Articles | Volume 11, issue 6
https://doi.org/10.5194/amt-11-3351-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/amt-11-3351-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Jun 2018
Research article |
| 12 Jun 2018
| 12 Jun 2018
Dynamic–gravimetric preparation of metrologically traceable primary calibration standards for halogenated greenhouse gases
Myriam Guillevic
CORRESPONDING AUTHOR
Federal Institute of Metrology METAS, 3003 Berne, Switzerland
Martin K. Vollmer
Laboratory for Air Pollution and Environmental Technology, Empa, Swiss Federal Laboratories for Materials Science and Technology, Dübendorf, Switzerland
Simon A. Wyss
Laboratory for Air Pollution and Environmental Technology, Empa, Swiss Federal Laboratories for Materials Science and Technology, Dübendorf, Switzerland
Daiana Leuenberger
Federal Institute of Metrology METAS, 3003 Berne, Switzerland
now at: Federal Office for the Environment FOEN, Air Pollution and Chemicals Division, 3003 Berne, Switzerland
Andreas Ackermann
Federal Institute of Metrology METAS, 3003 Berne, Switzerland
Céline Pascale
Federal Institute of Metrology METAS, 3003 Berne, Switzerland
Bernhard Niederhauser
Federal Institute of Metrology METAS, 3003 Berne, Switzerland
Stefan Reimann
Laboratory for Air Pollution and Environmental Technology, Empa, Swiss Federal Laboratories for Materials Science and Technology, Dübendorf, Switzerland
Viewed
Total article views: 3,335 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 05 Feb 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,185 | 1,034 | 116 | 3,335 | 475 | 105 | 87 |
- HTML: 2,185
- PDF: 1,034
- XML: 116
- Total: 3,335
- Supplement: 475
- BibTeX: 105
- EndNote: 87
Total article views: 2,672 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 12 Jun 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,876 | 693 | 103 | 2,672 | 275 | 101 | 79 |
- HTML: 1,876
- PDF: 693
- XML: 103
- Total: 2,672
- Supplement: 275
- BibTeX: 101
- EndNote: 79
Total article views: 663 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 05 Feb 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 309 | 341 | 13 | 663 | 200 | 4 | 8 |
- HTML: 309
- PDF: 341
- XML: 13
- Total: 663
- Supplement: 200
- BibTeX: 4
- EndNote: 8
Viewed (geographical distribution)
Total article views: 3,335 (including HTML, PDF, and XML)
Thereof 3,096 with geography defined
and 239 with unknown origin.
Total article views: 2,672 (including HTML, PDF, and XML)
Thereof 2,528 with geography defined
and 144 with unknown origin.
Total article views: 663 (including HTML, PDF, and XML)
Thereof 568 with geography defined
and 95 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
12 citations as recorded by crossref.
- Automated fragment formula annotation for electron ionisation, high resolution mass spectrometry: application to atmospheric measurements of halocarbons M. Guillevic et al. 10.1186/s13321-021-00544-w
- A comprehensive evaluation of the use of Lagrangian particle dispersion models for inverse modeling of greenhouse gas emissions M. Vojta et al. 10.5194/gmd-15-8295-2022
- Stability study and uncertainty evaluation of CO2 certified reference materials for greenhouse gases monitoring F. Durbiano et al. 10.1016/j.measurement.2024.114653
- SI-traceable validation of a laser spectrometer for balloon-borne measurements of water vapor in the upper atmosphere S. Brunamonti et al. 10.5194/amt-16-4391-2023
- Validation of breath biomarkers for obstructive sleep apnea N. Nowak et al. 10.1016/j.sleep.2021.06.040
- Trace level analysis of reactive ISO 14687 impurities in hydrogen fuel using laser-based spectroscopic detection methods H. Meuzelaar et al. 10.1016/j.ijhydene.2020.09.046
- An indirect-calibration method for non-target quantification of trace gases applied to a time series of fourth-generation synthetic halocarbons at the Taunus Observatory (Germany) F. Lefrancois et al. 10.5194/amt-14-4669-2021
- High-precision methane isotopic abundance analysis using near-infrared absorption spectroscopy at 100 Torr Z. Liu et al. 10.1039/D0AN01588A
- Unexpected nascent atmospheric emissions of three ozone-depleting hydrochlorofluorocarbons M. Vollmer et al. 10.1073/pnas.2010914118
- First Atmospheric Measurements and Emission Estimates of HFO-1336mzz(Z) D. Rust et al. 10.1021/acs.est.3c01826
- A review on preparation methods and measurement techniques of reference gas mixtures . Komal & D. Soni 10.1016/j.microc.2023.109742
- Atmospheric histories and emissions of chlorofluorocarbons CFC-13 (CClF<sub>3</sub>), ΣCFC-114 (C<sub>2</sub>Cl<sub>2</sub>F<sub>4</sub>), and CFC-115 (C<sub>2</sub>ClF<sub>5</sub>) M. Vollmer et al. 10.5194/acp-18-979-2018
11 citations as recorded by crossref.
- Automated fragment formula annotation for electron ionisation, high resolution mass spectrometry: application to atmospheric measurements of halocarbons M. Guillevic et al. 10.1186/s13321-021-00544-w
- A comprehensive evaluation of the use of Lagrangian particle dispersion models for inverse modeling of greenhouse gas emissions M. Vojta et al. 10.5194/gmd-15-8295-2022
- Stability study and uncertainty evaluation of CO2 certified reference materials for greenhouse gases monitoring F. Durbiano et al. 10.1016/j.measurement.2024.114653
- SI-traceable validation of a laser spectrometer for balloon-borne measurements of water vapor in the upper atmosphere S. Brunamonti et al. 10.5194/amt-16-4391-2023
- Validation of breath biomarkers for obstructive sleep apnea N. Nowak et al. 10.1016/j.sleep.2021.06.040
- Trace level analysis of reactive ISO 14687 impurities in hydrogen fuel using laser-based spectroscopic detection methods H. Meuzelaar et al. 10.1016/j.ijhydene.2020.09.046
- An indirect-calibration method for non-target quantification of trace gases applied to a time series of fourth-generation synthetic halocarbons at the Taunus Observatory (Germany) F. Lefrancois et al. 10.5194/amt-14-4669-2021
- High-precision methane isotopic abundance analysis using near-infrared absorption spectroscopy at 100 Torr Z. Liu et al. 10.1039/D0AN01588A
- Unexpected nascent atmospheric emissions of three ozone-depleting hydrochlorofluorocarbons M. Vollmer et al. 10.1073/pnas.2010914118
- First Atmospheric Measurements and Emission Estimates of HFO-1336mzz(Z) D. Rust et al. 10.1021/acs.est.3c01826
- A review on preparation methods and measurement techniques of reference gas mixtures . Komal & D. Soni 10.1016/j.microc.2023.109742
1 citations as recorded by crossref.
Latest update: 24 Apr 2024
Short summary
We present new primary calibration scales for five halogenated greenhouse gases. The preparation method, newly applied to halocarbons, is dynamic and gravimetric
and allows the generation of reference gas mixtures at near-ambient levels (pmol mol−1). Each prepared molar fraction is traceable to the
realisation of SI units (International System of Units) and is assigned an uncertainty estimate following international guidelines.
We present new primary calibration scales for five halogenated greenhouse gases. The preparation...
