Atmospheric Measurement Techniques
Atmospheric Measurement Techniques
AMT
Articles | Volume 8, issue 5
Articles | Volume 8, issue 5
https://doi.org/10.5194/amt-8-2225-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-2225-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
Articles | Volume 8, issue 5
Research article
 | 
29 May 2015
Research article |  | 29 May 2015

Development of a photochemical source for the production and calibration of acyl peroxynitrate compounds

P. R. Veres and J. M. Roberts

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Short summary
A dynamic system for the calibration of acyl peroxynitrate compounds has been developed to reduce the difficulty, required time, and stability of laboratory standards. We present a photochemical source for the generation of acetyl peroxynitrate (PAN), propionyl peroxynitrate (PPN), acryloyl peroxynitrate (APAN), methacryloyl peroxynitrate (MPAN), and crotonyl peroxynitrate (CPAN). Validation of the APN products was performed using iodide ion chemical ionization mass spectroscopy (I- CIMS).
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