Development of a photochemical source for the production and calibration of acyl peroxynitrate compounds

Veres, P. R.; Roberts, J. M.

doi:https://doi.org/10.5194/amt-8-2225-2015

Articles | Volume 8, issue 5

https://doi.org/10.5194/amt-8-2225-2015

© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

https://doi.org/10.5194/amt-8-2225-2015

© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Articles | Volume 8, issue 5

Research article

|

29 May 2015

Research article |

| 29 May 2015

Development of a photochemical source for the production and calibration of acyl peroxynitrate compounds

P. R. Veres and J. M. Roberts

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Final revised paper (published on 29 May 2015)
Preprint (discussion started on 03 Feb 2015)

Interactive discussion

Status: closed

AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment

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- Supplement

RC C184: 'Review of "Development of a photochemical source for the production and calibration of acyl peroxynitrate compounds" by P.R. Veres and J.R. Roberts', Anonymous Referee #1, 24 Feb 2015
- AC C999: 'Author reply to "Anonymous Referee #1"', P.R. Veres, 04 May 2015
RC C319: 'Review of Veres and Roberts. “Development of a photochemical source for the production and calibration of acyl peroxynitrate compounds.', Anonymous Referee #2, 17 Mar 2015
- AC C1002: 'Author reply to "Anonymous Referee #2"', P.R. Veres, 04 May 2015

Short summary

A dynamic system for the calibration of acyl peroxynitrate compounds has been developed to reduce the difficulty, required time, and stability of laboratory standards. We present a photochemical source for the generation of acetyl peroxynitrate (PAN), propionyl peroxynitrate (PPN), acryloyl peroxynitrate (APAN), methacryloyl peroxynitrate (MPAN), and crotonyl peroxynitrate (CPAN). Validation of the APN products was performed using iodide ion chemical ionization mass spectroscopy (I- CIMS).