Articles | Volume 11, issue 12
https://doi.org/10.5194/amt-11-6815-2018
https://doi.org/10.5194/amt-11-6815-2018
Research article
 | 
21 Dec 2018
Research article |  | 21 Dec 2018

Low-pressure gas chromatography with chemical ionization mass spectrometry for quantification of multifunctional organic compounds in the atmosphere

Krystal T. Vasquez, Hannah M. Allen, John D. Crounse, Eric Praske, Lu Xu, Anke C. Noelscher, and Paul O. Wennberg

Related authors

Parameterizations of US wildfire and prescribed fire emission ratios and emission factors based on FIREX-AQ aircraft measurements
Georgios I. Gkatzelis, Matthew M. Coggon, Chelsea E. Stockwell, Rebecca S. Hornbrook, Hannah Allen, Eric C. Apel, Megan M. Bela, Donald R. Blake, Ilann Bourgeois, Steven S. Brown, Pedro Campuzano-Jost, Jason M. St. Clair, James H. Crawford, John D. Crounse, Douglas A. Day, Joshua P. DiGangi, Glenn S. Diskin, Alan Fried, Jessica B. Gilman, Hongyu Guo, Johnathan W. Hair, Hannah S. Halliday, Thomas F. Hanisco, Reem Hannun, Alan Hills, L. Gregory Huey, Jose L. Jimenez, Joseph M. Katich, Aaron Lamplugh, Young Ro Lee, Jin Liao, Jakob Lindaas, Stuart A. McKeen, Tomas Mikoviny, Benjamin A. Nault, J. Andrew Neuman, John B. Nowak, Demetrios Pagonis, Jeff Peischl, Anne E. Perring, Felix Piel, Pamela S. Rickly, Michael A. Robinson, Andrew W. Rollins, Thomas B. Ryerson, Melinda K. Schueneman, Rebecca H. Schwantes, Joshua P. Schwarz, Kanako Sekimoto, Vanessa Selimovic, Taylor Shingler, David J. Tanner, Laura Tomsche, Krystal T. Vasquez, Patrick R. Veres, Rebecca Washenfelder, Petter Weibring, Paul O. Wennberg, Armin Wisthaler, Glenn M. Wolfe, Caroline C. Womack, Lu Xu, Katherine Ball, Robert J. Yokelson, and Carsten Warneke
Atmos. Chem. Phys., 24, 929–956, https://doi.org/10.5194/acp-24-929-2024,https://doi.org/10.5194/acp-24-929-2024, 2024
Short summary
FORest Canopy Atmosphere Transfer (FORCAsT) 2.0: model updates and evaluation with observations at a mixed forest site
Dandan Wei, Hariprasad D. Alwe, Dylan B. Millet, Brandon Bottorff, Michelle Lew, Philip S. Stevens, Joshua D. Shutter, Joshua L. Cox, Frank N. Keutsch, Qianwen Shi, Sarah C. Kavassalis, Jennifer G. Murphy, Krystal T. Vasquez, Hannah M. Allen, Eric Praske, John D. Crounse, Paul O. Wennberg, Paul B. Shepson, Alexander A. T. Bui, Henry W. Wallace, Robert J. Griffin, Nathaniel W. May, Megan Connor, Jonathan H. Slade, Kerri A. Pratt, Ezra C. Wood, Mathew Rollings, Benjamin L. Deming, Daniel C. Anderson, and Allison L. Steiner
Geosci. Model Dev., 14, 6309–6329, https://doi.org/10.5194/gmd-14-6309-2021,https://doi.org/10.5194/gmd-14-6309-2021, 2021
Short summary

Related subject area

Subject: Gases | Technique: In Situ Measurement | Topic: Instruments and Platforms
Multiphysical description of atmospheric pressure interface chemical ionisation in MION2 and Eisele type inlets
Henning Finkenzeller, Jyri Mikkilä, Cecilia Righi, Paxton Juuti, Mikko Sipilä, Matti Rissanen, Douglas Worsnop, Aleksei Shcherbinin, Nina Sarnela, and Juha Kangasluoma
Atmos. Meas. Tech., 17, 5989–6001, https://doi.org/10.5194/amt-17-5989-2024,https://doi.org/10.5194/amt-17-5989-2024, 2024
Short summary
A portable nitrogen dioxide instrument using cavity-enhanced absorption spectroscopy
Steven A. Bailey, Reem A. Hannun, Andrew K. Swanson, and Thomas F. Hanisco
Atmos. Meas. Tech., 17, 5903–5910, https://doi.org/10.5194/amt-17-5903-2024,https://doi.org/10.5194/amt-17-5903-2024, 2024
Short summary
Development and deployment of a mid-cost CO2 sensor monitoring network to support atmospheric inverse modeling for quantifying urban CO2 emissions in Paris
Jinghui Lian, Olivier Laurent, Mali Chariot, Luc Lienhardt, Michel Ramonet, Hervé Utard, Thomas Lauvaux, François-Marie Bréon, Grégoire Broquet, Karina Cucchi, Laurent Millair, and Philippe Ciais
Atmos. Meas. Tech., 17, 5821–5839, https://doi.org/10.5194/amt-17-5821-2024,https://doi.org/10.5194/amt-17-5821-2024, 2024
Short summary
UAV-based in situ measurements of CO2 and CH4 fluxes over complex natural ecosystems
Abdullah Bolek, Martin Heimann, and Mathias Göckede
Atmos. Meas. Tech., 17, 5619–5636, https://doi.org/10.5194/amt-17-5619-2024,https://doi.org/10.5194/amt-17-5619-2024, 2024
Short summary
A new aerial approach for quantifying and attributing methane emissions: implementation and validation
Jonathan F. Dooley, Kenneth Minschwaner, Manvendra K. Dubey, Sahar H. El Abbadi, Evan D. Sherwin, Aaron G. Meyer, Emily Follansbee, and James E. Lee
Atmos. Meas. Tech., 17, 5091–5111, https://doi.org/10.5194/amt-17-5091-2024,https://doi.org/10.5194/amt-17-5091-2024, 2024
Short summary

Cited articles

Amelynck, C., Schoon, N., and Arijs, E.: Gas phase reactions of CF3O and CF3OH2O with nitric, formic, and acetic acid, Int. J. Mass. Spectrom., 203, 165–175, https://doi.org/10.1016/S1387-3806(00)00321-3, 2000a. a
Amelynck, C., Van, A.-M., Schoon, B. N., and Arijs, E.: Gas phase reactions of CF3O and CF3OH2O and their relevance to the detection of stratospheric HCl, Int. J. Mass. Spectrom., 202, 207–216, https://doi.org/10.1016/S1387-3806(00)00244-X, 2000b. a
Apel, E. C., Hills, A. J., Lueb, R., Zindel, S., Eisele, S., and Riemer, D. D.: A fast-GC/MS system to measure C2 to C4 carbonyls and methanol aboard aircraft, J. Geophys. Res.-Atmos., 108, 8794, https://doi.org/10.1029/2002JD003199, 2003. a, b
Apel, E. C., Brauers, T., Koppmann, R., Bandowe, B., Boßmeyer, J., Holzke, C., Tillmann, R., Wahner, A., Wegener, R., Brunner, A., Jocher, M., Ruuskanen, T., Spirig, C., Steigner, D., Steinbrecher, R., Gomez Alvarez, E., Müller, K., Burrows, J. P., Schade, G., Solomon, S. J., Ladstätter-Weißenmayer, A., Simmonds, P., Young, D., Hopkins, J. R., Lewis, A. C., Legreid, G., Reimann, S., Hansel, A., Wisthaler, A., Blake, R. S., Ellis, A. M., Monks, P. S., and Wyche, K. P.: Intercomparison of oxygenated volatile organic compound measurements at the SAPHIR atmosphere simulation chamber, J. Geophys. Res.-Atmos., 113, D20307, https://doi.org/10.1029/2008JD009865, 2008. a
Arey, J., Crowley, D. E., Crowley, M., Resketo, M., and Lester, J.: Hydrocarbon emissions from natural vegetation in California's South Coast Air Basin, Atmos. Environ., 29, 2977–2988, https://doi.org/10.1016/1352-2310(95)00137-N, 1995. a
Download
Short summary
Oxygenated volatile organic compounds (OVOCs) are difficult to measure in the atmosphere due to their high reactivity and low concentrations. This hinders our understanding of their impact on air quality and climate. Therefore, we have developed a field-deployable instrument capable of providing isomer-resolved measurements of OVOCs in the ambient air. Its performance is assessed through data collected both in the laboratory and during two field studies.