Articles | Volume 10, issue 5
https://doi.org/10.5194/amt-10-1911-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-10-1911-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
31 May 2017
Research article |
| 31 May 2017
Evaluation of the accuracy of thermal dissociation CRDS and LIF techniques for atmospheric measurement of reactive nitrogen species
Caroline C. Womack
Chemical Sciences Division, Earth Science Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA
J. Andrew Neuman
Chemical Sciences Division, Earth Science Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Boulder, CO 80309, USA
Patrick R. Veres
Chemical Sciences Division, Earth Science Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Boulder, CO 80309, USA
Scott J. Eilerman
Chemical Sciences Division, Earth Science Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Boulder, CO 80309, USA
Charles A. Brock
Chemical Sciences Division, Earth Science Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA
Zachary C. J. Decker
Department of Chemistry and Biochemistry, University of Colorado, Boulder, Boulder, CO 80309, USA
Kyle J. Zarzana
Chemical Sciences Division, Earth Science Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Boulder, CO 80309, USA
William P. Dube
Chemical Sciences Division, Earth Science Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Boulder, CO 80309, USA
Robert J. Wild
Chemical Sciences Division, Earth Science Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Boulder, CO 80309, USA
Paul J. Wooldridge
Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720, USA
Ronald C. Cohen
Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720, USA
Department of Earth and Planetary Science, University of California, Berkeley, Berkeley, CA 94720, USA
Chemical Sciences Division, Earth Science Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA
Department of Chemistry and Biochemistry, University of Colorado, Boulder, Boulder, CO 80309, USA
Viewed
Total article views: 3,549 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 20 Dec 2016)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,291 | 1,132 | 126 | 3,549 | 467 | 159 | 179 |
- HTML: 2,291
- PDF: 1,132
- XML: 126
- Total: 3,549
- Supplement: 467
- BibTeX: 159
- EndNote: 179
Total article views: 2,879 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 31 May 2017)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,924 | 866 | 89 | 2,879 | 296 | 134 | 132 |
- HTML: 1,924
- PDF: 866
- XML: 89
- Total: 2,879
- Supplement: 296
- BibTeX: 134
- EndNote: 132
Total article views: 670 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 20 Dec 2016)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 367 | 266 | 37 | 670 | 171 | 25 | 47 |
- HTML: 367
- PDF: 266
- XML: 37
- Total: 670
- Supplement: 171
- BibTeX: 25
- EndNote: 47
Viewed (geographical distribution)
Total article views: 3,549 (including HTML, PDF, and XML)
Thereof 3,460 with geography defined
and 89 with unknown origin.
Total article views: 2,879 (including HTML, PDF, and XML)
Thereof 2,794 with geography defined
and 85 with unknown origin.
Total article views: 670 (including HTML, PDF, and XML)
Thereof 666 with geography defined
and 4 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
17 citations as recorded by crossref.
- Contribution of Organic Nitrates to Organic Aerosol over South Korea during KORUS-AQ H. Kenagy et al. 10.1021/acs.est.1c05521
- Thermal dissociation cavity-enhanced absorption spectrometer for measuring NO<sub>2</sub>, RO<sub>2</sub>NO<sub>2</sub>, and RONO<sub>2</sub> in the atmosphere C. Li et al. 10.5194/amt-14-4033-2021
- Comparison of airborne measurements of NO, NO2, HONO, NOy, and CO during FIREX-AQ I. Bourgeois et al. 10.5194/amt-15-4901-2022
- Reactive indoor air chemistry and health—A workshop summary J. Wells et al. 10.1016/j.ijheh.2017.09.009
- Quantification of Non-refractory Aerosol Nitrate in Ambient Air by Thermal Dissociation Cavity Ring-Down Spectroscopy N. Garner et al. 10.1021/acs.est.0c01156
- Field Measurement of Alkyl Nitrates in the Atmosphere C. Li et al. 10.6023/A23100460
- Sources and Secondary Production of Organic Aerosols in the Northeastern United States during WINTER J. Schroder et al. 10.1029/2018JD028475
- Measurement of NO<sub><i>x</i></sub> and NO<sub><i>y</i></sub> with a thermal dissociation cavity ring-down spectrometer (TD-CRDS): instrument characterisation and first deployment N. Friedrich et al. 10.5194/amt-13-5739-2020
- A Wide-Range and Calibration-Free Spectrometer Which Combines Wavelength Modulation and Direct Absorption Spectroscopy with Cavity Ringdown Spectroscopy Z. Wang et al. 10.3390/s20030585
- Quantification of peroxynitric acid and peroxyacyl nitrates using an ethane-based thermal dissociation peroxy radical chemical amplification cavity ring-down spectrometer Y. Taha et al. 10.5194/amt-11-4109-2018
- Development of an Analytical Method for the Detection of NO<sub>z</sub> and Its Application to the Atmospheric Analysis at a Mountain Site R. WADA et al. 10.2116/bunsekikagaku.67.333
- Comparison of Airborne Reactive Nitrogen Measurements During WINTER T. Sparks et al. 10.1029/2019JD030700
- A thermal-dissociation–cavity ring-down spectrometer (TD-CRDS) for the detection of organic nitrates in gas and particle phases N. Keehan et al. 10.5194/amt-13-6255-2020
- Characterization of a catalyst-based conversion technique to measure total particulate nitrogen and organic carbon and comparison to a particle mass measurement instrument C. Stockwell et al. 10.5194/amt-11-2749-2018
- Reactive nitrogen around the Arabian Peninsula and in the Mediterranean Sea during the 2017 AQABA ship campaign N. Friedrich et al. 10.5194/acp-21-7473-2021
- The <i>Fires, Asian, and Stratospheric Transport</i>–Las Vegas Ozone Study (<i>FAST</i>-LVOS) A. Langford et al. 10.5194/acp-22-1707-2022
- Modeling NH4NO3 Over the San Joaquin Valley During the 2013 DISCOVER‐AQ Campaign J. Kelly et al. 10.1029/2018JD028290
17 citations as recorded by crossref.
- Contribution of Organic Nitrates to Organic Aerosol over South Korea during KORUS-AQ H. Kenagy et al. 10.1021/acs.est.1c05521
- Thermal dissociation cavity-enhanced absorption spectrometer for measuring NO<sub>2</sub>, RO<sub>2</sub>NO<sub>2</sub>, and RONO<sub>2</sub> in the atmosphere C. Li et al. 10.5194/amt-14-4033-2021
- Comparison of airborne measurements of NO, NO2, HONO, NOy, and CO during FIREX-AQ I. Bourgeois et al. 10.5194/amt-15-4901-2022
- Reactive indoor air chemistry and health—A workshop summary J. Wells et al. 10.1016/j.ijheh.2017.09.009
- Quantification of Non-refractory Aerosol Nitrate in Ambient Air by Thermal Dissociation Cavity Ring-Down Spectroscopy N. Garner et al. 10.1021/acs.est.0c01156
- Field Measurement of Alkyl Nitrates in the Atmosphere C. Li et al. 10.6023/A23100460
- Sources and Secondary Production of Organic Aerosols in the Northeastern United States during WINTER J. Schroder et al. 10.1029/2018JD028475
- Measurement of NO<sub><i>x</i></sub> and NO<sub><i>y</i></sub> with a thermal dissociation cavity ring-down spectrometer (TD-CRDS): instrument characterisation and first deployment N. Friedrich et al. 10.5194/amt-13-5739-2020
- A Wide-Range and Calibration-Free Spectrometer Which Combines Wavelength Modulation and Direct Absorption Spectroscopy with Cavity Ringdown Spectroscopy Z. Wang et al. 10.3390/s20030585
- Quantification of peroxynitric acid and peroxyacyl nitrates using an ethane-based thermal dissociation peroxy radical chemical amplification cavity ring-down spectrometer Y. Taha et al. 10.5194/amt-11-4109-2018
- Development of an Analytical Method for the Detection of NO<sub>z</sub> and Its Application to the Atmospheric Analysis at a Mountain Site R. WADA et al. 10.2116/bunsekikagaku.67.333
- Comparison of Airborne Reactive Nitrogen Measurements During WINTER T. Sparks et al. 10.1029/2019JD030700
- A thermal-dissociation–cavity ring-down spectrometer (TD-CRDS) for the detection of organic nitrates in gas and particle phases N. Keehan et al. 10.5194/amt-13-6255-2020
- Characterization of a catalyst-based conversion technique to measure total particulate nitrogen and organic carbon and comparison to a particle mass measurement instrument C. Stockwell et al. 10.5194/amt-11-2749-2018
- Reactive nitrogen around the Arabian Peninsula and in the Mediterranean Sea during the 2017 AQABA ship campaign N. Friedrich et al. 10.5194/acp-21-7473-2021
- The <i>Fires, Asian, and Stratospheric Transport</i>–Las Vegas Ozone Study (<i>FAST</i>-LVOS) A. Langford et al. 10.5194/acp-22-1707-2022
- Modeling NH4NO3 Over the San Joaquin Valley During the 2013 DISCOVER‐AQ Campaign J. Kelly et al. 10.1029/2018JD028290
Latest update: 23 Nov 2024
Short summary
The accurate detection of reactive nitrogen species (NOy) is key to understanding tropospheric ozone production. Typically, NOy is detected by thermal conversion to NO2, followed by NO2 detection. Here, we assess the conversion efficiency of several NOy species to NO2 in a thermal dissociation cavity ring-down spectrometer and discuss how this conversion efficiency is affected by certain experimental conditions, such as oven residence time, and interferences from non-NOy species.
The accurate detection of reactive nitrogen species (NOy) is key to understanding tropospheric...
