Articles | Volume 11, issue 12
https://doi.org/10.5194/amt-11-6815-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-11-6815-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
21 Dec 2018
Research article |
| 21 Dec 2018
| 21 Dec 2018
Low-pressure gas chromatography with chemical ionization mass spectrometry for quantification of multifunctional organic compounds in the atmosphere
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA
Hannah M. Allen
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA
John D. Crounse
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA
Eric Praske
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA
Anke C. Noelscher
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA
now at: Deutscher Wetterdienst, Technische Infrastruktur, Frankfurter Straße 135, Offenbach am Main, Germany
Paul O. Wennberg
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA 91125, USA
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- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
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- Chemistry of Functionalized Reactive Organic Intermediates in the Earth’s Atmosphere: Impact, Challenges, and Progress V. Barber & J. Kroll 10.1021/acs.jpca.1c08221
- Synthesis and Characterization of Atmospherically Relevant Hydroxy Hydroperoxides P. Mettke et al. 10.3390/atmos13040507
- Atmospheric Photo-Oxidation of 2-Ethoxyethanol: Autoxidation Chemistry of Glycol Ethers H. Yu et al. 10.1021/acs.jpca.3c04456
- Rapid hydrolysis of tertiary isoprene nitrate efficiently removes NO x from the atmosphere K. Vasquez et al. 10.1073/pnas.2017442117
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- Stereoselectivity in Atmospheric Autoxidation K. Møller et al. 10.1021/acs.jpclett.9b01972
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- Determination of Semivolatile Organic Nitrates in Ambient Atmosphere by Gas Chromatography/Electron Ionization–Mass Spectrometry R. Li et al. 10.3390/atmos10020088
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- Accretion product formation in the self-reaction of ethene-derived hydroxy peroxy radicals S. Murphy et al. 10.1039/D3EA00020F
- Intramolecular Hydrogen Shift Chemistry of Hydroperoxy-Substituted Peroxy Radicals E. Praske et al. 10.1021/acs.jpca.8b09745
18 citations as recorded by crossref.
- FORest Canopy Atmosphere Transfer (FORCAsT) 2.0: model updates and evaluation with observations at a mixed forest site D. Wei et al. 10.5194/gmd-14-6309-2021
- Unimolecular Reactions of Peroxy Radicals Formed in the Oxidation of α-Pinene and β-Pinene by Hydroxyl Radicals L. Xu et al. 10.1021/acs.jpca.8b11726
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Chemistry and deposition in the Model of Atmospheric composition at Global and Regional scales using Inversion Techniques for Trace gas Emissions (MAGRITTE v1.1) – Part 1: Chemical mechanism J. Müller et al. 10.5194/gmd-12-2307-2019
- Isolating α-Pinene Ozonolysis Pathways Reveals New Insights into Peroxy Radical Chemistry and Secondary Organic Aerosol Formation Z. Zhao et al. 10.1021/acs.est.1c02107
- Coupling a gas chromatograph simultaneously to a flame ionization detector and chemical ionization mass spectrometer for isomer-resolved measurements of particle-phase organic compounds C. Bi et al. 10.5194/amt-14-3895-2021
- Chemistry of Functionalized Reactive Organic Intermediates in the Earth’s Atmosphere: Impact, Challenges, and Progress V. Barber & J. Kroll 10.1021/acs.jpca.1c08221
- Synthesis and Characterization of Atmospherically Relevant Hydroxy Hydroperoxides P. Mettke et al. 10.3390/atmos13040507
- Atmospheric Photo-Oxidation of 2-Ethoxyethanol: Autoxidation Chemistry of Glycol Ethers H. Yu et al. 10.1021/acs.jpca.3c04456
- Rapid hydrolysis of tertiary isoprene nitrate efficiently removes NO x from the atmosphere K. Vasquez et al. 10.1073/pnas.2017442117
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- Stereoselectivity in Atmospheric Autoxidation K. Møller et al. 10.1021/acs.jpclett.9b01972
- New Insights into the Radical Chemistry and Product Distribution in the OH-Initiated Oxidation of Benzene L. Xu et al. 10.1021/acs.est.0c04780
- Determination of Semivolatile Organic Nitrates in Ambient Atmosphere by Gas Chromatography/Electron Ionization–Mass Spectrometry R. Li et al. 10.3390/atmos10020088
- Observations of speciated isoprene nitrates in Beijing: implications for isoprene chemistry C. Reeves et al. 10.5194/acp-21-6315-2021
- Quantification of isomer-resolved iodide chemical ionization mass spectrometry sensitivity and uncertainty using a voltage-scanning approach C. Bi et al. 10.5194/amt-14-6835-2021
- Accretion product formation in the self-reaction of ethene-derived hydroxy peroxy radicals S. Murphy et al. 10.1039/D3EA00020F
1 citations as recorded by crossref.
Discussed (final revised paper)
Latest update: 24 Apr 2024
Short summary
Oxygenated volatile organic compounds (OVOCs) are difficult to measure in the atmosphere due to their high reactivity and low concentrations. This hinders our understanding of their impact on air quality and climate. Therefore, we have developed a field-deployable instrument capable of providing isomer-resolved measurements of OVOCs in the ambient air. Its performance is assessed through data collected both in the laboratory and during two field studies.
Oxygenated volatile organic compounds (OVOCs) are difficult to measure in the atmosphere due to...
