Articles | Volume 11, issue 6
https://doi.org/10.5194/amt-11-3479-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-3479-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
19 Jun 2018
Research article |
| 19 Jun 2018
| 19 Jun 2018
Kinetically controlled glass transition measurement of organic aerosol thin films using broadband dielectric spectroscopy
Yue Zhang
Department of Chemistry, Boston College, Chestnut Hill, MA 02459, USA
Aerodyne Research Inc., Billerica, MA 01821, USA
Department of Environmental Science and Engineering, Gillings School of Global Public Health, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599, USA
Shachi Katira
Department of Chemistry, University of California, Berkeley, CA 94720, USA
Andrew Lee
Department of Chemistry, Boston College, Chestnut Hill, MA 02459, USA
now at: Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599, USA
Andrew T. Lambe
Aerodyne Research Inc., Billerica, MA 01821, USA
Timothy B. Onasch
Department of Chemistry, Boston College, Chestnut Hill, MA 02459, USA
Aerodyne Research Inc., Billerica, MA 01821, USA
Aerodyne Research Inc., Billerica, MA 01821, USA
William A. Brooks
Aerodyne Research Inc., Billerica, MA 01821, USA
Manjula R. Canagaratna
Aerodyne Research Inc., Billerica, MA 01821, USA
Andrew Freedman
Aerodyne Research Inc., Billerica, MA 01821, USA
John T. Jayne
Aerodyne Research Inc., Billerica, MA 01821, USA
Doug R. Worsnop
Aerodyne Research Inc., Billerica, MA 01821, USA
Paul Davidovits
CORRESPONDING AUTHOR
Department of Chemistry, Boston College, Chestnut Hill, MA 02459, USA
David Chandler
Department of Chemistry, University of California, Berkeley, CA 94720, USA
deceased, April 2017
Aerodyne Research Inc., Billerica, MA 01821, USA
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Cited
11 citations as recorded by crossref.
- The Cooling Rate- and Volatility-Dependent Glass-Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy Y. Zhang et al. 10.1021/acs.est.9b03317
- Heterogeneous Hydroxyl Radical Oxidation of Isoprene-Epoxydiol-Derived Methyltetrol Sulfates: Plausible Formation Mechanisms of Previously Unexplained Organosulfates in Ambient Fine Aerosols Y. Chen et al. 10.1021/acs.estlett.0c00276
- Morphology and Viscosity Changes after Reactive Uptake of Isoprene Epoxydiols in Submicrometer Phase Separated Particles with Secondary Organic Aerosol Formed from Different Volatile Organic Compounds Z. Lei et al. 10.1021/acsearthspacechem.1c00156
- Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Y. Zhang et al. 10.1021/acsearthspacechem.9b00209
- The effects of morphology, mobility size, and secondary organic aerosol (SOA) material coating on the ice nucleation activity of black carbon in the cirrus regime C. Zhang et al. 10.5194/acp-20-13957-2020
- Glass Transition Temperatures of Individual Submicrometer Atmospheric Particles: Direct Measurement via Heated Atomic Force Microscopy Probe Z. Lei et al. 10.1021/acs.analchem.2c01979
- Laboratory study of the heterogeneous ice nucleation on black-carbon-containing aerosol L. Nichman et al. 10.5194/acp-19-12175-2019
- Characterising the glass transition temperature-structure relationship through a recurrent neural network C. Borredon et al. 10.1016/j.nocx.2023.100185
- Glass Transition Temperatures of Organic Mixtures from Isoprene Epoxydiol-Derived Secondary Organic Aerosol B. Chen et al. 10.1021/acs.jpca.2c08936
- Carbon-Based Nanomaterials for Plasmonic Sensors: A Review B. Gupta et al. 10.3390/s19163536
- Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions Y. Li et al. 10.5194/acp-20-8103-2020
11 citations as recorded by crossref.
- The Cooling Rate- and Volatility-Dependent Glass-Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy Y. Zhang et al. 10.1021/acs.est.9b03317
- Heterogeneous Hydroxyl Radical Oxidation of Isoprene-Epoxydiol-Derived Methyltetrol Sulfates: Plausible Formation Mechanisms of Previously Unexplained Organosulfates in Ambient Fine Aerosols Y. Chen et al. 10.1021/acs.estlett.0c00276
- Morphology and Viscosity Changes after Reactive Uptake of Isoprene Epoxydiols in Submicrometer Phase Separated Particles with Secondary Organic Aerosol Formed from Different Volatile Organic Compounds Z. Lei et al. 10.1021/acsearthspacechem.1c00156
- Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Y. Zhang et al. 10.1021/acsearthspacechem.9b00209
- The effects of morphology, mobility size, and secondary organic aerosol (SOA) material coating on the ice nucleation activity of black carbon in the cirrus regime C. Zhang et al. 10.5194/acp-20-13957-2020
- Glass Transition Temperatures of Individual Submicrometer Atmospheric Particles: Direct Measurement via Heated Atomic Force Microscopy Probe Z. Lei et al. 10.1021/acs.analchem.2c01979
- Laboratory study of the heterogeneous ice nucleation on black-carbon-containing aerosol L. Nichman et al. 10.5194/acp-19-12175-2019
- Characterising the glass transition temperature-structure relationship through a recurrent neural network C. Borredon et al. 10.1016/j.nocx.2023.100185
- Glass Transition Temperatures of Organic Mixtures from Isoprene Epoxydiol-Derived Secondary Organic Aerosol B. Chen et al. 10.1021/acs.jpca.2c08936
- Carbon-Based Nanomaterials for Plasmonic Sensors: A Review B. Gupta et al. 10.3390/s19163536
- Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions Y. Li et al. 10.5194/acp-20-8103-2020
Latest update: 20 Nov 2024
Short summary
We have adopted a new technique for measuring glass-forming properties of atmospherically relevant organic aerosols at submicron sizes and relatively low mass concentrations. Aerosol particles are deposited in the form of a thin film with interdigitated electrodes using electrostatic precipitation. Broadband dielectric spectroscopy is used to measure the kinetically controlled glass transition temperatures of glycerol and citric acid aerosols with three atmospheric relevant cooling rates.
We have adopted a new technique for measuring glass-forming properties of atmospherically...
