Atmospheric Measurement Techniques
Atmospheric Measurement Techniques
AMT
Articles | Volume 10, issue 5
Articles | Volume 10, issue 5
https://doi.org/10.5194/amt-10-1911-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-10-1911-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Articles | Volume 10, issue 5
Research article
 | 
31 May 2017
Research article |  | 31 May 2017

Evaluation of the accuracy of thermal dissociation CRDS and LIF techniques for atmospheric measurement of reactive nitrogen species

Caroline C. Womack, J. Andrew Neuman, Patrick R. Veres, Scott J. Eilerman, Charles A. Brock, Zachary C. J. Decker, Kyle J. Zarzana, William P. Dube, Robert J. Wild, Paul J. Wooldridge, Ronald C. Cohen, and Steven S. Brown

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Short summary
The accurate detection of reactive nitrogen species (NOy) is key to understanding tropospheric ozone production. Typically, NOy is detected by thermal conversion to NO2, followed by NO2 detection. Here, we assess the conversion efficiency of several NOy species to NO2 in a thermal dissociation cavity ring-down spectrometer and discuss how this conversion efficiency is affected by certain experimental conditions, such as oven residence time, and interferences from non-NOy species.
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