Articles | Volume 8, issue 10
https://doi.org/10.5194/amt-8-4243-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-4243-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
14 Oct 2015
Research article |
| 14 Oct 2015
Intercomparison of the comparative reactivity method (CRM) and pump–probe technique for measuring total OH reactivity in an urban environment
Mines Douai, SAGE, 59508 Douai, France
Department of Chemistry, Indiana University, Bloomington, IN, USA
now at: School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
M. Blocquet
Université de Lille, PhysicoChimie des Processus de Combustion et de l'Atmosphère (PC2A) UMR 8522 CNRS/Lille 1, Cité scientifique, 59655 Villeneuve d'Ascq Cedex, France
C. Schoemaecker
Université de Lille, PhysicoChimie des Processus de Combustion et de l'Atmosphère (PC2A) UMR 8522 CNRS/Lille 1, Cité scientifique, 59655 Villeneuve d'Ascq Cedex, France
T. Léonardis
Mines Douai, SAGE, 59508 Douai, France
Université de Lille, Lille, France
N. Locoge
Mines Douai, SAGE, 59508 Douai, France
Université de Lille, Lille, France
C. Fittschen
Université de Lille, PhysicoChimie des Processus de Combustion et de l'Atmosphère (PC2A) UMR 8522 CNRS/Lille 1, Cité scientifique, 59655 Villeneuve d'Ascq Cedex, France
B. Hanoune
Université de Lille, PhysicoChimie des Processus de Combustion et de l'Atmosphère (PC2A) UMR 8522 CNRS/Lille 1, Cité scientifique, 59655 Villeneuve d'Ascq Cedex, France
P. S. Stevens
Department of Chemistry, Indiana University, Bloomington, IN, USA
School of Public and Environmental Affairs, Indiana University, Bloomington, IN, USA
Department of Earth and Environmental Sciences, Indian Institute of Science Education and Research Mohali, Sector 81, S. A. S. Nagar, Manauli PO, Punjab 140306, India
S. Dusanter
Mines Douai, SAGE, 59508 Douai, France
Université de Lille, Lille, France
Université de Lille, PhysicoChimie des Processus de Combustion et de l'Atmosphère (PC2A) UMR 8522 CNRS/Lille 1, Cité scientifique, 59655 Villeneuve d'Ascq Cedex, France
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Cited
28 citations as recorded by crossref.
- Comprehensive measurements of atmospheric OH reactivity and trace species within a suburban forest near Tokyo during AQUAS-TAMA campaign S. Ramasamy et al. 10.1016/j.atmosenv.2018.04.035
- Water does not catalyze the reaction of OH radicals with ethanol I. Weber et al. 10.1039/D0CP00467G
- Water Vapor Does Not Catalyze the Reaction between Methanol and OH Radicals W. Chao et al. 10.1002/ange.201900711
- How the OH reactivity affects the ozone production efficiency: case studies in Beijing and Heshan, China Y. Yang et al. 10.5194/acp-17-7127-2017
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
- LES study of the impact of moist thermals on the oxidative capacity of the atmosphere in southern West Africa F. Brosse et al. 10.5194/acp-18-6601-2018
- Variability of hydroxyl radical (OH) reactivity in the Landes maritime pine forest: results from the LANDEX campaign 2017 S. Bsaibes et al. 10.5194/acp-20-1277-2020
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- A large role of missing volatile organic compound reactivity from anthropogenic emissions in ozone pollution regulation W. Wang et al. 10.5194/acp-24-4017-2024
- Measurements of Total OH Reactivity During CalNex‐LA R. Hansen et al. 10.1029/2020JD032988
- A quantitative understanding of total OH reactivity and ozone production in a coastal industrial area during the Yokohama air quality study (AQUAS) campaign of summer 2019 J. Li et al. 10.1016/j.atmosenv.2021.118754
- A novel semi-direct method to measure OH reactivity by chemical ionization mass spectrometry (CIMS) J. Muller et al. 10.5194/amt-11-4413-2018
- ROOOH: a missing piece of the puzzle for OH measurements in low-NO environments? C. Fittschen et al. 10.5194/acp-19-349-2019
- Shipborne measurements of total OH reactivity around the Arabian Peninsula and its role in ozone chemistry E. Pfannerstill et al. 10.5194/acp-19-11501-2019
- Atmospheric OH reactivity in the western United States determined from comprehensive gas-phase measurements during WE-CAN W. Permar et al. 10.1039/D2EA00063F
- Time-Resolved Laser-Flash Photolysis Faraday Rotation Spectrometer: A New Tool for Total OH Reactivity Measurement and Free Radical Kinetics Research N. Wei et al. 10.1021/acs.analchem.9b05117
- Intercomparison of OH and OH reactivity measurements in a high isoprene and low NO environment during the Southern Oxidant and Aerosol Study (SOAS) D. Sanchez et al. 10.1016/j.atmosenv.2017.10.056
- Global modelling of the total OH reactivity: investigations on the “missing” OH sink and its atmospheric implications V. Ferracci et al. 10.5194/acp-18-7109-2018
- A Review of the Direct Measurement of Total OH Reactivity: Ambient Air and Vehicular Emission X. Yang 10.3390/su152316246
- Towards a quantitative understanding of total OH reactivity: A review Y. Yang et al. 10.1016/j.atmosenv.2016.03.010
- OH reactivity of the urban air in Helsinki, Finland, during winter A. Praplan et al. 10.1016/j.atmosenv.2017.09.013
- Water Vapor Does Not Catalyze the Reaction between Methanol and OH Radicals W. Chao et al. 10.1002/anie.201900711
- Contributions to OH reactivity from unexplored volatile organic compounds measured by PTR-ToF-MS – a case study in a suburban forest of the Seoul metropolitan area during the Korea–United States Air Quality Study (KORUS-AQ) 2016 D. Sanchez et al. 10.5194/acp-21-6331-2021
- Comparison of OH reactivity measurements in the atmospheric simulation chamber SAPHIR H. Fuchs et al. 10.5194/amt-10-4023-2017
- The improved comparative reactivity method (ICRM): measurements of OH reactivity under high-NO<sub><i>x</i></sub> conditions in ambient air W. Wang et al. 10.5194/amt-14-2285-2021
- Large unexplained suite of chemically reactive compounds present in ambient air due to biomass fires V. Kumar et al. 10.1038/s41598-017-19139-3
- Intercomparison of two comparative reactivity method instruments inf the Mediterranean basin during summer 2013 N. Zannoni et al. 10.5194/amt-8-3851-2015
- Detailed characterizations of the new Mines Douai comparative reactivity method instrument via laboratory experiments and modeling V. Michoud et al. 10.5194/amt-8-3537-2015
26 citations as recorded by crossref.
- Comprehensive measurements of atmospheric OH reactivity and trace species within a suburban forest near Tokyo during AQUAS-TAMA campaign S. Ramasamy et al. 10.1016/j.atmosenv.2018.04.035
- Water does not catalyze the reaction of OH radicals with ethanol I. Weber et al. 10.1039/D0CP00467G
- Water Vapor Does Not Catalyze the Reaction between Methanol and OH Radicals W. Chao et al. 10.1002/ange.201900711
- How the OH reactivity affects the ozone production efficiency: case studies in Beijing and Heshan, China Y. Yang et al. 10.5194/acp-17-7127-2017
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
- LES study of the impact of moist thermals on the oxidative capacity of the atmosphere in southern West Africa F. Brosse et al. 10.5194/acp-18-6601-2018
- Variability of hydroxyl radical (OH) reactivity in the Landes maritime pine forest: results from the LANDEX campaign 2017 S. Bsaibes et al. 10.5194/acp-20-1277-2020
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- A large role of missing volatile organic compound reactivity from anthropogenic emissions in ozone pollution regulation W. Wang et al. 10.5194/acp-24-4017-2024
- Measurements of Total OH Reactivity During CalNex‐LA R. Hansen et al. 10.1029/2020JD032988
- A quantitative understanding of total OH reactivity and ozone production in a coastal industrial area during the Yokohama air quality study (AQUAS) campaign of summer 2019 J. Li et al. 10.1016/j.atmosenv.2021.118754
- A novel semi-direct method to measure OH reactivity by chemical ionization mass spectrometry (CIMS) J. Muller et al. 10.5194/amt-11-4413-2018
- ROOOH: a missing piece of the puzzle for OH measurements in low-NO environments? C. Fittschen et al. 10.5194/acp-19-349-2019
- Shipborne measurements of total OH reactivity around the Arabian Peninsula and its role in ozone chemistry E. Pfannerstill et al. 10.5194/acp-19-11501-2019
- Atmospheric OH reactivity in the western United States determined from comprehensive gas-phase measurements during WE-CAN W. Permar et al. 10.1039/D2EA00063F
- Time-Resolved Laser-Flash Photolysis Faraday Rotation Spectrometer: A New Tool for Total OH Reactivity Measurement and Free Radical Kinetics Research N. Wei et al. 10.1021/acs.analchem.9b05117
- Intercomparison of OH and OH reactivity measurements in a high isoprene and low NO environment during the Southern Oxidant and Aerosol Study (SOAS) D. Sanchez et al. 10.1016/j.atmosenv.2017.10.056
- Global modelling of the total OH reactivity: investigations on the “missing” OH sink and its atmospheric implications V. Ferracci et al. 10.5194/acp-18-7109-2018
- A Review of the Direct Measurement of Total OH Reactivity: Ambient Air and Vehicular Emission X. Yang 10.3390/su152316246
- Towards a quantitative understanding of total OH reactivity: A review Y. Yang et al. 10.1016/j.atmosenv.2016.03.010
- OH reactivity of the urban air in Helsinki, Finland, during winter A. Praplan et al. 10.1016/j.atmosenv.2017.09.013
- Water Vapor Does Not Catalyze the Reaction between Methanol and OH Radicals W. Chao et al. 10.1002/anie.201900711
- Contributions to OH reactivity from unexplored volatile organic compounds measured by PTR-ToF-MS – a case study in a suburban forest of the Seoul metropolitan area during the Korea–United States Air Quality Study (KORUS-AQ) 2016 D. Sanchez et al. 10.5194/acp-21-6331-2021
- Comparison of OH reactivity measurements in the atmospheric simulation chamber SAPHIR H. Fuchs et al. 10.5194/amt-10-4023-2017
- The improved comparative reactivity method (ICRM): measurements of OH reactivity under high-NO<sub><i>x</i></sub> conditions in ambient air W. Wang et al. 10.5194/amt-14-2285-2021
- Large unexplained suite of chemically reactive compounds present in ambient air due to biomass fires V. Kumar et al. 10.1038/s41598-017-19139-3
2 citations as recorded by crossref.
- Intercomparison of two comparative reactivity method instruments inf the Mediterranean basin during summer 2013 N. Zannoni et al. 10.5194/amt-8-3851-2015
- Detailed characterizations of the new Mines Douai comparative reactivity method instrument via laboratory experiments and modeling V. Michoud et al. 10.5194/amt-8-3537-2015
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Latest update: 18 Apr 2024
Short summary
This paper describes and presents results from a intercomparison, in an environment rich in NOx (i.e., NO+NO2), of two OH reactivity instruments: one based on the comparative reactivity method, and one based on the pump-probe method. Co-located measurements were made of both ambient air and standard mixtures. Ambient OH reactivity values measured by both instruments were found to be in good agreement for ambient NOx mixing ratios as high as 100 ppbv.
This paper describes and presents results from a intercomparison, in an environment rich in NOx...
