Articles | Volume 17, issue 14
https://doi.org/10.5194/amt-17-4553-2024
https://doi.org/10.5194/amt-17-4553-2024
Research article
 | 
31 Jul 2024
Research article |  | 31 Jul 2024

Characterization of a new Teflon chamber and on-line analysis of isomeric multifunctional photooxidation products

Finja Löher, Esther Borrás, Amalia Muñoz, and Anke Christine Nölscher

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Short summary
We constructed and characterized a new indoor Teflon atmospheric simulation chamber. We evaluated wall losses, photolysis rates, and secondary reactions of multifunctional photooxidation products in the chamber. To measure these products on-line, we combined chromatographic and mass spectrometric analyses to obtain both isomeric information and a high temporal resolution. For method validation, we studied the formation yields of the main ring-retaining products of toluene.