Articles | Volume 14, issue 5
https://doi.org/10.5194/amt-14-3693-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-14-3693-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Estimation of particulate organic nitrates from thermodenuder–aerosol mass spectrometer measurements in the North China Plain
Weiqi Xu
State Key Laboratory of Atmospheric Boundary Layer Physics and
Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of
Sciences, Beijing 100029, China
Masayuki Takeuchi
School of Civil and Environmental Engineering, Georgia Institute of
Technology, Atlanta, GA 30332, USA
Chun Chen
State Key Laboratory of Atmospheric Boundary Layer Physics and
Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of
Sciences, Beijing 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
Yanmei Qiu
State Key Laboratory of Atmospheric Boundary Layer Physics and
Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of
Sciences, Beijing 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
Conghui Xie
State Key Laboratory of Atmospheric Boundary Layer Physics and
Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of
Sciences, Beijing 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
now at: State Key Joint Laboratory of Environmental Simulation and
Pollution Control, College of Environmental Sciences and Engineering, Peking
University, Beijing 100871, China
Wanyun Xu
State Key Laboratory of Severe Weather & Key Laboratory for
Atmospheric Chemistry, Institute of Atmospheric Composition, Chinese Academy
of Meteorological Sciences, Beijing 100081, China
Nan Ma
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Douglas R. Worsnop
Aerodyne Research Inc., Billerica, MA 01821, USA
School of Civil and Environmental Engineering, Georgia Institute of
Technology, Atlanta, GA 30332, USA
School of Earth and Atmospheric Sciences, Georgia Institute of
Technology, Atlanta, GA 30332, USA
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA
State Key Laboratory of Atmospheric Boundary Layer Physics and
Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of
Sciences, Beijing 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
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19 citations as recorded by crossref.
- A systematic re-evaluation of methods for quantification of bulk particle-phase organic nitrates using real-time aerosol mass spectrometry D. Day et al. 10.5194/amt-15-459-2022
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al. 10.1038/s41467-022-35546-1
- Enhanced formation of nitrogenous organic aerosols and brown carbon after aging in the planetary boundary layer Y. Wu et al. 10.1038/s41612-024-00726-x
- New measurements reveal a large contribution of nitrogenous molecules to ambient organic aerosol X. Yu et al. 10.1038/s41612-024-00620-6
- First Online Observation of Aerosol Total Organic Nitrogen at an Urban Site: Insights Into the Emission Sources and Formation Pathways of Nitrogenous Organic Aerosols X. Yu et al. 10.1029/2023JD038921
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al. 10.1016/j.atmosres.2024.107586
- Primary and Secondary Organic Nitrate in Northwest China: A Case Study C. Lin et al. 10.1021/acs.estlett.1c00692
- Applications of environmental mass spectrometry in atmospheric haze chemistry T. Chen et al. 10.1016/j.trac.2024.117614
- Long-term study of chemical characteristics of aerosol compositions in the rural environment of Rūgšteliškis (Lithuania) T. Gill et al. 10.1016/j.apr.2024.102048
- Evaluating the response of the Aerodyne aerosol mass spectrometer to monoterpene- and isoprene-derived organic nitrate standards M. Takeuchi et al. 10.1080/02786826.2024.2389183
- Secondary Brown Carbon Formation From Photooxidation of Furans From Biomass Burning T. Joo et al. 10.1029/2023GL104900
- The Impact of Agroecosystems on Nitrous Acid (HONO) Emissions during Spring and Autumn in the North China Plain J. Zeng et al. 10.3390/toxics12050331
- A comprehensive evaluation of enhanced temperature influence on gas and aerosol chemistry in the lamp-enclosed oxidation flow reactor (OFR) system T. Pan et al. 10.5194/amt-17-4915-2024
- Insights into characteristics and formation mechanisms of secondary organic aerosols in the Guangzhou urban area M. Zhai et al. 10.5194/acp-23-5119-2023
- Characterization of particulate organic nitrates in the Yangtze River Delta, East China, using the time-of-flight aerosol chemical speciation monitor D. Ge et al. 10.1016/j.atmosenv.2021.118927
- Severe photochemical pollution formation associated with strong HONO emissions from dew and guttation evaporation W. Xu et al. 10.1016/j.scitotenv.2023.169309
- Contribution of Organic Nitrates to Organic Aerosol over South Korea during KORUS-AQ H. Kenagy et al. 10.1021/acs.est.1c05521
- Organic aerosol volatility and viscosity in the North China Plain: contrast between summer and winter W. Xu et al. 10.5194/acp-21-5463-2021
17 citations as recorded by crossref.
- A systematic re-evaluation of methods for quantification of bulk particle-phase organic nitrates using real-time aerosol mass spectrometry D. Day et al. 10.5194/amt-15-459-2022
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al. 10.1038/s41467-022-35546-1
- Enhanced formation of nitrogenous organic aerosols and brown carbon after aging in the planetary boundary layer Y. Wu et al. 10.1038/s41612-024-00726-x
- New measurements reveal a large contribution of nitrogenous molecules to ambient organic aerosol X. Yu et al. 10.1038/s41612-024-00620-6
- First Online Observation of Aerosol Total Organic Nitrogen at an Urban Site: Insights Into the Emission Sources and Formation Pathways of Nitrogenous Organic Aerosols X. Yu et al. 10.1029/2023JD038921
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al. 10.1016/j.atmosres.2024.107586
- Primary and Secondary Organic Nitrate in Northwest China: A Case Study C. Lin et al. 10.1021/acs.estlett.1c00692
- Applications of environmental mass spectrometry in atmospheric haze chemistry T. Chen et al. 10.1016/j.trac.2024.117614
- Long-term study of chemical characteristics of aerosol compositions in the rural environment of Rūgšteliškis (Lithuania) T. Gill et al. 10.1016/j.apr.2024.102048
- Evaluating the response of the Aerodyne aerosol mass spectrometer to monoterpene- and isoprene-derived organic nitrate standards M. Takeuchi et al. 10.1080/02786826.2024.2389183
- Secondary Brown Carbon Formation From Photooxidation of Furans From Biomass Burning T. Joo et al. 10.1029/2023GL104900
- The Impact of Agroecosystems on Nitrous Acid (HONO) Emissions during Spring and Autumn in the North China Plain J. Zeng et al. 10.3390/toxics12050331
- A comprehensive evaluation of enhanced temperature influence on gas and aerosol chemistry in the lamp-enclosed oxidation flow reactor (OFR) system T. Pan et al. 10.5194/amt-17-4915-2024
- Insights into characteristics and formation mechanisms of secondary organic aerosols in the Guangzhou urban area M. Zhai et al. 10.5194/acp-23-5119-2023
- Characterization of particulate organic nitrates in the Yangtze River Delta, East China, using the time-of-flight aerosol chemical speciation monitor D. Ge et al. 10.1016/j.atmosenv.2021.118927
- Severe photochemical pollution formation associated with strong HONO emissions from dew and guttation evaporation W. Xu et al. 10.1016/j.scitotenv.2023.169309
2 citations as recorded by crossref.
Latest update: 22 Nov 2024
Short summary
Here we developed a method for estimation of particulate organic nitrates (pON) from the measurements of a high-resolution aerosol mass spectrometer coupled with a thermodenuder based on the volatility differences between inorganic nitrate and pON. The results generally had improvements in reducing negative values due to the influences of a high concentration of inorganic nitrate and a constant ratio of NO+ to NO2+ of organic nitrates (RON).
Here we developed a method for estimation of particulate organic nitrates (pON) from the...