Articles | Volume 13, issue 11
https://doi.org/10.5194/amt-13-5873-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-13-5873-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
06 Nov 2020
Research article |
| 06 Nov 2020
| 06 Nov 2020
A portable, robust, stable, and tunable calibration source for gas-phase nitrous acid (HONO)
Melodie Lao
Department of Chemistry, York University, Toronto, ON, Canada
Leigh R. Crilley
Department of Chemistry, York University, Toronto, ON, Canada
Leyla Salehpoor
Department of Chemistry, York University, Toronto, ON, Canada
Teles C. Furlani
Department of Chemistry, York University, Toronto, ON, Canada
Ilann Bourgeois
NOAA Chemical Sciences Laboratory, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
J. Andrew Neuman
NOAA Chemical Sciences Laboratory, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Andrew W. Rollins
NOAA Chemical Sciences Laboratory, Boulder, CO, USA
Patrick R. Veres
NOAA Chemical Sciences Laboratory, Boulder, CO, USA
Rebecca A. Washenfelder
NOAA Chemical Sciences Laboratory, Boulder, CO, USA
Caroline C. Womack
NOAA Chemical Sciences Laboratory, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Cora J. Young
Department of Chemistry, York University, Toronto, ON, Canada
Department of Chemistry, York University, Toronto, ON, Canada
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Cited
14 citations as recorded by crossref.
- Widespread formation of toxic nitrated bisphenols indoors by heterogeneous reactions with HONO D. Yang et al. 10.1126/sciadv.abq7023
- Comparison of two photolytic calibration methods for nitrous acid A. Lindsay & E. Wood 10.5194/amt-15-5455-2022
- HONO Measurement by Catalytic Conversion to NO on Nafion Surfaces Z. Payne et al. 10.1021/acs.est.2c05944
- Comparison of airborne measurements of NO, NO2, HONO, NOy, and CO during FIREX-AQ I. Bourgeois et al. 10.5194/amt-15-4901-2022
- Development of a laser-photofragmentation laser-induced fluorescence instrument for the detection of nitrous acid and hydroxyl radicals in the atmosphere B. Bottorff et al. 10.5194/amt-14-6039-2021
- Development and validation of a new in situ technique to measure total gaseous chlorine in air T. Furlani et al. 10.5194/amt-16-181-2023
- Avoiding Regrettable Replacements: Can the Introduction of Novel Functional Groups Move PFAS from Recalcitrant to Reactive? A. Folkerson et al. 10.1021/acs.est.3c06232
- Emerging investigator series: an instrument to measure and speciate the total reactive nitrogen budget indoors: description and field measurements L. Crilley et al. 10.1039/D2EM00446A
- Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical between 314 and 433 K E. Assaf et al. 10.1021/acs.jpca.2c09095
- Key Role of Equilibrium HONO Concentration over Soil in Quantifying Soil–Atmosphere HONO Fluxes F. Bao et al. 10.1021/acs.est.1c06716
- Validation of a new cavity ring-down spectrometer for measuring tropospheric gaseous hydrogen chloride T. Furlani et al. 10.5194/amt-14-5859-2021
- Atmospheric Fate of a New Polyfluoroalkyl Building Block, C3F7OCHFCF2SCH2CH2OH S. Joudan et al. 10.1021/acs.est.0c07584
- A source for the continuous generation of pure and quantifiable HONO mixtures G. Villena & J. Kleffmann 10.5194/amt-15-627-2022
- A boron dipyrromethene (BODIPY) based probe for selective passive sampling of atmospheric nitrous acid (HONO) indoors D. Nodeh-Farahani et al. 10.1039/D1AN01089A
14 citations as recorded by crossref.
- Widespread formation of toxic nitrated bisphenols indoors by heterogeneous reactions with HONO D. Yang et al. 10.1126/sciadv.abq7023
- Comparison of two photolytic calibration methods for nitrous acid A. Lindsay & E. Wood 10.5194/amt-15-5455-2022
- HONO Measurement by Catalytic Conversion to NO on Nafion Surfaces Z. Payne et al. 10.1021/acs.est.2c05944
- Comparison of airborne measurements of NO, NO2, HONO, NOy, and CO during FIREX-AQ I. Bourgeois et al. 10.5194/amt-15-4901-2022
- Development of a laser-photofragmentation laser-induced fluorescence instrument for the detection of nitrous acid and hydroxyl radicals in the atmosphere B. Bottorff et al. 10.5194/amt-14-6039-2021
- Development and validation of a new in situ technique to measure total gaseous chlorine in air T. Furlani et al. 10.5194/amt-16-181-2023
- Avoiding Regrettable Replacements: Can the Introduction of Novel Functional Groups Move PFAS from Recalcitrant to Reactive? A. Folkerson et al. 10.1021/acs.est.3c06232
- Emerging investigator series: an instrument to measure and speciate the total reactive nitrogen budget indoors: description and field measurements L. Crilley et al. 10.1039/D2EM00446A
- Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical between 314 and 433 K E. Assaf et al. 10.1021/acs.jpca.2c09095
- Key Role of Equilibrium HONO Concentration over Soil in Quantifying Soil–Atmosphere HONO Fluxes F. Bao et al. 10.1021/acs.est.1c06716
- Validation of a new cavity ring-down spectrometer for measuring tropospheric gaseous hydrogen chloride T. Furlani et al. 10.5194/amt-14-5859-2021
- Atmospheric Fate of a New Polyfluoroalkyl Building Block, C3F7OCHFCF2SCH2CH2OH S. Joudan et al. 10.1021/acs.est.0c07584
- A source for the continuous generation of pure and quantifiable HONO mixtures G. Villena & J. Kleffmann 10.5194/amt-15-627-2022
- A boron dipyrromethene (BODIPY) based probe for selective passive sampling of atmospheric nitrous acid (HONO) indoors D. Nodeh-Farahani et al. 10.1039/D1AN01089A
Discussed (final revised paper)
Latest update: 19 Apr 2024
Short summary
Nitrous acid (HONO) is a key intermediate in the generation of oxidants and fate of nitrogen oxides in the atmosphere. High-purity calibration sources that produce stable atmospherically relevant levels under field conditions have not been made to date, reducing measurement accuracy. In this study a simple salt-coated tube humidified with water vapor is demonstrated to produce pure stable low levels of HONO, with modifications allowing the generation of higher amounts.
Nitrous acid (HONO) is a key intermediate in the generation of oxidants and fate of nitrogen...
