Articles | Volume 9, issue 11
https://doi.org/10.5194/amt-9-5315-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-9-5315-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
07 Nov 2016
Research article |
| 07 Nov 2016
Sensitive detection of n-alkanes using a mixed ionization mode proton-transfer-reaction mass spectrometer
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, CA, USA
Centro de Ciencias de la Atmosfera, Universidad Nacional Autonoma
de Mexico, Mexico
Pawel K. Misztal
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, CA, USA
Robin Weber
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, CA, USA
David R. Worton
National Physical Laboratory, Teddington, Middlesex, TW11 0LW, UK
Haofei Zhang
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, CA, USA
Greg Drozd
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, CA, USA
Allen H. Goldstein
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, CA, USA
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Cited
28 citations as recorded by crossref.
- CF3+and CF2H+: new reagents for n-alkane determination in chemical ionisation reaction mass spectrometry R. Blake et al. 10.1039/C6AN02118B
- Gas-phase composition and secondary organic aerosol formation from standard and particle filter-retrofitted gasoline direct injection vehicles investigated in a batch and flow reactor S. Pieber et al. 10.5194/acp-18-9929-2018
- Using advanced mass spectrometry techniques to fully characterize atmospheric organic carbon: current capabilities and remaining gaps G. Isaacman-VanWertz et al. 10.1039/C7FD00021A
- Characterizing sources and emissions of volatile organic compounds in a northern California residence using space‐ and time‐resolved measurements Y. Liu et al. 10.1111/ina.12562
- Transient changes of volatile organic compounds (VOCs) during dulce de leche preparation by a direct injection mass spectrometer based on proton transfer reaction (PTR‐MS) M. Asaduzzaman et al. 10.1111/ijfs.15138
- Direct Detection of Small n-Alkanes at Sub-ppbv Level by Photoelectron-Induced O2+ Cation Chemical Ionization Mass Spectrometry at kPa Pressure Y. Wang et al. 10.1021/acs.analchem.8b00595
- Measurements of higher alkanes using NO<sup>+</sup> chemical ionization in PTR-ToF-MS: important contributions of higher alkanes to secondary organic aerosols in China C. Wang et al. 10.5194/acp-20-14123-2020
- Through‐Space Charge Transfer: A New Way to Develop a High‐Performance Fluorescence Sensing Film towards Opto‐Electronically Inert Alkanes Z. Wang et al. 10.1002/ange.202207619
- Chemical identification and quantification of volatile organic compounds emitted by sewage sludge K. Haider et al. 10.1016/j.scitotenv.2022.155948
- Decoding the social volatilome by tracking rapid context-dependent odour change S. Roberts et al. 10.1098/rstb.2019.0259
- Temperature dependence of volatile organic compound emissions from surface coatings: Inter-species difference observed in real indoor environments and mechanistic understanding J. Qiu et al. 10.1016/j.buildenv.2022.109954
- Through‐Space Charge Transfer: A New Way to Develop a High‐Performance Fluorescence Sensing Film towards Opto‐Electronically Inert Alkanes Z. Wang et al. 10.1002/anie.202207619
- A review of microbial and chemical assessment of indoor surfaces V. Mihucz et al. 10.1080/05704928.2021.1995870
- Online measurements of cycloalkanes based on NO+ chemical ionization in proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS) Y. Chen et al. 10.5194/amt-15-6935-2022
- Gas Analysis by Electron Ionization Combined with Chemical Ionization in a Compact FTICR Mass Spectrometer M. Heninger et al. 10.1021/acs.analchem.8b01107
- Effects of elevated oxygen levels on VOC analysis by means of PTR-ToF-MS P. Trefz et al. 10.1088/1752-7163/ab28ec
- Detection and Identification of VOCs Using Differential Ion Mobility Spectrometry (DMS) W. Fabianowski et al. 10.3390/molecules27010234
- Identification and quantification of VOCs by proton transfer reaction time of flight mass spectrometry: An experimental workflow for the optimization of specificity, sensitivity, and accuracy A. Romano & G. Hanna 10.1002/jms.4063
- Non-target scanning of organics from cooking emissions using comprehensive two-dimensional gas chromatography-mass spectrometer (GC×GC-MS) K. Song et al. 10.1016/j.apgeochem.2023.105601
- Use of Rapid Reduced Electric Field Switching to Enhance Compound Specificity for Proton Transfer Reaction-Mass Spectrometry R. González-Méndez et al. 10.1021/acs.analchem.7b05211
- Long-chain alkanes in the atmosphere: A review J. Li et al. 10.1016/j.jes.2021.07.021
- Comparison between Spatially Resolved Airborne Flux Measurements and Emission Inventories of Volatile Organic Compounds in Los Angeles E. Pfannerstill et al. 10.1021/acs.est.3c03162
- Proton Affinities of Alkanes Y. Fu et al. 10.1021/jasms.2c00152
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
- VOC emission rates over London and South East England obtained by airborne eddy covariance A. Vaughan et al. 10.1039/C7FD00002B
- Spatial Uncertainty in Modeling Inhalation Exposure to Volatile Organic Compounds in Response to the Application of Consumer Spray Products Y. Jung et al. 10.3390/ijerph18105334
- Volatile Organic Compound Emissions from Humans Indoors X. Tang et al. 10.1021/acs.est.6b04415
- Time Resolved Measurements of Speciated Tailpipe Emissions from Motor Vehicles: Trends with Emission Control Technology, Cold Start Effects, and Speciation G. Drozd et al. 10.1021/acs.est.6b04513
26 citations as recorded by crossref.
- CF3+and CF2H+: new reagents for n-alkane determination in chemical ionisation reaction mass spectrometry R. Blake et al. 10.1039/C6AN02118B
- Gas-phase composition and secondary organic aerosol formation from standard and particle filter-retrofitted gasoline direct injection vehicles investigated in a batch and flow reactor S. Pieber et al. 10.5194/acp-18-9929-2018
- Using advanced mass spectrometry techniques to fully characterize atmospheric organic carbon: current capabilities and remaining gaps G. Isaacman-VanWertz et al. 10.1039/C7FD00021A
- Characterizing sources and emissions of volatile organic compounds in a northern California residence using space‐ and time‐resolved measurements Y. Liu et al. 10.1111/ina.12562
- Transient changes of volatile organic compounds (VOCs) during dulce de leche preparation by a direct injection mass spectrometer based on proton transfer reaction (PTR‐MS) M. Asaduzzaman et al. 10.1111/ijfs.15138
- Direct Detection of Small n-Alkanes at Sub-ppbv Level by Photoelectron-Induced O2+ Cation Chemical Ionization Mass Spectrometry at kPa Pressure Y. Wang et al. 10.1021/acs.analchem.8b00595
- Measurements of higher alkanes using NO<sup>+</sup> chemical ionization in PTR-ToF-MS: important contributions of higher alkanes to secondary organic aerosols in China C. Wang et al. 10.5194/acp-20-14123-2020
- Through‐Space Charge Transfer: A New Way to Develop a High‐Performance Fluorescence Sensing Film towards Opto‐Electronically Inert Alkanes Z. Wang et al. 10.1002/ange.202207619
- Chemical identification and quantification of volatile organic compounds emitted by sewage sludge K. Haider et al. 10.1016/j.scitotenv.2022.155948
- Decoding the social volatilome by tracking rapid context-dependent odour change S. Roberts et al. 10.1098/rstb.2019.0259
- Temperature dependence of volatile organic compound emissions from surface coatings: Inter-species difference observed in real indoor environments and mechanistic understanding J. Qiu et al. 10.1016/j.buildenv.2022.109954
- Through‐Space Charge Transfer: A New Way to Develop a High‐Performance Fluorescence Sensing Film towards Opto‐Electronically Inert Alkanes Z. Wang et al. 10.1002/anie.202207619
- A review of microbial and chemical assessment of indoor surfaces V. Mihucz et al. 10.1080/05704928.2021.1995870
- Online measurements of cycloalkanes based on NO+ chemical ionization in proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS) Y. Chen et al. 10.5194/amt-15-6935-2022
- Gas Analysis by Electron Ionization Combined with Chemical Ionization in a Compact FTICR Mass Spectrometer M. Heninger et al. 10.1021/acs.analchem.8b01107
- Effects of elevated oxygen levels on VOC analysis by means of PTR-ToF-MS P. Trefz et al. 10.1088/1752-7163/ab28ec
- Detection and Identification of VOCs Using Differential Ion Mobility Spectrometry (DMS) W. Fabianowski et al. 10.3390/molecules27010234
- Identification and quantification of VOCs by proton transfer reaction time of flight mass spectrometry: An experimental workflow for the optimization of specificity, sensitivity, and accuracy A. Romano & G. Hanna 10.1002/jms.4063
- Non-target scanning of organics from cooking emissions using comprehensive two-dimensional gas chromatography-mass spectrometer (GC×GC-MS) K. Song et al. 10.1016/j.apgeochem.2023.105601
- Use of Rapid Reduced Electric Field Switching to Enhance Compound Specificity for Proton Transfer Reaction-Mass Spectrometry R. González-Méndez et al. 10.1021/acs.analchem.7b05211
- Long-chain alkanes in the atmosphere: A review J. Li et al. 10.1016/j.jes.2021.07.021
- Comparison between Spatially Resolved Airborne Flux Measurements and Emission Inventories of Volatile Organic Compounds in Los Angeles E. Pfannerstill et al. 10.1021/acs.est.3c03162
- Proton Affinities of Alkanes Y. Fu et al. 10.1021/jasms.2c00152
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
- VOC emission rates over London and South East England obtained by airborne eddy covariance A. Vaughan et al. 10.1039/C7FD00002B
- Spatial Uncertainty in Modeling Inhalation Exposure to Volatile Organic Compounds in Response to the Application of Consumer Spray Products Y. Jung et al. 10.3390/ijerph18105334
2 citations as recorded by crossref.
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Latest update: 16 Jul 2024
Short summary
Proton transfer reaction mass spectrometry (PTR-MS) was used to detect n-alkanes that generally have a lower proton affinity than water and therefore proton transfer (PT) by reaction with H3O+ is not an effective mechanism for their detection. In this study, we developed a method using a conventional PTR-MS to detect n-alkanes by optimizing ion source and drift tube conditions to vary the relative amounts of different primary ions (H3O+, O2+, NO+) in the reaction chamber (drift tube).
Proton transfer reaction mass spectrometry (PTR-MS) was used to detect n-alkanes that generally...
