Articles | Volume 11, issue 6
https://doi.org/10.5194/amt-11-3351-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/amt-11-3351-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Dynamic–gravimetric preparation of metrologically traceable primary calibration standards for halogenated greenhouse gases
Myriam Guillevic
CORRESPONDING AUTHOR
Federal Institute of Metrology METAS, 3003 Berne, Switzerland
Martin K. Vollmer
Laboratory for Air Pollution and Environmental Technology, Empa, Swiss Federal Laboratories for Materials Science and Technology, Dübendorf, Switzerland
Simon A. Wyss
Laboratory for Air Pollution and Environmental Technology, Empa, Swiss Federal Laboratories for Materials Science and Technology, Dübendorf, Switzerland
Daiana Leuenberger
Federal Institute of Metrology METAS, 3003 Berne, Switzerland
now at: Federal Office for the Environment FOEN, Air Pollution and Chemicals Division, 3003 Berne, Switzerland
Andreas Ackermann
Federal Institute of Metrology METAS, 3003 Berne, Switzerland
Céline Pascale
Federal Institute of Metrology METAS, 3003 Berne, Switzerland
Bernhard Niederhauser
Federal Institute of Metrology METAS, 3003 Berne, Switzerland
Stefan Reimann
Laboratory for Air Pollution and Environmental Technology, Empa, Swiss Federal Laboratories for Materials Science and Technology, Dübendorf, Switzerland
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Latest update: 23 Nov 2024
Short summary
We present new primary calibration scales for five halogenated greenhouse gases. The preparation method, newly applied to halocarbons, is dynamic and gravimetric
and allows the generation of reference gas mixtures at near-ambient levels (pmol mol−1). Each prepared molar fraction is traceable to the
realisation of SI units (International System of Units) and is assigned an uncertainty estimate following international guidelines.
We present new primary calibration scales for five halogenated greenhouse gases. The preparation...