Articles | Volume 16, issue 5
https://doi.org/10.5194/amt-16-1407-2023
https://doi.org/10.5194/amt-16-1407-2023
Research article
 | 
16 Mar 2023
Research article |  | 16 Mar 2023

Using tunable infrared laser direct absorption spectroscopy for ambient hydrogen chloride detection: HCl-TILDAS

John W. Halfacre, Jordan Stewart, Scott C. Herndon, Joseph R. Roscioli, Christoph Dyroff, Tara I. Yacovitch, Michael Flynn, Stephen J. Andrews, Steven S. Brown, Patrick R. Veres, and Pete M. Edwards

Data sets

Ammonia and Water Abundance Measurements from Los Gatos Research Ammonia Analyzer Instrument at Manchester Air Quality Site 2019-22 N. Watson https://catalogue.ceda.ac.uk/uuid/5fc811f707f54415b129882a38889501

Nitrogen Dioxide Abundance Data from Teledyne Model T500U Instrument at the Manchester Air Quality Site N. Watson https://catalogue.ceda.ac.uk/uuid/f60761f3279042859e5c2902dfa0f2ef

NO and NOy Abundance Data from Thermo Model 42i-Y NOY Analyzer Instrument at the Manchester Air Quality Site N. Watson https://catalogue.ceda.ac.uk/uuid/1d58f2f5e7874e55a83ca57311dcfb9a

ClearfLo: IOP Summer Atmospheric Chemistry and meteorology measurements and NAME Airmass Footprint dispersion model output at North Kensington, London B. Bandy, K. Faloon, E. Finessi, J. D. Lee, R. J. Leigh, D. Liu, P. S. Monks, D. E. Oram, S. Visser, J. Whitehead, and D. Young https://catalogue.ceda.ac.uk/uuid/4c35e63d6507408d96e4af3dce410e3d

ClearfLo: Atmospheric Chemistry measurements and NAME Airmass Footprint dispersion model output at North Kensington, London J. D. Lee and D. Young https://catalogue.ceda.ac.uk/uuid/6a5f9eedd68f43348692b3bace3eba45

ClearfLo: IOP Winter atmospheric chemistry and meteorology measurements and NAME Airmass Footprint dispersion model output across London sites J. D. Lee, S. Herndon, P. Zotter, S. Visser, B. Bandy, D. Oram, S. Laufs, J. R. Hopkins, and Z. L. Fleming https://catalogue.ceda.ac.uk/uuid/ba8180a9876a4ef1a127046a673d8864

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Short summary
This study details a new sampling method for the optical detection of hydrogen chloride (HCl). HCl is an important atmospheric reservoir for chlorine atoms, which can affect nitrogen oxide cycling and the lifetimes of volatile organic compounds and ozone. However, HCl has a high affinity for interacting with surfaces, thereby preventing fast, quantitative measurements. The sampling technique in this study minimizes these surface interactions and provides a high-quality measurement of HCl.