Articles | Volume 12, issue 2
https://doi.org/10.5194/amt-12-891-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-12-891-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
08 Feb 2019
Research article |
| 08 Feb 2019
| 08 Feb 2019
Measurements of hydroperoxy radicals (HO2) at atmospheric concentrations using bromide chemical ionisation mass spectrometry
Sascha R. Albrecht
CORRESPONDING AUTHOR
Institute of Energy and Climate Research – Troposphere (IEK-8), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Anna Novelli
Institute of Energy and Climate Research – Troposphere (IEK-8), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Andreas Hofzumahaus
Institute of Energy and Climate Research – Troposphere (IEK-8), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Sungah Kang
Institute of Energy and Climate Research – Troposphere (IEK-8), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Yare Baker
Institute of Energy and Climate Research – Troposphere (IEK-8), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Thomas Mentel
Institute of Energy and Climate Research – Troposphere (IEK-8), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research – Troposphere (IEK-8), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Hendrik Fuchs
Institute of Energy and Climate Research – Troposphere (IEK-8), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
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Cited
18 citations as recorded by crossref.
- Calibration of an airborne HOx instrument using the All Pressure Altitude-based Calibrator for HOx Experimentation (APACHE) D. Marno et al. 10.5194/amt-13-2711-2020
- Reaction between propionaldehyde and hydroxyperoxy radical in the atmosphere: A reaction route for the sink of propionaldehyde and the formation of formic acid D. Ding & B. Long 10.1016/j.atmosenv.2022.119202
- Advances on Atmospheric Oxidation Mechanism of Typical Aromatic Hydrocarbons M. Song et al. 10.6023/A21050224
- Measurements of Atmospheric HO2 Radicals Using Br-CIMS with Elimination of Potential Interferences from Ambient Peroxynitric Acid L. Wang et al. 10.1021/acs.analchem.4c01184
- Recent progress in chemical ionization mass spectrometry and its application in atmospheric environment W. Li et al. 10.1016/j.atmosenv.2024.120426
- Impact of HO2∕RO2 ratio on highly oxygenated α-pinene photooxidation products and secondary organic aerosol formation potential Y. Baker et al. 10.5194/acp-24-4789-2024
- Multi-scheme chemical ionization inlet (MION) for fast switching of reagent ion chemistry in atmospheric pressure chemical ionization mass spectrometry (CIMS) applications M. Rissanen et al. 10.5194/amt-12-6635-2019
- Molecular composition and volatility of multi-generation products formed from isoprene oxidation by nitrate radical R. Wu et al. 10.5194/acp-21-10799-2021
- Airborne measurement of peroxy radicals using chemical amplification coupled with cavity ring-down spectroscopy: the PeRCEAS instrument M. George et al. 10.5194/amt-13-2577-2020
- Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene R. Wu et al. 10.5194/amt-17-1811-2024
- Atmospheric photooxidation and ozonolysis of Δ3-carene and 3-caronaldehyde: rate constants and product yields L. Hantschke et al. 10.5194/acp-21-12665-2021
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Hydroxyl, hydroperoxyl free radicals determination methods in atmosphere and troposphere G. Wang et al. 10.1016/j.jes.2020.06.038
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- Techniques for measuring indoor radicals and radical precursors E. Alvarez et al. 10.1080/05704928.2022.2087666
- Photoelectron angular distributions in photodetachment from polarised d-like states: the case of HO2− C. Blackstone et al. 10.1080/00268976.2020.1831636
- Resolving Discrepancies between State-of-the-Art Theory and Experiment for HO2 + HO2 via Multiscale Informatics C. LaGrotta et al. 10.1021/acs.jpca.2c07297
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
18 citations as recorded by crossref.
- Calibration of an airborne HOx instrument using the All Pressure Altitude-based Calibrator for HOx Experimentation (APACHE) D. Marno et al. 10.5194/amt-13-2711-2020
- Reaction between propionaldehyde and hydroxyperoxy radical in the atmosphere: A reaction route for the sink of propionaldehyde and the formation of formic acid D. Ding & B. Long 10.1016/j.atmosenv.2022.119202
- Advances on Atmospheric Oxidation Mechanism of Typical Aromatic Hydrocarbons M. Song et al. 10.6023/A21050224
- Measurements of Atmospheric HO2 Radicals Using Br-CIMS with Elimination of Potential Interferences from Ambient Peroxynitric Acid L. Wang et al. 10.1021/acs.analchem.4c01184
- Recent progress in chemical ionization mass spectrometry and its application in atmospheric environment W. Li et al. 10.1016/j.atmosenv.2024.120426
- Impact of HO2∕RO2 ratio on highly oxygenated α-pinene photooxidation products and secondary organic aerosol formation potential Y. Baker et al. 10.5194/acp-24-4789-2024
- Multi-scheme chemical ionization inlet (MION) for fast switching of reagent ion chemistry in atmospheric pressure chemical ionization mass spectrometry (CIMS) applications M. Rissanen et al. 10.5194/amt-12-6635-2019
- Molecular composition and volatility of multi-generation products formed from isoprene oxidation by nitrate radical R. Wu et al. 10.5194/acp-21-10799-2021
- Airborne measurement of peroxy radicals using chemical amplification coupled with cavity ring-down spectroscopy: the PeRCEAS instrument M. George et al. 10.5194/amt-13-2577-2020
- Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene R. Wu et al. 10.5194/amt-17-1811-2024
- Atmospheric photooxidation and ozonolysis of Δ3-carene and 3-caronaldehyde: rate constants and product yields L. Hantschke et al. 10.5194/acp-21-12665-2021
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Hydroxyl, hydroperoxyl free radicals determination methods in atmosphere and troposphere G. Wang et al. 10.1016/j.jes.2020.06.038
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- Techniques for measuring indoor radicals and radical precursors E. Alvarez et al. 10.1080/05704928.2022.2087666
- Photoelectron angular distributions in photodetachment from polarised d-like states: the case of HO2− C. Blackstone et al. 10.1080/00268976.2020.1831636
- Resolving Discrepancies between State-of-the-Art Theory and Experiment for HO2 + HO2 via Multiscale Informatics C. LaGrotta et al. 10.1021/acs.jpca.2c07297
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
Latest update: 30 Mar 2025
Short summary
Within this study we demonstrate reliable measurement of hydroperoxy (HO2) radicals via chemical ionisation mass spectrometry. HO2 is detected as an ion cluster with bromide ions, which allows a selective detection. This direct and sensitive measurement provides reliable data of HO2 radical concentrations in the atmosphere as demonstrated in the first application in simulation chamber experiments.
Within this study we demonstrate reliable measurement of hydroperoxy (HO2) radicals via chemical...
