Articles | Volume 19, issue 7
https://doi.org/10.5194/amt-19-2369-2026
https://doi.org/10.5194/amt-19-2369-2026
Research article
 | 
10 Apr 2026
Research article |  | 10 Apr 2026

Simultaneous measurements of near-surface CO2 and NO2 to monitor the fossil-fuel combustion-derived CO2 in the Greater Tokyo Area

Hitoshi Irie, Masataka Nomoto, Yoshikazu Kamiya, and Yukio Terao

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Cited articles

Bisht, J. S. H., Patra, P. K., Takigawa, M., Kanaya, Y., Yamaguchi, M., Machida, T., and Tanimoto, H.: High-resolution simulation of CO2 using WRF-GHG over the Kanto region in Japan, J. Geophys. Res.-Atmos., 130, e2025JD043589, https://doi.org/10.1029/2025JD043589, 2025. 
Damiani, A., Irie, H., Yamaguchi, K., Hoque, H. M. S., Nakayama, T., Matsumi, Y., Kondo, T., and Da Silva, A.: Variabilities in PM2.5 and black carbon surface concentrations reproduced by aerosol optical properties estimated by sky radiometer and MAX-DOAS instruments, Remote Sens., 13, 3163, https://doi.org/10.3390/rs13163163, 2021. 
Damiani, A., Irie, H., Belikov, D. A., Kaizuka, S., Hoque, H. M. S., and Cordero, R. R.: Peculiar COVID-19 effects in the Greater Tokyo Area revealed by spatiotemporal variabilities of tropospheric gases and light-absorbing aerosols, Atmos. Chem. Phys., 22, 12705–12726, https://doi.org/10.5194/acp-22-12705-2022, 2022. 
Hirano, T., Sugawara, H., Murayama, S., and Kondo, H.: Diurnal variation of CO2 flux in an urban area of Tokyo, SOLA, 11, 100–103, https://doi.org/10.2151/sola.2015-024, 2015. 
IPCC (Intergovernmental Panel on Climate Change): Climate Change 2021: The Physical Science Basis, Cambridge University Press, Cambridge, https://doi.org/10.1017/9781009157896, 2021. 
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Continuous year-round measurements in Chiba, Japan, combining in‑situ CO2 observations with MAX‑DOAS (Multi-Axis Differential Optical Absorption Spectroscopy) NO2, showed that CO2 levels decrease on days with low near-surface NO2. CO2 enhancements quantified using these low-NO2 days correlated strongly with NO₂ and black carbon, indicating that this metric effectively tracks fossil-fuel-derived CO₂. The approach offers a simple, accurate method for monitoring urban CO2 emissions in megacities.
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