Articles | Volume 7, issue 10
https://doi.org/10.5194/amt-7-3611-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-7-3611-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Amine permeation sources characterized with acid neutralization and sensitivities of an amine mass spectrometer
N. A. Freshour
Chemistry Department, Augsburg College, Minneapolis, MN 55454, USA
K. K. Carlson
Chemistry Department, Augsburg College, Minneapolis, MN 55454, USA
Y. A. Melka
Chemistry Department, Augsburg College, Minneapolis, MN 55454, USA
S. Hinz
Chemistry Department, Augsburg College, Minneapolis, MN 55454, USA
B. Panta
Chemistry Department, Augsburg College, Minneapolis, MN 55454, USA
D. R. Hanson
Chemistry Department, Augsburg College, Minneapolis, MN 55454, USA
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Cited
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34 citations as recorded by crossref.
- Gas-to-particle partitioning of atmospheric amines observed at a mountain site in southern China F. Liu et al. 10.1016/j.atmosenv.2018.09.038
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- Role of Methanesulfonic Acid in Sulfuric Acid–Amine and Ammonia New Particle Formation J. Johnson & C. Jen 10.1021/acsearthspacechem.3c00017
- Detection of atmospheric gaseous amines and amides by a high-resolution time-of-flight chemical ionization mass spectrometer with protonated ethanol reagent ions L. Yao et al. 10.5194/acp-16-14527-2016
- Chemical ionization of clusters formed from sulfuric acid and dimethylamine or diamines C. Jen et al. 10.5194/acp-16-12513-2016
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- Integrated experimental and theoretical approach to probe the synergistic effect of ammonia in methanesulfonic acid reactions with small alkylamines V. Perraud et al. 10.1039/C9EM00431A
- On the properties and atmospheric implication of amine-hydrated clusters J. Chen et al. 10.1039/C5RA11462D
- Kinetic study of C1 criegee intermediate with diethylamine and ethylamine and their atmospheric implications J. Shi et al. 10.1016/j.cplett.2023.140885
- Sulfuric acid nucleation: An experimental study of the effect of seven bases W. Glasoe et al. 10.1002/2014JD022730
- Multiple new-particle growth pathways observed at the US DOE Southern Great Plains field site A. Hodshire et al. 10.5194/acp-16-9321-2016
- H<sub>2</sub>SO<sub>4</sub> and particle production in a photolytic flow reactor: chemical modeling, cluster thermodynamics and contamination issues D. Hanson et al. 10.5194/acp-19-8999-2019
- Bisulfate – cluster based atmospheric pressure chemical ionization mass spectrometer for high-sensitivity (< 100 ppqV) detection of atmospheric dimethyl amine: proof-of-concept and first ambient data from boreal forest M. Sipilä et al. 10.5194/amt-8-4001-2015
- Reactions of Methanesulfonic Acid with Amines and Ammonia as a Source of New Particles in Air H. Chen et al. 10.1021/acs.jpcb.5b07433
- High-resolution modeling of gaseous methylamines over a polluted region in China: source-dependent emissions and implications of spatial variations J. Mao et al. 10.5194/acp-18-7933-2018
- Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry L. Rondo et al. 10.1002/2015JD023868
- Observations of Gas-Phase Alkylamines at a Coastal Site in the East Mediterranean Atmosphere E. Tzitzikalaki et al. 10.3390/atmos12111454
- Challenges associated with the sampling and analysis of organosulfur compounds in air using real-time PTR-ToF-MS and offline GC-FID V. Perraud et al. 10.5194/amt-9-1325-2016
- New particle formation in the sulfuric acid–dimethylamine–water system: reevaluation of CLOUD chamber measurements and comparison to an aerosol nucleation and growth model A. Kürten et al. 10.5194/acp-18-845-2018
- Ideas and perspectives: on the emission of amines from terrestrial vegetation in the context of new atmospheric particle formation J. Sintermann & A. Neftel 10.5194/bg-12-3225-2015
- Advances in offline approaches for trace measurements of complex organic compound mixtures via soft ionization and high-resolution tandem mass spectrometry P. Khare et al. 10.1016/j.chroma.2019.03.037
- Particle formation and growth from oxalic acid, methanesulfonic acid, trimethylamine and water: a combined experimental and theoretical study K. Arquero et al. 10.1039/C7CP04468B
- The Role of Oxalic Acid in New Particle Formation from Methanesulfonic Acid, Methylamine, and Water K. Arquero et al. 10.1021/acs.est.6b05056
- Synergistic Effect of Ammonia and Methylamine on Nucleation in the Earth’s Atmosphere. A Theoretical Study C. Wang et al. 10.1021/acs.jpca.8b00681
- Observation of new particle formation and measurement of sulfuric acid, ammonia, amines and highly oxidized organic molecules at a rural site in central Germany A. Kürten et al. 10.5194/acp-16-12793-2016
- Chemical composition of different size ultrafine particulate matter measured by nanoparticle chemical ionization mass spectrometer W. Wang et al. 10.1016/j.jes.2021.09.036
- Detection of dimethylamine in the low pptv range using nitrate chemical ionization atmospheric pressure interface time-of-flight (CI-APi-TOF) mass spectrometry M. Simon et al. 10.5194/amt-9-2135-2016
- A tutorial guide on new particle formation experiments using a laminar flow reactor S. Fomete et al. 10.1016/j.jaerosci.2021.105808
- Diamine‐sulfuric acid reactions are a potent source of new particle formation C. Jen et al. 10.1002/2015GL066958
- Atmospheric implications of hydrogen bonding between methanesulfonic acid and 12 kinds of N-containing compounds D. Chen et al. 10.1016/j.comptc.2024.114879
2 citations as recorded by crossref.
- Measurement of atmospheric amines and ammonia using the high resolution time-of-flight chemical ionization mass spectrometry J. Zheng et al. 10.1016/j.atmosenv.2014.12.002
- Stabilization of sulfuric acid dimers by ammonia, methylamine, dimethylamine, and trimethylamine C. Jen et al. 10.1002/2014JD021592
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Short summary
Amine permeation tubes were quantified via absorption of gaseous amines by dilute acid solutions. Calibrations of an amine mass spectrometer with these permeation tubes show that the mass spectrometer is very sensitive to amines. Measurements of ambient amines are presented from two recent field campaigns. The amine mass spectrometer instrumentation and sampling arrangements are extensively discussed.
Amine permeation tubes were quantified via absorption of gaseous amines by dilute acid...