Articles | Volume 13, issue 5
https://doi.org/10.5194/amt-13-2397-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-13-2397-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 May 2020
Research article |
| 15 May 2020
| 15 May 2020
Nitrate radical generation via continuous generation of dinitrogen pentoxide in a laminar flow reactor coupled to an oxidation flow reactor
Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica, MA, USA
Ezra C. Wood
Department of Chemistry, Drexel University, Philadelphia, PA, USA
Jordan E. Krechmer
Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica, MA, USA
Francesca Majluf
Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica, MA, USA
Leah R. Williams
Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica, MA, USA
Philip L. Croteau
Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica, MA, USA
Manuela Cirtog
Laboratoire Inter-Universitaire des Systèmes Atmosphériques (LISA), UMR CNRS 7583, Université Paris-Est-Créteil, Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil, France
Anaïs Féron
Laboratoire Inter-Universitaire des Systèmes Atmosphériques (LISA), UMR CNRS 7583, Université Paris-Est-Créteil, Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil, France
Jean-Eudes Petit
Laboratoire des Sciences du Climat et de l'Environnement (CNRS-CEA-UVSQ), CEA Orme des Merisiers, Gif-sur-Yvette, France
Alexandre Albinet
Institut National de l'Environnement Industriel et des Risques (Ineris), Verneuil-en-Halatte, France
Jose L. Jimenez
Department of Chemistry and Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
Department of Chemistry and Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
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Cited
9 citations as recorded by crossref.
- Conversion of Catechol to 4-Nitrocatechol in Aqueous Microdroplets Exposed to O3 and NO2 M. Rana et al. 10.1021/acsestair.3c00001
- Diel cycle impacts on the chemical and light absorption properties of organic carbon aerosol from wildfires in the western United States B. Sumlin et al. 10.5194/acp-21-11843-2021
- Technical note: Gas-phase nitrate radical generation via irradiation of aerated ceric ammonium nitrate mixtures A. Lambe et al. 10.5194/acp-23-13869-2023
- Oxidation of Catechols at the Air–Water Interface by Nitrate Radicals M. Rana & M. Guzman 10.1021/acs.est.2c05640
- Insights into secondary organic aerosol formation from the day- and nighttime oxidation of polycyclic aromatic hydrocarbons and furans in an oxidation flow reactor A. El Mais et al. 10.5194/acp-23-15077-2023
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Insights Into Formation and Aging of Secondary Organic Aerosol From Oxidation Flow Reactors: A Review Z. Zhang et al. 10.1007/s40726-024-00309-7
- Detecting and Characterizing Particulate Organic Nitrates with an Aerodyne Long-ToF Aerosol Mass Spectrometer F. Graeffe et al. 10.1021/acsearthspacechem.2c00314
- Evolution of the light-absorption properties of combustion brown carbon aerosols following reaction with nitrate radicals Z. Cheng et al. 10.1080/02786826.2020.1726867
8 citations as recorded by crossref.
- Conversion of Catechol to 4-Nitrocatechol in Aqueous Microdroplets Exposed to O3 and NO2 M. Rana et al. 10.1021/acsestair.3c00001
- Diel cycle impacts on the chemical and light absorption properties of organic carbon aerosol from wildfires in the western United States B. Sumlin et al. 10.5194/acp-21-11843-2021
- Technical note: Gas-phase nitrate radical generation via irradiation of aerated ceric ammonium nitrate mixtures A. Lambe et al. 10.5194/acp-23-13869-2023
- Oxidation of Catechols at the Air–Water Interface by Nitrate Radicals M. Rana & M. Guzman 10.1021/acs.est.2c05640
- Insights into secondary organic aerosol formation from the day- and nighttime oxidation of polycyclic aromatic hydrocarbons and furans in an oxidation flow reactor A. El Mais et al. 10.5194/acp-23-15077-2023
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Insights Into Formation and Aging of Secondary Organic Aerosol From Oxidation Flow Reactors: A Review Z. Zhang et al. 10.1007/s40726-024-00309-7
- Detecting and Characterizing Particulate Organic Nitrates with an Aerodyne Long-ToF Aerosol Mass Spectrometer F. Graeffe et al. 10.1021/acsearthspacechem.2c00314
Latest update: 16 Jul 2024
Short summary
We present a new method to continuously generate N2O5 in the gas phase that is injected into a reactor where it decomposes to generate nitrate radicals (NO3). To assess the applicability of the method towards different chemical systems, we present experimental and model characterization of the integrated NO3 exposure and other metrics as a function of operating conditions. We demonstrate the method by characterizing secondary organic aerosol particles generated from the β-pinene + NO3 reaction.
We present a new method to continuously generate N2O5 in the gas phase that is injected into a...
