Articles | Volume 13, issue 5
https://doi.org/10.5194/amt-13-2797-2020
https://doi.org/10.5194/amt-13-2797-2020
Research article
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28 May 2020
Research article | Highlight paper |  | 28 May 2020

N2O isotopocule measurements using laser spectroscopy: analyzer characterization and intercomparison

Stephen J. Harris, Jesper Liisberg, Longlong Xia, Jing Wei, Kerstin Zeyer, Longfei Yu, Matti Barthel, Benjamin Wolf, Bryce F. J. Kelly, Dioni I. Cendón, Thomas Blunier, Johan Six, and Joachim Mohn

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Cited articles

ABB-Los Gatos Research Inc.: Off-Axis Integrated Cavity Output Spectroscopy (OA-ICOS), available at: http://www.lgrinc.com/advantages/, last access: 15 August 2019. 
Allan, D. W.: Statistics of atomic frequency standards, P. IEEE, 54, 221–230, 1966. 
Assan, S., Baudic, A., Guemri, A., Ciais, P., Gros, V., and Vogel, F. R.: Characterization of interferences to in situ observations of δ13CH4 and C2H6 when using a cavity ring-down spectrometer at industrial sites, Atmos. Meas. Tech., 10, 2077–2091, https://doi.org/10.5194/amt-10-2077-2017, 2017. 
Baer, D. S., Paul, J. B., Gupta, M., and O'Keefe, A.: Sensitive absorption measurements in the near-infrared region using off-axis integrated-cavity-output spectroscopy, Appl. Phys. B-Lasers O., 75, 261–265, https://doi.org/10.1007/s00340-002-0971-z, 2002. 
Baggs, E. M.: A review of stable isotope techniques for N2O source partitioning in soils: recent progress, remaining challenges and future considerations, Rapid Commun. Mass Sp., 22, 1664–1672, https://doi.org/10.1002/rcm.3456, 2008. 
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Short summary
The latest commercial laser spectrometers have the potential to revolutionize N2O isotope analysis. However, to do so, they must be able to produce trustworthy data. Here, we test the performance of widely used laser spectrometers for ambient air applications and identify instrument-specific dependencies on gas matrix and trace gas concentrations. We then provide a calibration workflow to facilitate the operation of these instruments in order to generate reproducible and accurate data.