Articles | Volume 12, issue 3
https://doi.org/10.5194/amt-12-1685-2019
https://doi.org/10.5194/amt-12-1685-2019
Research article
 | 
15 Mar 2019
Research article |  | 15 Mar 2019

The interference of tetrachloromethane in the measurement of benzene in the air by a gas chromatography–photoionisation detector (GC-PID)

Cristina Romero-Trigueros, María Esther González, Marta Doval Miñarro, and Enrique González Ferradás

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Short summary
Determining benzene in ambient air is mandatory in the European Union. The reference measuring technique is by gas chromatography (GC), and a photometric ionisation detector is recommended. This study shows that the simultaneous presence of benzene and tetrachloromethane causes a significant decrease in GC–photoionisation detector (GC-PID) readings. Given the importance of this behaviour, a possible mechanism was proposed. This study highlights the uncertainty of measuring benzene with a GC-PID.