- XML: 15
- Total: 688
- Supplement: 158
- BibTeX: 5
- EndNote: 14
Viewed (geographical distribution)
Total article views: 3,174 (including HTML, PDF, and XML)
Thereof 3,088 with geography defined
and 86 with unknown origin.
Total article views: 2,486 (including HTML, PDF, and XML)
Thereof 2,438 with geography defined
and 48 with unknown origin.
Total article views: 688 (including HTML, PDF, and XML)
Thereof 650 with geography defined
and 38 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
23 citations as recorded by crossref.
- OH chemistry of non-methane organic gases (NMOGs) emitted from laboratory and ambient biomass burning smoke: evaluating the influence of furans and oxygenated aromatics on ozone and secondary NMOG formation M. Coggon et al. 10.5194/acp-19-14875-2019
- Where there is smoke there is mercury: Assessing boreal forest fire mercury emissions using aircraft and highlighting uncertainties associated with upscaling emissions estimates D. McLagan et al. 10.5194/acp-21-5635-2021
- UV and infrared absorption spectra and 248 nm photolysis of maleic anhydride (C4H2O3) P. Marshall et al. 10.1016/j.jphotochem.2019.111953
- Temperature-compensated ppb-level sulfur dioxide detection system based on fourier transform ultraviolet differential optical absorption spectrum method B. Peng et al. 10.1016/j.snb.2020.127988
- Total organic carbon measurements reveal major gaps in petrochemical emissions reporting M. He et al. 10.1126/science.adj6233
- Reactive nitrogen and total organic carbon calibration techniques for the Aerodyne aerosol mass spectrometer D. Price et al. 10.1080/02786826.2023.2218462
- Mobile Near-Field Measurements of Biomass Burning Volatile Organic Compounds: Emission Ratios and Factor Analysis F. Majluf et al. 10.1021/acs.estlett.2c00194
- Development and validation of a new in situ technique to measure total gaseous chlorine in air T. Furlani et al. 10.5194/amt-16-181-2023
- Observations of cyanogen bromide (BrCN) in the global troposphere and their relation to polar surface O3 destruction J. Roberts et al. 10.5194/acp-24-3421-2024
- An ultra-sensitive detection system for sulfur dioxide and nitric oxide based on improved differential optical absorption spectroscopy method B. Peng et al. 10.1016/j.saa.2020.118169
- The nitrogen budget of laboratory-simulated western US wildfires during the FIREX 2016 Fire Lab study J. Roberts et al. 10.5194/acp-20-8807-2020
- Emerging investigator series: an instrument to measure and speciate the total reactive nitrogen budget indoors: description and field measurements L. Crilley et al. 10.1039/D2EM00446A
- Fire Influence on Regional to Global Environments and Air Quality (FIREX‐AQ) C. Warneke et al. 10.1029/2022JD037758
- Study on the concentration retrieval of SO2 and NO2 in mixed gases based on the improved DOAS method Y. Yang et al. 10.1039/D3RA01512B
- A Method to Measure Total Gaseous Fluorine R. Ye et al. 10.1021/acs.estlett.4c00553
- Estimation of atmospheric total organic carbon (TOC) – paving the path towards carbon budget closure M. Yang & Z. Fleming 10.5194/acp-19-459-2019
- Solubility and solution-phase chemistry of isocyanic acid, methyl isocyanate, and cyanogen halides J. Roberts & Y. Liu 10.5194/acp-19-4419-2019
- Quantification of Non-refractory Aerosol Nitrate in Ambient Air by Thermal Dissociation Cavity Ring-Down Spectroscopy N. Garner et al. 10.1021/acs.est.0c01156
- Complexity in the Evolution, Composition, and Spectroscopy of Brown Carbon in Aircraft Measurements of Wildfire Plumes R. Washenfelder et al. 10.1029/2022GL098951
- Ultrasensitive NO Monitoring System Based on Fourier Transform Ultraviolet Differential Optical Absorption Spectrum B. Peng & Y. Guo 10.1109/TIM.2024.3450069
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
- Optical properties of biomass burning aerosol during the 2021 Oregon fire season: comparison between wild and prescribed fires A. Marsavin et al. 10.1039/D2EA00118G
- Non-methane organic gas emissions from biomass burning: identification, quantification, and emission factors from PTR-ToF during the FIREX 2016 laboratory experiment A. Koss et al. 10.5194/acp-18-3299-2018
22 citations as recorded by crossref.
- OH chemistry of non-methane organic gases (NMOGs) emitted from laboratory and ambient biomass burning smoke: evaluating the influence of furans and oxygenated aromatics on ozone and secondary NMOG formation M. Coggon et al. 10.5194/acp-19-14875-2019
- Where there is smoke there is mercury: Assessing boreal forest fire mercury emissions using aircraft and highlighting uncertainties associated with upscaling emissions estimates D. McLagan et al. 10.5194/acp-21-5635-2021
- UV and infrared absorption spectra and 248 nm photolysis of maleic anhydride (C4H2O3) P. Marshall et al. 10.1016/j.jphotochem.2019.111953
- Temperature-compensated ppb-level sulfur dioxide detection system based on fourier transform ultraviolet differential optical absorption spectrum method B. Peng et al. 10.1016/j.snb.2020.127988
- Total organic carbon measurements reveal major gaps in petrochemical emissions reporting M. He et al. 10.1126/science.adj6233
- Reactive nitrogen and total organic carbon calibration techniques for the Aerodyne aerosol mass spectrometer D. Price et al. 10.1080/02786826.2023.2218462
- Mobile Near-Field Measurements of Biomass Burning Volatile Organic Compounds: Emission Ratios and Factor Analysis F. Majluf et al. 10.1021/acs.estlett.2c00194
- Development and validation of a new in situ technique to measure total gaseous chlorine in air T. Furlani et al. 10.5194/amt-16-181-2023
- Observations of cyanogen bromide (BrCN) in the global troposphere and their relation to polar surface O3 destruction J. Roberts et al. 10.5194/acp-24-3421-2024
- An ultra-sensitive detection system for sulfur dioxide and nitric oxide based on improved differential optical absorption spectroscopy method B. Peng et al. 10.1016/j.saa.2020.118169
- The nitrogen budget of laboratory-simulated western US wildfires during the FIREX 2016 Fire Lab study J. Roberts et al. 10.5194/acp-20-8807-2020
- Emerging investigator series: an instrument to measure and speciate the total reactive nitrogen budget indoors: description and field measurements L. Crilley et al. 10.1039/D2EM00446A
- Fire Influence on Regional to Global Environments and Air Quality (FIREX‐AQ) C. Warneke et al. 10.1029/2022JD037758
- Study on the concentration retrieval of SO2 and NO2 in mixed gases based on the improved DOAS method Y. Yang et al. 10.1039/D3RA01512B
- A Method to Measure Total Gaseous Fluorine R. Ye et al. 10.1021/acs.estlett.4c00553
- Estimation of atmospheric total organic carbon (TOC) – paving the path towards carbon budget closure M. Yang & Z. Fleming 10.5194/acp-19-459-2019
- Solubility and solution-phase chemistry of isocyanic acid, methyl isocyanate, and cyanogen halides J. Roberts & Y. Liu 10.5194/acp-19-4419-2019
- Quantification of Non-refractory Aerosol Nitrate in Ambient Air by Thermal Dissociation Cavity Ring-Down Spectroscopy N. Garner et al. 10.1021/acs.est.0c01156
- Complexity in the Evolution, Composition, and Spectroscopy of Brown Carbon in Aircraft Measurements of Wildfire Plumes R. Washenfelder et al. 10.1029/2022GL098951
- Ultrasensitive NO Monitoring System Based on Fourier Transform Ultraviolet Differential Optical Absorption Spectrum B. Peng & Y. Guo 10.1109/TIM.2024.3450069
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
- Optical properties of biomass burning aerosol during the 2021 Oregon fire season: comparison between wild and prescribed fires A. Marsavin et al. 10.1039/D2EA00118G
Latest update: 20 Nov 2024
Short summary
This work investigates the total conversion of particle-bound nitrogen and organic carbon across platinum and molybdenum catalysts followed by NO–O3 chemiluminescence and nondispersive infrared CO2 detection. We show the instrument is an accurate particle mass measurement method and demonstrate its ability to calibrate particle mass measurement instrumentation through comparisons with a calibrated particle-into-liquid sampler coupled to an electrospray ionization source of a mass spectrometer.
This work investigates the total conversion of particle-bound nitrogen and organic carbon across...
