Articles | Volume 16, issue 2
https://doi.org/10.5194/amt-16-355-2023
https://doi.org/10.5194/amt-16-355-2023
Research article
 | 
24 Jan 2023
Research article |  | 24 Jan 2023

Laser-induced sublimation extraction for centimeter-resolution multi-species greenhouse gas analysis on ice cores

Lars Mächler, Daniel Baggenstos, Florian Krauss, Jochen Schmitt, Bernhard Bereiter, Remo Walther, Christoph Reinhard, Béla Tuzson, Lukas Emmenegger, and Hubertus Fischer

Related authors

Sectoral attribution of greenhouse gas and pollutant emissions using multi-species eddy covariance on a tall tower in Zurich, Switzerland
Rainer Hilland, Josh Hashemi, Stavros Stagakis, Dominik Brunner, Lionel Constantin, Natascha Kljun, Betty Molinier, Samuel Hammer, Lukas Emmenegger, and Andreas Christen
EGUsphere, https://doi.org/10.5194/egusphere-2025-1088,https://doi.org/10.5194/egusphere-2025-1088, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
The ZiCOS-M CO2 sensor network: measurement performance and CO2 variability across Zurich
Stuart K. Grange, Pascal Rubli, Andrea Fischer, Dominik Brunner, Christoph Hueglin, and Lukas Emmenegger
Atmos. Chem. Phys., 25, 2781–2806, https://doi.org/10.5194/acp-25-2781-2025,https://doi.org/10.5194/acp-25-2781-2025, 2025
Short summary
Technical note: An interactive dashboard to facilitate quality control of in-situ atmospheric composition measurements
Yuri Brugnara, Martin Steinbacher, Simone Baffelli, and Lukas Emmenegger
EGUsphere, https://doi.org/10.5194/egusphere-2024-3556,https://doi.org/10.5194/egusphere-2024-3556, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Evidence of successful methane mitigation in one of Europe's most important oil production region
Gerrit Kuhlmann, Foteini Stavropoulou, Stefan Schwietzke, Daniel Zavala-Araiza, Andrew Thorpe, Andreas Hueni, Lukas Emmenegger, Andreea Calcan, Thomas Röckmann, and Dominik Brunner
EGUsphere, https://doi.org/10.5194/egusphere-2024-3494,https://doi.org/10.5194/egusphere-2024-3494, 2024
Short summary
Brief communication: RADIX (Rapid Access Drilling and Ice eXtraction) dust logger test in the EastGRIP (East Greenland Ice-core Project) hole
Jakob Schwander, Thomas F. Stocker, Remo Walther, Samuel Marending, Tobias Erhardt, Chantal Zeppenfeld, and Jürg Jost
The Cryosphere, 18, 5613–5617, https://doi.org/10.5194/tc-18-5613-2024,https://doi.org/10.5194/tc-18-5613-2024, 2024
Short summary

Related subject area

Subject: Gases | Technique: Laboratory Measurement | Topic: Instruments and Platforms
Product ion distributions using H3O+ proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS): mechanisms, transmission effects, and instrument-to-instrument variability
Michael F. Link, Megan S. Claflin, Christina E. Cecelski, Ayomide A. Akande, Delaney Kilgour, Paul A. Heine, Matthew Coggon, Chelsea E. Stockwell, Andrew Jensen, Jie Yu, Han N. Huynh, Jenna C. Ditto, Carsten Warneke, William Dresser, Keighan Gemmell, Spiro Jorga, Rileigh L. Robertson, Joost de Gouw, Timothy Bertram, Jonathan P. D. Abbatt, Nadine Borduas-Dedekind, and Dustin Poppendieck
Atmos. Meas. Tech., 18, 1013–1038, https://doi.org/10.5194/amt-18-1013-2025,https://doi.org/10.5194/amt-18-1013-2025, 2025
Short summary
Simultaneous measurement of greenhouse gases (CH4, CO2 and N2O) using a simplified gas chromatography system
Michał Bucha, Dominika Lewicka-Szczebak, and Piotr Wójtowicz
Atmos. Meas. Tech., 18, 897–908, https://doi.org/10.5194/amt-18-897-2025,https://doi.org/10.5194/amt-18-897-2025, 2025
Short summary
A new portable sampler of atmospheric methane for radiocarbon measurements
Giulia Zazzeri, Lukas Wacker, Negar Haghipour, Philip Gautschi, Thomas Laemmel, Sönke Szidat, and Heather Graven
Atmos. Meas. Tech., 18, 319–325, https://doi.org/10.5194/amt-18-319-2025,https://doi.org/10.5194/amt-18-319-2025, 2025
Short summary
Influence of ambient NO and NO2 on the quantification of total peroxy nitrates (∑PNs) and total alkyl nitrates (∑ANs) by thermal dissociation cavity ring-down spectroscopy (TD-CRDS)
Laura Wüst, Patrick Dewald, Gunther N. T. E. Türk, Jos Lelieveld, and John N. Crowley
EGUsphere, https://doi.org/10.5194/egusphere-2024-3694,https://doi.org/10.5194/egusphere-2024-3694, 2024
Short summary
High-precision oxygen isotope (δ18O) measurements of atmospheric dioxygen using optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS)
Clément Piel, Daniele Romanini, Morgane Farradèche, Justin Chaillot, Clémence Paul, Nicolas Bienville, Thomas Lauwers, Joana Sauze, Kévin Jaulin, Frédéric Prié, and Amaëlle Landais
Atmos. Meas. Tech., 17, 6647–6658, https://doi.org/10.5194/amt-17-6647-2024,https://doi.org/10.5194/amt-17-6647-2024, 2024
Short summary

Cited articles

Baumgartner, M., Kindler, P., Eicher, O., Floch, G., Schilt, A., Schwander, J., Spahni, R., Capron, E., Chappellaz, J., Leuenberger, M., Fischer, H., and Stocker, T. F.: NGRIP CH4 concentration from 120 to 10 kyr before present and its relation to a δ15N temperature reconstruction from the same ice core, Clim. Past, 10, 903–920, https://doi.org/10.5194/cp-10-903-2014, 2014. a, b
Bauska, T. K., Brook, E. J., Mix, A. C., and Ross, A.: High-precision dual-inlet IRMS measurements of the stable isotopes of CO2 and the N2O / CO2 ratio from polar ice core samples, Atmos. Meas. Tech., 7, 3825–3837, https://doi.org/10.5194/amt-7-3825-2014, 2014. a
Bauska, T. K., Brook, E. J., Marcott, S. A., Baggenstos, D., Shackleton, S., Severinghaus, J. P., and Petrenko, V. V.: Controls on Millennial-Scale Atmospheric CO2 Variability During the Last Glacial Period, Geophys. Res. Lett., 45, 7731–7740, https://doi.org/10.1029/2018GL077881, 2018. a, b
Bereiter, B., Stocker, T. F., and Fischer, H.: A centrifugal ice microtome for measurements of atmospheric CO2 on air trapped in polar ice cores, Atmos. Meas. Tech., 6, 251–262, https://doi.org/10.5194/amt-6-251-2013, 2013. a
Bereiter, B., Fischer, H., Schwander, J., and Stocker, T. F.: Diffusive equilibration of N2, O2 and CO2 mixing ratios in a 1.5-million-years-old ice core, The Cryosphere, 8, 245–256, https://doi.org/10.5194/tc-8-245-2014, 2014. a
Download
Short summary
We present a new method to extract the gases from ice cores and measure their greenhouse gas composition. The ice is sublimated continuously with a near-infrared laser, releasing the gases, which are then analyzed on a laser absorption spectrometer. The main advantage over previous efforts is a low effective resolution of 1–2 cm. This capability is crucial for the analysis of highly thinned ice, as expected from ongoing drilling efforts to extend ice core history further back in time.
Share