Estimation of sulfuric acid concentration using ambient ion composition and concentration data obtained with atmospheric pressure interface time-of-flight ion mass spectrometer
Lisa J. Beck,Siegfried Schobesberger,Mikko Sipilä,Veli-Matti Kerminen,and Markku Kulmala
Institute for Atmospheric and Earth System Research/Physics,
University of Helsinki, 00014 Helsinki, Finland
Aerosol and Haze Laboratory, Beijing Advanced Innovation Center for
Soft Matter Sciences and Engineering,Beijing University of Chemical
Technology (BUCT), Beijing, China
Joint International Research Laboratory of Atmospheric and Earth
System Sciences, School of Atmospheric Sciences, Nanjing University,
Nanjing, China
Viewed
Total article views: 3,787 (including HTML, PDF, and XML)
HTML
PDF
XML
Total
BibTeX
EndNote
2,665
1,033
89
3,787
114
124
HTML: 2,665
PDF: 1,033
XML: 89
Total: 3,787
BibTeX: 114
EndNote: 124
Views and downloads (calculated since 13 Sep 2021)
Cumulative views and downloads
(calculated since 13 Sep 2021)
Total article views: 2,473 (including HTML, PDF, and XML)
HTML
PDF
XML
Total
BibTeX
EndNote
1,713
699
61
2,473
99
106
HTML: 1,713
PDF: 699
XML: 61
Total: 2,473
BibTeX: 99
EndNote: 106
Views and downloads (calculated since 31 Mar 2022)
Cumulative views and downloads
(calculated since 31 Mar 2022)
Total article views: 1,314 (including HTML, PDF, and XML)
HTML
PDF
XML
Total
BibTeX
EndNote
952
334
28
1,314
15
18
HTML: 952
PDF: 334
XML: 28
Total: 1,314
BibTeX: 15
EndNote: 18
Views and downloads (calculated since 13 Sep 2021)
Cumulative views and downloads
(calculated since 13 Sep 2021)
Viewed (geographical distribution)
Total article views: 3,787 (including HTML, PDF, and XML)
Thereof 3,734 with geography defined
and 53 with unknown origin.
Total article views: 2,473 (including HTML, PDF, and XML)
Thereof 2,436 with geography defined
and 37 with unknown origin.
Total article views: 1,314 (including HTML, PDF, and XML)
Thereof 1,298 with geography defined
and 16 with unknown origin.
Sulfuric acid is known to be a main compound in atmospheric new particle formation. Yet, its concentration is very low, which leads to challenges in detecting it. In our study, we derive the sulfuric acid concentration from measurements of ambient ions with a mass spectrometer. Our validation shows that the theoretical approach using the bisulfate ion and its clusters with H2SO4 captures the sulfuric acid concentration very well during daytime.
Sulfuric acid is known to be a main compound in atmospheric new particle formation. Yet, its...
