Articles | Volume 13, issue 11
https://doi.org/10.5194/amt-13-6311-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-13-6311-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
25 Nov 2020
Research article |
| 25 Nov 2020
| 25 Nov 2020
Implementation of an incoherent broadband cavity-enhanced absorption spectroscopy technique in an atmospheric simulation chamber for in situ NO3 monitoring: characterization and validation for kinetic studies
Axel Fouqueau
LISA, UMR CNRS 7583, Université Paris-Est Créteil,
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil, France
Manuela Cirtog
CORRESPONDING AUTHOR
LISA, UMR CNRS 7583, Université Paris-Est Créteil,
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil, France
Mathieu Cazaunau
LISA, UMR CNRS 7583, Université Paris-Est Créteil,
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil, France
Edouard Pangui
LISA, UMR CNRS 7583, Université Paris-Est Créteil,
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil, France
Pascal Zapf
LISA, UMR CNRS 7583, Université Paris-Est Créteil,
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil, France
Guillaume Siour
LISA, UMR CNRS 7583, Université Paris-Est Créteil,
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil, France
Xavier Landsheere
LISA, UMR CNRS 7583, Université Paris-Est Créteil,
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil, France
Guillaume Méjean
LIPHY, UMR CNRS 5588, Université Grenoble Alpes, Grenoble, France
Daniele Romanini
LIPHY, UMR CNRS 5588, Université Grenoble Alpes, Grenoble, France
Bénédicte Picquet-Varrault
LISA, UMR CNRS 7583, Université Paris-Est Créteil,
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil, France
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Cited
12 citations as recorded by crossref.
- Techniques for measuring indoor radicals and radical precursors E. Alvarez et al. 10.1080/05704928.2022.2087666
- Detecting and Characterizing Particulate Organic Nitrates with an Aerodyne Long-ToF Aerosol Mass Spectrometer F. Graeffe et al. 10.1021/acsearthspacechem.2c00314
- An experimental study of the reactivity of terpinolene and β-caryophyllene with the nitrate radical A. Fouqueau et al. 10.5194/acp-22-6411-2022
- Individual quantification of ozone and reactive nitrogen species in mixtures by broadband UV–visible absorption spectra deconvolution S. Huh et al. 10.1088/1361-6595/ad5ebb
- Secondary aerosol formation during the dark oxidation of residential biomass burning emissions J. Kodros et al. 10.1039/D2EA00031H
- A comparative and experimental study of the reactivity with nitrate radical of two terpenes: α-terpinene and γ-terpinene A. Fouqueau et al. 10.5194/acp-20-15167-2020
- Detection of nitrous acid in the atmospheric simulation chamber SAPHIR using open-path incoherent broadband cavity-enhanced absorption spectroscopy and extractive long-path absorption photometry S. Dixneuf et al. 10.5194/amt-15-945-2022
- Development of a broadband cavity-enhanced absorption spectrometer for simultaneous measurements of ambient NO3, NO2, and H2O W. Nam et al. 10.5194/amt-15-4473-2022
- Simulation of organic aerosol, its precursors, and related oxidants in the Landes pine forest in southwestern France: accounting for domain-specific land use and physical conditions A. Cholakian et al. 10.5194/acp-23-3679-2023
- Nitrate radical generation via continuous generation of dinitrogen pentoxide in a laminar flow reactor coupled to an oxidation flow reactor A. Lambe et al. 10.5194/amt-13-2397-2020
- Nighttime chemistry of biomass burning emissions in urban areas: A dual mobile chamber study S. Jorga et al. 10.5194/acp-21-15337-2021
- Nitrate radical generation via continuous generation of dinitrogen pentoxide in a laminar flow reactor coupled to an oxidation flow reactor A. Lambe et al. 10.5194/amt-13-2397-2020
11 citations as recorded by crossref.
- Techniques for measuring indoor radicals and radical precursors E. Alvarez et al. 10.1080/05704928.2022.2087666
- Detecting and Characterizing Particulate Organic Nitrates with an Aerodyne Long-ToF Aerosol Mass Spectrometer F. Graeffe et al. 10.1021/acsearthspacechem.2c00314
- An experimental study of the reactivity of terpinolene and β-caryophyllene with the nitrate radical A. Fouqueau et al. 10.5194/acp-22-6411-2022
- Individual quantification of ozone and reactive nitrogen species in mixtures by broadband UV–visible absorption spectra deconvolution S. Huh et al. 10.1088/1361-6595/ad5ebb
- Secondary aerosol formation during the dark oxidation of residential biomass burning emissions J. Kodros et al. 10.1039/D2EA00031H
- A comparative and experimental study of the reactivity with nitrate radical of two terpenes: α-terpinene and γ-terpinene A. Fouqueau et al. 10.5194/acp-20-15167-2020
- Detection of nitrous acid in the atmospheric simulation chamber SAPHIR using open-path incoherent broadband cavity-enhanced absorption spectroscopy and extractive long-path absorption photometry S. Dixneuf et al. 10.5194/amt-15-945-2022
- Development of a broadband cavity-enhanced absorption spectrometer for simultaneous measurements of ambient NO3, NO2, and H2O W. Nam et al. 10.5194/amt-15-4473-2022
- Simulation of organic aerosol, its precursors, and related oxidants in the Landes pine forest in southwestern France: accounting for domain-specific land use and physical conditions A. Cholakian et al. 10.5194/acp-23-3679-2023
- Nitrate radical generation via continuous generation of dinitrogen pentoxide in a laminar flow reactor coupled to an oxidation flow reactor A. Lambe et al. 10.5194/amt-13-2397-2020
- Nighttime chemistry of biomass burning emissions in urban areas: A dual mobile chamber study S. Jorga et al. 10.5194/acp-21-15337-2021
Latest update: 21 Feb 2025
Short summary
An incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) technique has been developed for the in situ monitoring of NO3 radicals in the CSA simulation chamber at LISA. The optical cavity allows a high sensitivity for NO3 detection up to 6 ppt for an integration time of 10 s. The technique is now fully operational and can be used to determine rate constants for fast reactions involving complex volatile organic compounds (with rate constants up to 10−10 cm3 molecule−1 s−1).
An incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) technique has been...
