Articles | Volume 18, issue 19
https://doi.org/10.5194/amt-18-5003-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-18-5003-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Turbulent enhancement ratios used for characterizing local emission sources in a complex urban environment
Christian Lamprecht
CORRESPONDING AUTHOR
Department of Atmospheric and Cryospheric Sciences, University of Innsbruck, Innrain 52f, Innsbruck, 6020, Austria
Martin Graus
Department of Atmospheric and Cryospheric Sciences, University of Innsbruck, Innrain 52f, Innsbruck, 6020, Austria
now at: Ionicon Analytik GmbH, Eduard-Bodem-Gasse 3, Innsbruck, 6020, Austria
Marcus Striednig
Department of Atmospheric and Cryospheric Sciences, University of Innsbruck, Innrain 52f, Innsbruck, 6020, Austria
Michael Stichaner
Department of Atmospheric and Cryospheric Sciences, University of Innsbruck, Innrain 52f, Innsbruck, 6020, Austria
Werner Jud
Department of Atmospheric and Cryospheric Sciences, University of Innsbruck, Innrain 52f, Innsbruck, 6020, Austria
Andreas Held
Institut für Technischen Umweltschutz, TU Berlin, Straße des 17. Juni 135, Berlin 10623, Germany
Department of Atmospheric and Cryospheric Sciences, University of Innsbruck, Innrain 52f, Innsbruck, 6020, Austria
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Jonas Elm, Aladár Czitrovszky, Andreas Held, Annele Virtanen, Astrid Kiendler-Scharr, Benjamin J. Murray, Daniel McCluskey, Daniele Contini, David Broday, Eirini Goudeli, Hilkka Timonen, Joan Rosell-Llompart, Jose L. Castillo, Evangelia Diapouli, Mar Viana, Maria E. Messing, Markku Kulmala, Naděžda Zíková, and Sebastian H. Schmitt
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Sihang Wang, Bin Yuan, Caihong Wu, Chaomin Wang, Tiange Li, Xianjun He, Yibo Huangfu, Jipeng Qi, Xiao-Bing Li, Qing'e Sha, Manni Zhu, Shengrong Lou, Hongli Wang, Thomas Karl, Martin Graus, Zibing Yuan, and Min Shao
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Volatile organic compound (VOC) emissions from vehicles are measured using online mass spectrometers. Differences between gasoline and diesel vehicles are observed with higher emission factors of most oxygenated VOCs (OVOCs) and heavier aromatics from diesel vehicles. A higher aromatics / toluene ratio could provide good indicators to distinguish emissions from both vehicle types. We show that OVOCs account for significant contributions to VOC emissions from vehicles, especially diesel vehicles.
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Ecosystems emit biogenic volatile organic compounds (BVOCs), which are then oxidized in the atmosphere, contributing to ozone and secondary aerosol formation. While flux measurements of BVOCs are state of the art, flux measurements of the less volatile oxidation products are difficult to achieve due to inlet losses. Here we present first flux measurements, utilizing a novel PTR3 instrument in combination with a specially designed wall-less inlet we put on top of the Hyytiälä tower in Finland.
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Arianna Peron, Lisa Kaser, Anne Charlott Fitzky, Martin Graus, Heidi Halbwirth, Jürgen Greiner, Georg Wohlfahrt, Boris Rewald, Hans Sandén, and Thomas Karl
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Drought events are expected to become more frequent with climate change. Along with these events atmospheric ozone is also expected to increase. Both can stress plants. Here we investigate to what extent these factors modulate the emission of volatile organic compounds (VOCs) from oak plants. We find an antagonistic effect between drought stress and ozone, impacting the emission of different BVOCs, which is indirectly controlled by stomatal opening, allowing plants to control their water budget.
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Short summary
Air pollution management requires accurate determination of emissions and emission ratios of air pollutants. In this paper, we explore a new way to resolve excess mixing ratios in turbulent plumes, which allows aggregation of unbiased ensemble averages of air pollutant ratios that can be compared with emission models. The approach is tested in an urban environment and used to resolve emission patterns of nitrogen oxides and carbon dioxide.
Air pollution management requires accurate determination of emissions and emission ratios of air...