Articles | Volume 9, issue 3
https://doi.org/10.5194/amt-9-1325-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-9-1325-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
30 Mar 2016
Research article |
| 30 Mar 2016
Challenges associated with the sampling and analysis of organosulfur compounds in air using real-time PTR-ToF-MS and offline GC-FID
Véronique Perraud
Department of Chemistry, University of California, Irvine, CA 92697, USA
Simone Meinardi
Department of Chemistry, University of California, Irvine, CA 92697, USA
Donald R. Blake
CORRESPONDING AUTHOR
Department of Chemistry, University of California, Irvine, CA 92697, USA
Barbara J. Finlayson-Pitts
CORRESPONDING AUTHOR
Department of Chemistry, University of California, Irvine, CA 92697, USA
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Cited
27 citations as recorded by crossref.
- Size-Resolved Chemical Composition of Sub-20 nm Particles from Methanesulfonic Acid Reactions with Methylamine and Ammonia V. Perraud et al. 10.1021/acsearthspacechem.0c00120
- Experimental and theoretical investigation of benzothiazole oxidation by OH in air and the role of O2 N. Karimova et al. 10.1039/D4EM00461B
- Study of the effect of marination treatment on garlic bioactive compounds through an innovative HPLC-DAD-MS method for alliin and curcuminoids analysis M. Ricciutelli et al. 10.1016/j.lwt.2020.109788
- Influence of saliva on individual in-mouth aroma release from raw cabbage (Brassica oleracea var. capitata f. rubra L.) and links to perception D. Frank et al. 10.1016/j.heliyon.2018.e01045
- Significant emissions of dimethyl sulfide and monoterpenes by big-leaf mahogany trees: discovery of a missing dimethyl sulfide source to the atmospheric environment L. Vettikkat et al. 10.5194/acp-20-375-2020
- Implications for new particle formation in air of the use of monoethanolamine in carbon capture and storage V. Perraud et al. 10.1039/D4CP00316K
- Characteristics of Spatial Distribution VOCs around Petrochemical Complex Using Passive Sampler S. Park et al. 10.5572/KOSAE.2022.38.5.764
- Direct analysis and monitoring of organosulphur compounds in the gaseous phase using portable mass spectrometry S. Giannoukos et al. 10.1039/C9AY01613A
- Identifying volatile in vitro biomarkers for oral bacteria with proton-transfer-reaction mass spectrometry and gas chromatography–mass spectrometry K. Roslund et al. 10.1038/s41598-021-96287-7
- Aldehydes gas ozonation monitoring: Interest of SIFT/MS versus GC/FID L. Vitola Pasetto et al. 10.1016/j.chemosphere.2019.06.186
- Measurements of volatile organic compounds in ambient air by gas-chromatography and real-time Vocus PTR-TOF-MS: calibrations, instrument background corrections, and introducing a PTR Data Toolkit A. Jensen et al. 10.5194/amt-16-5261-2023
- Multi-instrument comparison and compilation of non-methane organic gas emissions from biomass burning and implications for smoke-derived secondary organic aerosol precursors L. Hatch et al. 10.5194/acp-17-1471-2017
- Observed Relationships Between Cloud Droplet Effective Radius and Biogenic Gas Concentrations in Summertime Marine Stratocumulus Over the Eastern North Atlantic M. Miller et al. 10.1029/2021EA001929
- Oceanic emissions of dimethyl sulfide and methanethiol and their contribution to sulfur dioxide production in the marine atmosphere G. Novak et al. 10.5194/acp-22-6309-2022
- Large-volume constant-concentration sampling technique coupling with surface-enhanced Raman spectroscopy for rapid on-site gas analysis Z. Zhang et al. 10.1016/j.saa.2017.04.066
- Regenerative one-stage catalytic absorption process with cupric ions for removal of reduced sulfur compounds in polluted air P. Kasper & A. Feilberg 10.1080/09593330.2022.2077132
- Proton‐transfer‐reaction time‐of‐flight mass spectrometry (PTR‐TOF‐MS) as a tool for studying animal volatile organic compound (VOC) emissions M. Portillo‐Estrada et al. 10.1111/2041-210X.13554
- Extending PTR based breath analysis to real-time monitoring of reactive volatile organic compounds G. Pugliese et al. 10.1039/C9AN01478K
- Low-Cost Alternative for Online Analysis of Volatile Organic Compounds B. Rico et al. 10.1021/acs.analchem.4c00916
- The Production and Fate of Volatile Organosulfur Compounds in Sulfidic and Ferruginous Sediment J. Wilkening et al. 10.1029/2019JG005248
- Marine gas-phase sulfur emissions during an induced phytoplankton bloom D. Kilgour et al. 10.5194/acp-22-1601-2022
- An overview of conceptual-DFT based insights into global chemical reactivity of volatile sulfur compounds (VSCs) M. Bhatia 10.1016/j.comtox.2023.100295
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- The development and application of a new method for quantifying total atmospheric sulfur in the Alberta Oil Sands C. Mihele et al. 10.1080/10962247.2024.2440034
- An ultrasensitive SPI/PAI ion source based on a high-flux VUV lamp and its applications for the online mass spectrometric detection of sub-pptv sulfur ethers Y. Guo et al. 10.1016/j.talanta.2022.123558
- Method Validation and Dissipation Behaviour of Dimethyl Disulphide (DMDS) in Cucumber and Soil by Gas Chromatography-Tandem Mass Spectrometry A. Kaium et al. 10.3390/ijerph16224493
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
27 citations as recorded by crossref.
- Size-Resolved Chemical Composition of Sub-20 nm Particles from Methanesulfonic Acid Reactions with Methylamine and Ammonia V. Perraud et al. 10.1021/acsearthspacechem.0c00120
- Experimental and theoretical investigation of benzothiazole oxidation by OH in air and the role of O2 N. Karimova et al. 10.1039/D4EM00461B
- Study of the effect of marination treatment on garlic bioactive compounds through an innovative HPLC-DAD-MS method for alliin and curcuminoids analysis M. Ricciutelli et al. 10.1016/j.lwt.2020.109788
- Influence of saliva on individual in-mouth aroma release from raw cabbage (Brassica oleracea var. capitata f. rubra L.) and links to perception D. Frank et al. 10.1016/j.heliyon.2018.e01045
- Significant emissions of dimethyl sulfide and monoterpenes by big-leaf mahogany trees: discovery of a missing dimethyl sulfide source to the atmospheric environment L. Vettikkat et al. 10.5194/acp-20-375-2020
- Implications for new particle formation in air of the use of monoethanolamine in carbon capture and storage V. Perraud et al. 10.1039/D4CP00316K
- Characteristics of Spatial Distribution VOCs around Petrochemical Complex Using Passive Sampler S. Park et al. 10.5572/KOSAE.2022.38.5.764
- Direct analysis and monitoring of organosulphur compounds in the gaseous phase using portable mass spectrometry S. Giannoukos et al. 10.1039/C9AY01613A
- Identifying volatile in vitro biomarkers for oral bacteria with proton-transfer-reaction mass spectrometry and gas chromatography–mass spectrometry K. Roslund et al. 10.1038/s41598-021-96287-7
- Aldehydes gas ozonation monitoring: Interest of SIFT/MS versus GC/FID L. Vitola Pasetto et al. 10.1016/j.chemosphere.2019.06.186
- Measurements of volatile organic compounds in ambient air by gas-chromatography and real-time Vocus PTR-TOF-MS: calibrations, instrument background corrections, and introducing a PTR Data Toolkit A. Jensen et al. 10.5194/amt-16-5261-2023
- Multi-instrument comparison and compilation of non-methane organic gas emissions from biomass burning and implications for smoke-derived secondary organic aerosol precursors L. Hatch et al. 10.5194/acp-17-1471-2017
- Observed Relationships Between Cloud Droplet Effective Radius and Biogenic Gas Concentrations in Summertime Marine Stratocumulus Over the Eastern North Atlantic M. Miller et al. 10.1029/2021EA001929
- Oceanic emissions of dimethyl sulfide and methanethiol and their contribution to sulfur dioxide production in the marine atmosphere G. Novak et al. 10.5194/acp-22-6309-2022
- Large-volume constant-concentration sampling technique coupling with surface-enhanced Raman spectroscopy for rapid on-site gas analysis Z. Zhang et al. 10.1016/j.saa.2017.04.066
- Regenerative one-stage catalytic absorption process with cupric ions for removal of reduced sulfur compounds in polluted air P. Kasper & A. Feilberg 10.1080/09593330.2022.2077132
- Proton‐transfer‐reaction time‐of‐flight mass spectrometry (PTR‐TOF‐MS) as a tool for studying animal volatile organic compound (VOC) emissions M. Portillo‐Estrada et al. 10.1111/2041-210X.13554
- Extending PTR based breath analysis to real-time monitoring of reactive volatile organic compounds G. Pugliese et al. 10.1039/C9AN01478K
- Low-Cost Alternative for Online Analysis of Volatile Organic Compounds B. Rico et al. 10.1021/acs.analchem.4c00916
- The Production and Fate of Volatile Organosulfur Compounds in Sulfidic and Ferruginous Sediment J. Wilkening et al. 10.1029/2019JG005248
- Marine gas-phase sulfur emissions during an induced phytoplankton bloom D. Kilgour et al. 10.5194/acp-22-1601-2022
- An overview of conceptual-DFT based insights into global chemical reactivity of volatile sulfur compounds (VSCs) M. Bhatia 10.1016/j.comtox.2023.100295
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- The development and application of a new method for quantifying total atmospheric sulfur in the Alberta Oil Sands C. Mihele et al. 10.1080/10962247.2024.2440034
- An ultrasensitive SPI/PAI ion source based on a high-flux VUV lamp and its applications for the online mass spectrometric detection of sub-pptv sulfur ethers Y. Guo et al. 10.1016/j.talanta.2022.123558
- Method Validation and Dissipation Behaviour of Dimethyl Disulphide (DMDS) in Cucumber and Soil by Gas Chromatography-Tandem Mass Spectrometry A. Kaium et al. 10.3390/ijerph16224493
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
Latest update: 14 Dec 2024
Short summary
Gas phase organosulfur compounds in air serve as precursors of particles which impact human health, visibility, and climate. We compare here two different approaches to measuring these compounds, one an online mass spectrometry technique and the other canister sampling followed by offline analysis by gas chromatography. We show that each approach has its own advantages and limitations in measuring these compounds in complex mixtures, including some artifacts due to reactions on surfaces.
Gas phase organosulfur compounds in air serve as precursors of particles which impact human...
