Your feedback has highlighted several areas where we can improve the clarity and detail of our manuscript. We have addressed your specific questions below, and we believe these clarifications will resolve the concerns you have raised.

• We acknowledge your concern regarding the validation of large particle sizes. Our claim of a 20 µm upper limit was based on the AATF's design capabilities. However, you are correct that our presented data does not fully support this range, especially given the Vasilatou et al reference. The validation data, combining the PSL experiments (up to 5 µm) and tests with other chemicals, robustly supports a range up to 15 µm. We agree that this is a more defensible claim based on the presented results. Therefore, we will revise the manuscript to claim a validated upper limit of 15 µm.
• Thank you for raising this important point regarding aerosol homogenization and the potential for particle settling, especially for larger particles. This is a critical consideration that we addressed through the engineering of the AATF's turbulent flow regime, and we appreciate the opportunity to clarify this in the manuscript. Additional explanation will be added to Section 2.2 “Aerosol Homogenization & Turbulence Characteristics,” and we will also add more explicit distances in our diagram of the facility. We will emphasize residence time in our analysis, as this is the more critical parameter for particle transport processes like settling and evaporation. Stokes’ Law gives the terminal settling velocity of a spherical particle in a quiescent environment with settling velocity increasing as the size of the particle increases. For a 10 µm diameter particle, this velocity is on the order of 0.3 cm/s. At 2 m/s flow through the tube, it takes approximately 2.5 s for air to travel from the aerosol input to past the collection tubes. In this short amount of time, the larger particles in the chamber would be expected to travel 0.75 cm downward in a still environment. However, the AATF is not quiescent, but rather has fully developed turbulent flow at Re = 40,000. With fully developed turbulent flow, turbulent fluctuation velocity is estimated as approximately 5–10% of the mean flow velocity, (in this case 10–20 cm/s.) With the turbulent fluctuation velocity being over 30 times greater than the particle's terminal settling velocity, turbulent fluctuation is the dominating factor in determining settling in the AATF. At these velocities, the particles are forcibly entrained in the chaotic flow, keeping them homogenized and suspended throughout their transit in the AATF.
• Using calibrated reference instruments is essential to the validation process. We appreciate you raising this point and apologize that this was not sufficiently clear in the manuscript. In fact, key instruments within the AATF are calibrated and serve as the reference instruments for our intercomparisons. Specifically, the two TSI APS units, the Promo, and the UHSAS were calibrated by their respective manufacturers immediately prior to this effort. Droplet Measurement Technologies (the manufacturers of the UHSAS) specifically states that their calibration exceeds ISO Standard 25101-1. We will revise the manuscript to explicitly state the calibration status of these instruments and to clarify their role as internal reference standards for the AATF. To ensure long-term data quality, we will add to our manuscript our plan to implement a routine verification protocol, such as periodically introducing PSL aerosols, to monitor instrument stability over time. We will also acknowledge that, as is fundamental to all aerosol sizing techniques, measurements of non-ideal aerosols carry inherent uncertainties related to material properties like density and refractive index.
• We would like to clarify that the validation measurements shown in Figure 3 were, in fact, performed using size-certified polystyrene latex (PSL) spheres. We apologize for omitting this critical detail from the figure caption and the main text. This method was chosen precisely to check the sizing accuracy of the instruments, as you correctly recommend, and to ensure sampling consistency throughout the cross-section of the AATF. We will amend the manuscript, specifically to Section 2.2 “Aerosol Homogenization & Turbulence Characteristics” and to the caption for Figure 3, to clearly state that size-certified PSL spheres were used in these validation experiments. This will reinforce the quantitative accuracy of our presented data.

We believe these revisions will fully address your concerns and significantly strengthen the manuscript. We thank you again for your valuable feedback, which has helped us identify where our manuscript can be improved.

We completely agree with the reviewer that a side-by-side intercomparison of the two APS instruments is a crucial baseline step for data validation.

To address this, we have updated the manuscript to include the results of a side-by-side baseline comparison of the two APS units that was performed using NIST-traceable polystyrene latex (PSL) spheres prior to their integration into the AATF. This baseline evaluation showed excellent agreement, with a percent difference of less than 5% at 2 and 4 micrometer sizes. A higher percent difference of approximately 45% was observed at 1 micrometer, which we attribute to differences in the instrument age and calibration cycles between the two specific units at the time of the test (one unit was brand new, while the other was older).

Given this verified baseline and the highly turbulent flow promoting rapid mixing and spatial homogeneity, we can confidently attribute the discrepancies in mass loading observed during the AATF testing to this expected inter-unit variability rather than physical stratification or poor mixing in the flow tube. This is further supported by our observation that restarting APS1 resolved the offset in the 10-20 micrometer range.

We have added a transparent discussion of this limitation to the manuscript. Taking the reviewer's feedback, we have also committed to implementing a mandatory side-by-side baseline comparison protocol for all future multi-instrument campaigns at the AATF.

Response to Minor Comments

• We agree that specifying the exact APS unit improves clarity. We have systematically reviewed the manuscript and figure captions to explicitly specify "APS1" or "APS2" where applicable.
• In Fig. 2 and 9, the blue shaded area represents the standard deviation of the measurements across multiple trials. We apologize for this omission, and the captions have been updated.
• We have adopted the suggested phrasing for the caption of Fig. 3, added the value for Vmax, and clarified the sample probe positions in the text, indicating that the heights and lateral positions were chosen so that no sample probe would be obstructed by a preceding sample probe.
• We have spelled out gas chromatograph/mass spectrometer at the first occurrence of GC/MS.
• 'Data shown in Fig.5 is from event 4' was rephrased and the reference moved.
• In Figure 7, the Promo data appears out of scale due to a highly varying mass calculation triggered by a small number of large particles in the long tail of the phenanthrene distribution. The y-axis scale has been changed to a log plot so as to not provide truncated data.

• While we agree with the reviewer that an in-line dryer would help stabilize the aerosol, implementing dryers at the AATF scale presents significant engineering and operational challenges. First, testing the effects of ambient air humidity on aerosol behavior is often an intended capability of the facility, so drying the main AATF flow itself would be counterproductive. Instead, a dryer would need to be implemented exclusively for the aerosol generator. This would require pulling the generation section offline and adding a large drying section. The dried aerosol would then need to be coupled back into the AATF tubes. This configuration requires a larger facility footprint and introduces additional, uncharacterized wall losses in the generation and drying chambers. While evaluating localized drying approaches for the generators will be considered for future work, full implementation requires structural modifications beyond the scope of this baseline paper.
• We thank the reviewer for pointing out inconsistency in subfigure labels. We have applied a uniform a), b), c) subfigure labeling convention to all figures in the manuscript.