Articles | Volume 9, issue 10
Atmos. Meas. Tech., 9, 4955–4975, 2016

Special issue: TROPOMI on Sentinel-5 Precursor: data products and...

Atmos. Meas. Tech., 9, 4955–4975, 2016

Research article 07 Oct 2016

Research article | 07 Oct 2016

Carbon monoxide total column retrievals from TROPOMI shortwave infrared measurements

Jochen Landgraf1, Joost aan de Brugh1, Remco Scheepmaker1, Tobias Borsdorff1, Haili Hu1, Sander Houweling1,3, Andre Butz2, Ilse Aben1, and Otto Hasekamp1 Jochen Landgraf et al.
  • 1SRON Netherlands Institute for Space Research, Utrecht, the Netherlands
  • 2Deutsches Zentrum für Luft- und Raumfahrt e.V. (DLR), Institut für Physik der Atmosphäre, Oberpfaffenhofen, Germany
  • 3Institute for Marine and Atmospheric Research Utrecht, Utrecht, the Netherlands

Abstract. The Tropospheric Monitoring Instrument (TROPOMI) spectrometer is the single payload of the Copernicus Sentinel 5 Precursor (S5P) mission. It measures Earth radiance spectra in the shortwave infrared spectral range around 2.3 µm with a dedicated instrument module. These measurements provide carbon monoxide (CO) total column densities over land, which for clear sky conditions are highly sensitive to the tropospheric boundary layer. For cloudy atmospheres over land and ocean, the column sensitivity changes according to the light path through the atmosphere. In this study, we present the physics-based operational S5P algorithm to infer atmospheric CO columns satisfying the envisaged accuracy ( <  15 %) and precision ( <  10 %) both for clear sky and cloudy observations with low cloud height. Here, methane absorption in the 2.3 µm range is combined with methane abundances from a global chemical transport model to infer information on atmospheric scattering. For efficient processing, we deploy a linearized two-stream radiative transfer model as forward model and a profile scaling approach to adjust the CO abundance in the inversion. Based on generic measurement ensembles, including clear sky and cloudy observations, we estimated the CO retrieval precision to be  ≤  11 % for surface albedo  ≥  0.03 and solar zenith angle  ≤  70°. CO biases of  ≤  3 % are introduced by inaccuracies in the methane a priori knowledge. For strongly enhanced CO concentrations in the tropospheric boundary layer and for cloudy conditions, CO errors in the order of 8 % can be introduced by the retrieval of cloud parameters of our algorithm. Moreover, we estimated the effect of a distorted spectral instrument response due to the inhomogeneous illumination of the instrument entrance slit in the flight direction to be  <  2 % with pseudo-random characteristics when averaging over space and time. Finally, the CO data exploitation is demonstrated for a TROPOMI orbit of simulated shortwave infrared measurements. Overall, the study demonstrates that for an instrument that performs in compliance with the pre-flight specifications, the CO product will meet the required product performance well.

Short summary
In 2016, the Sentinel 5 Precursor mission will be launched, with the TROPOMI instrument as its single payload. It will deliver daily global measurements of carbon monoxide for air quality monitoring as part of the Copernicus atmospheric services. In this paper, we focus on the operational data processing of the CO product from TROPOMI measurements of the shortwave infrared spectral range, and we discuss the algorithm's maturity.