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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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AMT | Articles | Volume 12, issue 7
Atmos. Meas. Tech., 12, 3841–3851, 2019
https://doi.org/10.5194/amt-12-3841-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Meas. Tech., 12, 3841–3851, 2019
https://doi.org/10.5194/amt-12-3841-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 12 Jul 2019

Research article | 12 Jul 2019

Separation and detection of aqueous atmospheric aerosol mimics using supercritical fluid chromatography–mass spectrometry

Daisy N. Grace et al.

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Short summary
The identification and quantification of compounds within an atmospheric particle can be difficult to achieve. We present a supercritical fluid chromatography method to separate these compounds prior to mass spectrometry analysis. The aqueous methylglyoxal–ammonium sulfate system was used as a proxy for atmospheric aerosol; polar columns combined with a carbon dioxide and methanol mobile phase provided the most efficient separation. This method can be extended to other atmospheric systems.
The identification and quantification of compounds within an atmospheric particle can be...
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