Articles | Volume 12, issue 3
https://doi.org/10.5194/amt-12-1861-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-12-1861-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
20 Mar 2019
Research article |
| 20 Mar 2019
| 20 Mar 2019
Using collision-induced dissociation to constrain sensitivity of ammonia chemical ionization mass spectrometry (NH4+ CIMS) to oxygenated volatile organic compounds
Alexander Zaytsev
CORRESPONDING AUTHOR
John A. Paulson School of Engineering and Applied Sciences, Harvard
University, Cambridge, MA 02138, USA
Martin Breitenlechner
John A. Paulson School of Engineering and Applied Sciences, Harvard
University, Cambridge, MA 02138, USA
Abigail R. Koss
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02139, USA
Christopher Y. Lim
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02139, USA
James C. Rowe
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02139, USA
Jesse H. Kroll
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02139, USA
Frank N. Keutsch
John A. Paulson School of Engineering and Applied Sciences, Harvard
University, Cambridge, MA 02138, USA
Department of Chemistry and Chemical Biology, Harvard University,
Cambridge, MA 02138, USA
Department of Earth and Planetary Sciences, Harvard University,
Cambridge, MA 02138, USA
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29 citations as recorded by crossref.
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- Highly oxygenated organic molecules produced by the oxidation of benzene and toluene in a wide range of OH exposure and NO<sub><i>x</i></sub> conditions X. Cheng et al. 10.5194/acp-21-12005-2021
- Anthropogenic Volatile Organic Compound (AVOC) Autoxidation as a Source of Highly Oxygenated Organic Molecules (HOM) M. Rissanen 10.1021/acs.jpca.1c06465
- Review of technologies and their applications for the speciated detection of RO2 radicals Y. Gao et al. 10.1016/j.jes.2022.09.028
- Ab initio calculation of the proton transfer reaction rate coefficients to volatile organic compounds related to cork taint in wine M. Bhatia et al. 10.1002/jms.4592
- Ring-opening yields and auto-oxidation rates of the resulting peroxy radicals from OH-oxidation of α-pinene and β-pinene B. Lee et al. 10.1039/D2EA00133K
- Gas phase H+, H3O+ and NH4+ affinities of oxygen-bearing volatile organic compounds; DFT calculations for soft chemical ionisation mass spectrometry M. Omezzine Gnioua et al. 10.1039/D3CP03604A
- Chamber studies of OH + dimethyl sulfoxide and dimethyl disulfide: insights into the dimethyl sulfide oxidation mechanism M. Goss & J. Kroll 10.5194/acp-24-1299-2024
- Correcting bias in log-linear instrument calibrations in the context of chemical ionization mass spectrometry C. Bi et al. 10.5194/amt-14-6551-2021
- Performance of a new coaxial ion–molecule reaction region for low-pressure chemical ionization mass spectrometry with reduced instrument wall interactions B. Palm et al. 10.5194/amt-12-5829-2019
- Quantification of isomer-resolved iodide chemical ionization mass spectrometry sensitivity and uncertainty using a voltage-scanning approach C. Bi et al. 10.5194/amt-14-6835-2021
- Real-Time Laboratory Measurements of VOC Emissions, Removal Rates, and Byproduct Formation from Consumer-Grade Oxidation-Based Air Cleaners Q. Ye et al. 10.1021/acs.estlett.1c00773
- The INNpinJeR: a new wall-free reactor for studying gas-phase reactions W. Scholz et al. 10.1039/D1EA00072A
- Temperature-dependent sensitivity of iodide chemical ionization mass spectrometers M. Robinson et al. 10.5194/amt-15-4295-2022
- Application of chemical derivatization techniques combined with chemical ionization mass spectrometry to detect stabilized Criegee intermediates and peroxy radicals in the gas phase A. Zaytsev et al. 10.5194/amt-14-2501-2021
- Tracking indoor volatile organic compounds with online mass spectrometry W. Liu et al. 10.1016/j.trac.2023.117514
- The $${\text{NH}}_{4}^{ + }$$(H2O)n Reagent Ion: Calculations of the Structure, Thermodynamic Parameters of Hydration, Equilibrium Composition, and Mobility A. Lebedev & S. Kolbinev 10.1134/S1061934822140039
- Indoor Air Quality Implications of Germicidal 222 nm Light V. Barber et al. 10.1021/acs.est.3c05680
- Ammonium adduct chemical ionization to investigate anthropogenic oxygenated gas-phase organic compounds in urban air P. Khare et al. 10.5194/acp-22-14377-2022
- Electrostatic Switching and Selection of H3O+, NO+, and O2+• Reagent Ions for Selected Ion Flow-Drift Tube Mass Spectrometric Analyses of Air and Breath P. Španěl et al. 10.1021/acs.analchem.9b00530
- Introducing the extended volatility range proton-transfer-reaction mass spectrometer (EVR PTR-MS) F. Piel et al. 10.5194/amt-14-1355-2021
- A versatile vacuum ultraviolet ion source for reduced pressure bipolar chemical ionization mass spectrometry M. Breitenlechner et al. 10.5194/amt-15-1159-2022
- Dimensionality-reduction techniques for complex mass spectrometric datasets: application to laboratory atmospheric organic oxidation experiments A. Koss et al. 10.5194/acp-20-1021-2020
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Chemical ionization mass spectrometry utilizing ammonium ions (NH4+ CIMS) for measurements of organic compounds in the atmosphere L. Xu et al. 10.5194/amt-15-7353-2022
- A novel method for producing NH4+ reagent ions in the hollow cathode glow discharge ion source of PTR-MS instruments M. Müller et al. 10.1016/j.ijms.2019.116254
- Product distribution, kinetics, and aerosol formation from the OH oxidation of dimethyl sulfide under different RO2 regimes Q. Ye et al. 10.5194/acp-22-16003-2022
- The $${\text{NH}}_{4}^{ + }$$(H2O) Reagent Ion: Mechanism of Increasing the Specificity of Ion Mobility Spectrometry Based Devices for Toxic Substances Detection in the Presence of Alkanes A. Lebedev & S. Kolbinev 10.1134/S1061934823140046
- Fast Peroxy Radical Isomerization and OH Recycling in the Reaction of OH Radicals with Dimethyl Sulfide T. Berndt et al. 10.1021/acs.jpclett.9b02567
29 citations as recorded by crossref.
- Mechanistic study of the formation of ring-retaining and ring-opening products from the oxidation of aromatic compounds under urban atmospheric conditions A. Zaytsev et al. 10.5194/acp-19-15117-2019
- Highly oxygenated organic molecules produced by the oxidation of benzene and toluene in a wide range of OH exposure and NO<sub><i>x</i></sub> conditions X. Cheng et al. 10.5194/acp-21-12005-2021
- Anthropogenic Volatile Organic Compound (AVOC) Autoxidation as a Source of Highly Oxygenated Organic Molecules (HOM) M. Rissanen 10.1021/acs.jpca.1c06465
- Review of technologies and their applications for the speciated detection of RO2 radicals Y. Gao et al. 10.1016/j.jes.2022.09.028
- Ab initio calculation of the proton transfer reaction rate coefficients to volatile organic compounds related to cork taint in wine M. Bhatia et al. 10.1002/jms.4592
- Ring-opening yields and auto-oxidation rates of the resulting peroxy radicals from OH-oxidation of α-pinene and β-pinene B. Lee et al. 10.1039/D2EA00133K
- Gas phase H+, H3O+ and NH4+ affinities of oxygen-bearing volatile organic compounds; DFT calculations for soft chemical ionisation mass spectrometry M. Omezzine Gnioua et al. 10.1039/D3CP03604A
- Chamber studies of OH + dimethyl sulfoxide and dimethyl disulfide: insights into the dimethyl sulfide oxidation mechanism M. Goss & J. Kroll 10.5194/acp-24-1299-2024
- Correcting bias in log-linear instrument calibrations in the context of chemical ionization mass spectrometry C. Bi et al. 10.5194/amt-14-6551-2021
- Performance of a new coaxial ion–molecule reaction region for low-pressure chemical ionization mass spectrometry with reduced instrument wall interactions B. Palm et al. 10.5194/amt-12-5829-2019
- Quantification of isomer-resolved iodide chemical ionization mass spectrometry sensitivity and uncertainty using a voltage-scanning approach C. Bi et al. 10.5194/amt-14-6835-2021
- Real-Time Laboratory Measurements of VOC Emissions, Removal Rates, and Byproduct Formation from Consumer-Grade Oxidation-Based Air Cleaners Q. Ye et al. 10.1021/acs.estlett.1c00773
- The INNpinJeR: a new wall-free reactor for studying gas-phase reactions W. Scholz et al. 10.1039/D1EA00072A
- Temperature-dependent sensitivity of iodide chemical ionization mass spectrometers M. Robinson et al. 10.5194/amt-15-4295-2022
- Application of chemical derivatization techniques combined with chemical ionization mass spectrometry to detect stabilized Criegee intermediates and peroxy radicals in the gas phase A. Zaytsev et al. 10.5194/amt-14-2501-2021
- Tracking indoor volatile organic compounds with online mass spectrometry W. Liu et al. 10.1016/j.trac.2023.117514
- The $${\text{NH}}_{4}^{ + }$$(H2O)n Reagent Ion: Calculations of the Structure, Thermodynamic Parameters of Hydration, Equilibrium Composition, and Mobility A. Lebedev & S. Kolbinev 10.1134/S1061934822140039
- Indoor Air Quality Implications of Germicidal 222 nm Light V. Barber et al. 10.1021/acs.est.3c05680
- Ammonium adduct chemical ionization to investigate anthropogenic oxygenated gas-phase organic compounds in urban air P. Khare et al. 10.5194/acp-22-14377-2022
- Electrostatic Switching and Selection of H3O+, NO+, and O2+• Reagent Ions for Selected Ion Flow-Drift Tube Mass Spectrometric Analyses of Air and Breath P. Španěl et al. 10.1021/acs.analchem.9b00530
- Introducing the extended volatility range proton-transfer-reaction mass spectrometer (EVR PTR-MS) F. Piel et al. 10.5194/amt-14-1355-2021
- A versatile vacuum ultraviolet ion source for reduced pressure bipolar chemical ionization mass spectrometry M. Breitenlechner et al. 10.5194/amt-15-1159-2022
- Dimensionality-reduction techniques for complex mass spectrometric datasets: application to laboratory atmospheric organic oxidation experiments A. Koss et al. 10.5194/acp-20-1021-2020
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Chemical ionization mass spectrometry utilizing ammonium ions (NH4+ CIMS) for measurements of organic compounds in the atmosphere L. Xu et al. 10.5194/amt-15-7353-2022
- A novel method for producing NH4+ reagent ions in the hollow cathode glow discharge ion source of PTR-MS instruments M. Müller et al. 10.1016/j.ijms.2019.116254
- Product distribution, kinetics, and aerosol formation from the OH oxidation of dimethyl sulfide under different RO2 regimes Q. Ye et al. 10.5194/acp-22-16003-2022
- The $${\text{NH}}_{4}^{ + }$$(H2O) Reagent Ion: Mechanism of Increasing the Specificity of Ion Mobility Spectrometry Based Devices for Toxic Substances Detection in the Presence of Alkanes A. Lebedev & S. Kolbinev 10.1134/S1061934823140046
- Fast Peroxy Radical Isomerization and OH Recycling in the Reaction of OH Radicals with Dimethyl Sulfide T. Berndt et al. 10.1021/acs.jpclett.9b02567
Latest update: 17 Apr 2024
Short summary
We present the development of a chemical ionization mass spectrometer which can be operated with either ammonium (NH4+) or hydronium (H3O+) as the reagent ion. We describe a mass spectrometric voltage scanning procedure based on collision-induced dissociation that allows us to determine the stability of detected ammonium–organic ions and hence constrain the sensitivity of the instrument to a wide range of organic compounds that cannot be calibrated directly.
We present the development of a chemical ionization mass spectrometer which can be operated with...
