Articles | Volume 13, issue 10
https://doi.org/10.5194/amt-13-5667-2020
https://doi.org/10.5194/amt-13-5667-2020
Research article
 | 
26 Oct 2020
Research article |  | 26 Oct 2020

A new method to correct the electrochemical concentration cell (ECC) ozonesonde time response and its implications for “background current” and pump efficiency

Holger Vömel, Herman G. J. Smit, David Tarasick, Bryan Johnson, Samuel J. Oltmans, Henry Selkirk, Anne M. Thompson, Ryan M. Stauffer, Jacquelyn C. Witte, Jonathan Davies, Roeland van Malderen, Gary A. Morris, Tatsumi Nakano, and Rene Stübi

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Latest update: 04 Mar 2024
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Short summary
The time response of electrochemical concentration cell (ECC) ozonesondes points to at least two distinct reaction pathways with time constants of approximately 20 s and 25 min. Properly considering these time constants eliminates the need for a poorly defined "background" and allows reducing ad hoc corrections based on laboratory tests. This reduces the uncertainty of ECC ozonesonde measurements throughout the profile and especially in regions of low ozone and strong gradients of ozone.