Articles | Volume 13, issue 5
https://doi.org/10.5194/amt-13-2797-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-13-2797-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| Highlight paper
| 
28 May 2020
Research article | Highlight paper |
| 28 May 2020
| 28 May 2020
N2O isotopocule measurements using laser spectroscopy: analyzer characterization and intercomparison
Stephen J. Harris
School of Biological, Earth and Environmental Sciences, UNSW Sydney, NSW, Australia
Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW, Australia
Jesper Liisberg
University of Copenhagen, Niels Bohr Institute, Copenhagen, Denmark
Longlong Xia
Karlsruhe Institute of Technology, IMK-IFU, Garmisch-Partenkirchen,
Germany
Empa, Laboratory for Air Pollution/Environmental Technology,
Dübendorf, Switzerland
Kerstin Zeyer
Empa, Laboratory for Air Pollution/Environmental Technology,
Dübendorf, Switzerland
Longfei Yu
Empa, Laboratory for Air Pollution/Environmental Technology,
Dübendorf, Switzerland
Matti Barthel
ETH Zürich, Department of Environmental Systems Science,
Zürich, Switzerland
Benjamin Wolf
Karlsruhe Institute of Technology, IMK-IFU, Garmisch-Partenkirchen,
Germany
Bryce F. J. Kelly
School of Biological, Earth and Environmental Sciences, UNSW Sydney, NSW, Australia
Dioni I. Cendón
Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW, Australia
Thomas Blunier
University of Copenhagen, Niels Bohr Institute, Copenhagen, Denmark
Johan Six
ETH Zürich, Department of Environmental Systems Science,
Zürich, Switzerland
Empa, Laboratory for Air Pollution/Environmental Technology,
Dübendorf, Switzerland
Viewed
Total article views: 7,564 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 05 Dec 2019)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 5,571 | 1,880 | 113 | 7,564 | 480 | 121 | 147 |
- HTML: 5,571
- PDF: 1,880
- XML: 113
- Total: 7,564
- Supplement: 480
- BibTeX: 121
- EndNote: 147
Total article views: 6,169 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 28 May 2020)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 4,941 | 1,125 | 103 | 6,169 | 390 | 111 | 142 |
- HTML: 4,941
- PDF: 1,125
- XML: 103
- Total: 6,169
- Supplement: 390
- BibTeX: 111
- EndNote: 142
Total article views: 1,395 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 05 Dec 2019)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 630 | 755 | 10 | 1,395 | 90 | 10 | 5 |
- HTML: 630
- PDF: 755
- XML: 10
- Total: 1,395
- Supplement: 90
- BibTeX: 10
- EndNote: 5
Viewed (geographical distribution)
Total article views: 7,564 (including HTML, PDF, and XML)
Thereof 6,943 with geography defined
and 621 with unknown origin.
Total article views: 6,169 (including HTML, PDF, and XML)
Thereof 5,809 with geography defined
and 360 with unknown origin.
Total article views: 1,395 (including HTML, PDF, and XML)
Thereof 1,134 with geography defined
and 261 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
35 citations as recorded by crossref.
- Utilizing Novel Field and Data Exploration Methods to Explore Hot Moments in High-Frequency Soil Nitrous Oxide Emissions Data: Opportunities and Challenges C. O’Connell et al. 10.3389/ffgc.2022.674348
- Development and verification of a novel isotopic N2O measurement technique for discrete static chamber samples using cavity ring‐down spectroscopy C. Bracken et al. 10.1002/rcm.9049
- Low N2O and variable CH4 fluxes from tropical forest soils of the Congo Basin M. Barthel et al. 10.1038/s41467-022-27978-6
- Precision Spectroscopy of Nitrous Oxide Isotopocules with a Cross-Dispersed Spectrometer and a Mid-Infrared Frequency Comb D. Bailey et al. 10.1021/acs.analchem.0c01868
- CleanEx: A Versatile Automated Methane Preconcentration Device for High-Precision Analysis of 13CH4, 12CH3D, and 13CH3D I. Prokhorov & J. Mohn 10.1021/acs.analchem.2c01949
- Primings of soil organic matter and denitrification mediate the effects of moisture on nitrous oxide production S. Thilakarathna & G. Hernandez-Ramirez 10.1016/j.soilbio.2021.108166
- A decision support tool for the selection of 15 N analysis methods of ammonium and nitrate M. Jia et al. 10.1007/s10705-022-10227-z
- Bacterial denitrification drives elevated N 2 O emissions in arid southern California drylands A. Krichels et al. 10.1126/sciadv.adj1989
- An approach for calibrating laser‐based N2O isotopic analyzers for soil biogeochemistry research E. Stuchiner et al. 10.1002/rcm.8978
- What can we learn from N2O isotope data? – Analytics, processes and modelling L. Yu et al. 10.1002/rcm.8858
- Simultaneous measurement of δ13C, δ18O and δ17O of atmospheric CO2 – performance assessment of a dual-laser absorption spectrometer P. Steur et al. 10.5194/amt-14-4279-2021
- Tracing plant–environment interactions from organismal to planetary scales using stable isotopes: a mini review J. Jez et al. 10.1042/ETLS20200277
- Smaller Aerobic Granules Significantly Reduce N2O Production by Ammonia-Oxidizing Bacteria: Evidences from Biochemical and Isotopic Analyses Y. Liu et al. 10.1021/acs.est.3c06246
- Characterisation of gas reference materials for underpinning atmospheric measurements of stable isotopes of nitrous oxide R. Hill-Pearce et al. 10.5194/amt-14-5447-2021
- Simultaneous 15N Online Analysis in NH4+, NO2–, NO3–, and N2O to Trace N2O Production Pathways in Nitrogen-Polluted Aqueous Environments K. Huang et al. 10.1021/acsestwater.3c00216
- Recent Progress in Cutting-edge Monitoring Tools for Microbiomes in Engineered Systems A. TERADA et al. 10.2965/jswe.45.91
- MULTICHARME: a modified Chernin-type multi-pass cell designed for IR and THz long-path absorption measurements in the CHARME atmospheric simulation chamber J. Decker et al. 10.5194/amt-15-1201-2022
- Effect of Physico-Chemical Properties Induced by N, P Co-Doped Biomass Porous Carbon on Nitrous Oxide Adsorption Performance X. Gong et al. 10.3390/su16104120
- Direct Comb Vernier Spectroscopy for Fractional Isotopic Ratio Determinations M. Siciliani de Cumis et al. 10.3390/s21175883
- Photochemical method for removing methane interference for improved gas analysis M. Polat et al. 10.5194/amt-14-8041-2021
- Characterizing the Importance of Denitrification for N2O Production in Soils Using Natural Abundance and Isotopic Labeling Techniques E. Stuchiner & J. von Fischer 10.1029/2021JG006555
- Soil gas probes for monitoring trace gas messengers of microbial activity J. Roscioli et al. 10.1038/s41598-021-86930-8
- Isotopomeric Peak Assignment for N2O in Cross-Labeling Experiments by Fiber-Enhanced Raman Multigas Spectroscopy A. Blohm et al. 10.1021/acs.analchem.3c04236
- The influence of tillage and fertilizer on the flux and source of nitrous oxide with reference to atmospheric variation using laser spectroscopy P. Ostrom et al. 10.1007/s10533-020-00742-y
- Mid-infrared supermirrors with finesse exceeding 400 000 G. Truong et al. 10.1038/s41467-023-43367-z
- A field system for measuring plant and soil carbon fluxes using stable isotope methods C. McCloskey et al. 10.1111/ejss.13016
- Tunable diode laser absorption spectroscopy for gas detection with a negative curvature anti-resonant hollow-core fiber K. Chai et al. 10.1016/j.optcom.2024.131278
- Global Research Alliance N2O chamber methodology guidelines: Considerations for automated flux measurement P. Grace et al. 10.1002/jeq2.20124
- Ideas and perspectives: A strategic assessment of methane and nitrous oxide measurements in the marine environment S. Wilson et al. 10.5194/bg-17-5809-2020
- Tracing N2O formation in full-scale wastewater treatment with natural abundance isotopes indicates control by organic substrate and process settings W. Gruber et al. 10.1016/j.wroa.2022.100130
- Nitrous Oxide Is No Laughing Matter: A Historical Review of Nitrous Oxide Gas-Sensing Capabilities Highlighting the Need for Further Exploration J. Milam-Guerrero et al. 10.1021/acssensors.2c01275
- Assessing nitrous oxide (N2O) isotopic analyzer performance for in-field use J. Francis Clar & R. Anex 10.1016/j.agrformet.2022.108855
- Multi-parameter methane measurement using near-infrared tunable diode laser absorption spectroscopy based on back propagation neural network Y. Li et al. 10.1016/j.infrared.2022.104275
- Recommendations on the measurement techniques of atmospheric pollutants from in situ and satellite observations: a review M. Rahman 10.1007/s12517-023-11410-4
- Doppler-free two-photon cavity ring-down spectroscopy of a nitrous oxide ( N2O ) vibrational overtone transition G. Zhao et al. 10.1103/PhysRevA.101.062509
33 citations as recorded by crossref.
- Utilizing Novel Field and Data Exploration Methods to Explore Hot Moments in High-Frequency Soil Nitrous Oxide Emissions Data: Opportunities and Challenges C. O’Connell et al. 10.3389/ffgc.2022.674348
- Development and verification of a novel isotopic N2O measurement technique for discrete static chamber samples using cavity ring‐down spectroscopy C. Bracken et al. 10.1002/rcm.9049
- Low N2O and variable CH4 fluxes from tropical forest soils of the Congo Basin M. Barthel et al. 10.1038/s41467-022-27978-6
- Precision Spectroscopy of Nitrous Oxide Isotopocules with a Cross-Dispersed Spectrometer and a Mid-Infrared Frequency Comb D. Bailey et al. 10.1021/acs.analchem.0c01868
- CleanEx: A Versatile Automated Methane Preconcentration Device for High-Precision Analysis of 13CH4, 12CH3D, and 13CH3D I. Prokhorov & J. Mohn 10.1021/acs.analchem.2c01949
- Primings of soil organic matter and denitrification mediate the effects of moisture on nitrous oxide production S. Thilakarathna & G. Hernandez-Ramirez 10.1016/j.soilbio.2021.108166
- A decision support tool for the selection of 15 N analysis methods of ammonium and nitrate M. Jia et al. 10.1007/s10705-022-10227-z
- Bacterial denitrification drives elevated N 2 O emissions in arid southern California drylands A. Krichels et al. 10.1126/sciadv.adj1989
- An approach for calibrating laser‐based N2O isotopic analyzers for soil biogeochemistry research E. Stuchiner et al. 10.1002/rcm.8978
- What can we learn from N2O isotope data? – Analytics, processes and modelling L. Yu et al. 10.1002/rcm.8858
- Simultaneous measurement of δ13C, δ18O and δ17O of atmospheric CO2 – performance assessment of a dual-laser absorption spectrometer P. Steur et al. 10.5194/amt-14-4279-2021
- Tracing plant–environment interactions from organismal to planetary scales using stable isotopes: a mini review J. Jez et al. 10.1042/ETLS20200277
- Smaller Aerobic Granules Significantly Reduce N2O Production by Ammonia-Oxidizing Bacteria: Evidences from Biochemical and Isotopic Analyses Y. Liu et al. 10.1021/acs.est.3c06246
- Characterisation of gas reference materials for underpinning atmospheric measurements of stable isotopes of nitrous oxide R. Hill-Pearce et al. 10.5194/amt-14-5447-2021
- Simultaneous 15N Online Analysis in NH4+, NO2–, NO3–, and N2O to Trace N2O Production Pathways in Nitrogen-Polluted Aqueous Environments K. Huang et al. 10.1021/acsestwater.3c00216
- Recent Progress in Cutting-edge Monitoring Tools for Microbiomes in Engineered Systems A. TERADA et al. 10.2965/jswe.45.91
- MULTICHARME: a modified Chernin-type multi-pass cell designed for IR and THz long-path absorption measurements in the CHARME atmospheric simulation chamber J. Decker et al. 10.5194/amt-15-1201-2022
- Effect of Physico-Chemical Properties Induced by N, P Co-Doped Biomass Porous Carbon on Nitrous Oxide Adsorption Performance X. Gong et al. 10.3390/su16104120
- Direct Comb Vernier Spectroscopy for Fractional Isotopic Ratio Determinations M. Siciliani de Cumis et al. 10.3390/s21175883
- Photochemical method for removing methane interference for improved gas analysis M. Polat et al. 10.5194/amt-14-8041-2021
- Characterizing the Importance of Denitrification for N2O Production in Soils Using Natural Abundance and Isotopic Labeling Techniques E. Stuchiner & J. von Fischer 10.1029/2021JG006555
- Soil gas probes for monitoring trace gas messengers of microbial activity J. Roscioli et al. 10.1038/s41598-021-86930-8
- Isotopomeric Peak Assignment for N2O in Cross-Labeling Experiments by Fiber-Enhanced Raman Multigas Spectroscopy A. Blohm et al. 10.1021/acs.analchem.3c04236
- The influence of tillage and fertilizer on the flux and source of nitrous oxide with reference to atmospheric variation using laser spectroscopy P. Ostrom et al. 10.1007/s10533-020-00742-y
- Mid-infrared supermirrors with finesse exceeding 400 000 G. Truong et al. 10.1038/s41467-023-43367-z
- A field system for measuring plant and soil carbon fluxes using stable isotope methods C. McCloskey et al. 10.1111/ejss.13016
- Tunable diode laser absorption spectroscopy for gas detection with a negative curvature anti-resonant hollow-core fiber K. Chai et al. 10.1016/j.optcom.2024.131278
- Global Research Alliance N2O chamber methodology guidelines: Considerations for automated flux measurement P. Grace et al. 10.1002/jeq2.20124
- Ideas and perspectives: A strategic assessment of methane and nitrous oxide measurements in the marine environment S. Wilson et al. 10.5194/bg-17-5809-2020
- Tracing N2O formation in full-scale wastewater treatment with natural abundance isotopes indicates control by organic substrate and process settings W. Gruber et al. 10.1016/j.wroa.2022.100130
- Nitrous Oxide Is No Laughing Matter: A Historical Review of Nitrous Oxide Gas-Sensing Capabilities Highlighting the Need for Further Exploration J. Milam-Guerrero et al. 10.1021/acssensors.2c01275
- Assessing nitrous oxide (N2O) isotopic analyzer performance for in-field use J. Francis Clar & R. Anex 10.1016/j.agrformet.2022.108855
- Multi-parameter methane measurement using near-infrared tunable diode laser absorption spectroscopy based on back propagation neural network Y. Li et al. 10.1016/j.infrared.2022.104275
2 citations as recorded by crossref.
- Recommendations on the measurement techniques of atmospheric pollutants from in situ and satellite observations: a review M. Rahman 10.1007/s12517-023-11410-4
- Doppler-free two-photon cavity ring-down spectroscopy of a nitrous oxide ( N2O ) vibrational overtone transition G. Zhao et al. 10.1103/PhysRevA.101.062509
Latest update: 08 May 2025
Short summary
The latest commercial laser spectrometers have the potential to revolutionize N2O isotope analysis. However, to do so, they must be able to produce trustworthy data. Here, we test the performance of widely used laser spectrometers for ambient air applications and identify instrument-specific dependencies on gas matrix and trace gas concentrations. We then provide a calibration workflow to facilitate the operation of these instruments in order to generate reproducible and accurate data.
The latest commercial laser spectrometers have the potential to revolutionize N2O isotope...
