Articles | Volume 12, issue 10
https://doi.org/10.5194/amt-12-5303-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-12-5303-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
07 Oct 2019
Research article |
| 07 Oct 2019
| 07 Oct 2019
Measurement techniques for identifying and quantifying hydroxymethanesulfonate (HMS) in an aqueous matrix and particulate matter using aerosol mass spectrometry and ion chromatography
John A. Paulson School of Engineering and Applied Sciences, Harvard
University, Cambridge, MA 02138, USA
Christopher Y. Lim
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02138, USA
Manjula R. Canagaratna
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc.,
Billerica, MA 02138, USA
Jesse H. Kroll
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02138, USA
Douglas R. Worsnop
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc.,
Billerica, MA 02138, USA
Frank N. Keutsch
John A. Paulson School of Engineering and Applied Sciences, Harvard
University, Cambridge, MA 02138, USA
Department of Chemistry and Chemical Biology, Harvard University,
Cambridge, MA 02138, USA
Department of Earth and Planetary Sciences, Harvard University,
Cambridge, MA 02138, USA
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Cited
31 citations as recorded by crossref.
- Significant Conversion of Organic Sulfur from Hydroxymethanesulfonate to Inorganic Sulfate and Peroxydisulfate Ions upon Heterogeneous OH Oxidation D. Lai et al. 10.1021/acs.estlett.3c00472
- Deactivating Effect of Hydroxyl Radicals Reactivity by Sulfate and Sulfite Functional Groups in Aqueous Phase─Atmospheric Implications for Small Organosulfur Compounds D. Lai et al. 10.1021/acsestair.4c00033
- Global modeling of heterogeneous hydroxymethanesulfonate chemistry S. Song et al. 10.5194/acp-21-457-2021
- Updated In-Cloud Secondary Aerosol Production in the Northern Hemisphere Predicted by the Community Multiscale Air Quality Modeling System K. Fahey et al. 10.1021/acsearthspacechem.4c00370
- Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field J. Liu et al. 10.1021/acs.estlett.1c00357
- Multiphase sulfur chemistry facilitates particle growth in a cold and dark urban environment J. Mao et al. 10.1039/D4FD00170B
- Spatiotemporal imputation of missing aerosol optical depth using hybrid machine learning with downscaling A. Tuheti et al. 10.1016/j.atmosenv.2024.120989
- A highly sensitive electrochemical sensor by growing Ag nanoparticles on the surface of PPy@PEDOT:PSS film for detecting sodium hydroxymethanesulfinate molecules T. Xu et al. 10.1016/j.fochx.2023.100701
- Sulfate Formation via Cloud Processing from Isoprene Hydroxyl Hydroperoxides (ISOPOOH) E. Dovrou et al. 10.1021/acs.est.9b04645
- Emission factors and evolution of SO2 measured from biomass burning in wildfires and agricultural fires P. Rickly et al. 10.5194/acp-22-15603-2022
- Influences of sources and weather dynamics on atmospheric deposition of Se species and other trace elements E. Breuninger et al. 10.5194/acp-24-2491-2024
- Contribution of hydroxymethanesulfonate (HMS) to severe winter haze in the North China Plain T. Ma et al. 10.5194/acp-20-5887-2020
- Aerosol high water contents favor sulfate and secondary organic aerosol formation from fossil fuel combustion emissions X. Huang et al. 10.1038/s41612-023-00504-1
- Multi-year, high-time resolution aerosol chemical composition and mass measurements from Fairbanks, Alaska E. Robinson et al. 10.1039/D4EA00008K
- Source and Chemistry of Hydroxymethanesulfonate (HMS) in Fairbanks, Alaska J. Campbell et al. 10.1021/acs.est.2c00410
- Hydroxymethanesulfonate and Sulfur(IV) in Fairbanks Winter During the ALPACA Study K. Dingilian et al. 10.1021/acsestair.4c00012
- Global Importance of Hydroxymethanesulfonate in Ambient Particulate Matter: Implications for Air Quality J. Moch et al. 10.1029/2020JD032706
- Universal ion chromatography method for anions in active pharmaceutical ingredients enabled by computer-assisted separation modeling T. Yuan et al. 10.1016/j.jpba.2023.115923
- Aerosol pH indicator and organosulfate detectability from aerosol mass spectrometry measurements M. Schueneman et al. 10.5194/amt-14-2237-2021
- Stability assessment of organic sulfur and organosulfate compounds in filter samples for quantification by Fourier- transform infrared spectroscopy M. Anunciado et al. 10.5194/amt-16-3515-2023
- A Detailed Reaction Mechanism for Thiosulfate Oxidation by Ozone in Aqueous Environments A. Deal et al. 10.1021/acs.est.4c06188
- Hydroxymethanesulfonate formation accelerated at the air-water interface by synergistic enthalpy-entropy effects J. Li et al. 10.1038/s41467-025-59712-3
- Towards a chemical mechanism of the oxidation of aqueous sulfur dioxide via isoprene hydroxyl hydroperoxides (ISOPOOH) E. Dovrou et al. 10.5194/acp-21-8999-2021
- Year-round modeling of sulfate aerosol over Asia through updates of aqueous-phase oxidation and gas-phase reactions with stabilized Criegee intermediates S. Itahashi et al. 10.1016/j.aeaoa.2021.100123
- Quantitative Determination of Hydroxymethanesulfonate (HMS) Using Ion Chromatography and UHPLC-LTQ-Orbitrap Mass Spectrometry: A Missing Source of Sulfur during Haze Episodes in Beijing L. Wei et al. 10.1021/acs.estlett.0c00528
- Hygroscopicity and cloud condensation nucleation activities of hydroxyalkylsulfonates C. Peng et al. 10.1016/j.scitotenv.2022.154767
- Predicted impacts of heterogeneous chemical pathways on particulate sulfur over Fairbanks (Alaska), the Northern Hemisphere, and the Contiguous United States S. Farrell et al. 10.5194/acp-25-3287-2025
- Overview of the Alaskan Layered Pollution and Chemical Analysis (ALPACA) Field Experiment W. Simpson et al. 10.1021/acsestair.3c00076
- Catalytic role of formaldehyde in particulate matter formation E. Dovrou et al. 10.1073/pnas.2113265119
- Detection of hydroxymethanesulfonate (HMS) by transition metal-anchored fullerene nanoclusters H. Louis et al. 10.1007/s13738-022-02707-4
- The acidity of atmospheric particles and clouds H. Pye et al. 10.5194/acp-20-4809-2020
31 citations as recorded by crossref.
- Significant Conversion of Organic Sulfur from Hydroxymethanesulfonate to Inorganic Sulfate and Peroxydisulfate Ions upon Heterogeneous OH Oxidation D. Lai et al. 10.1021/acs.estlett.3c00472
- Deactivating Effect of Hydroxyl Radicals Reactivity by Sulfate and Sulfite Functional Groups in Aqueous Phase─Atmospheric Implications for Small Organosulfur Compounds D. Lai et al. 10.1021/acsestair.4c00033
- Global modeling of heterogeneous hydroxymethanesulfonate chemistry S. Song et al. 10.5194/acp-21-457-2021
- Updated In-Cloud Secondary Aerosol Production in the Northern Hemisphere Predicted by the Community Multiscale Air Quality Modeling System K. Fahey et al. 10.1021/acsearthspacechem.4c00370
- Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field J. Liu et al. 10.1021/acs.estlett.1c00357
- Multiphase sulfur chemistry facilitates particle growth in a cold and dark urban environment J. Mao et al. 10.1039/D4FD00170B
- Spatiotemporal imputation of missing aerosol optical depth using hybrid machine learning with downscaling A. Tuheti et al. 10.1016/j.atmosenv.2024.120989
- A highly sensitive electrochemical sensor by growing Ag nanoparticles on the surface of PPy@PEDOT:PSS film for detecting sodium hydroxymethanesulfinate molecules T. Xu et al. 10.1016/j.fochx.2023.100701
- Sulfate Formation via Cloud Processing from Isoprene Hydroxyl Hydroperoxides (ISOPOOH) E. Dovrou et al. 10.1021/acs.est.9b04645
- Emission factors and evolution of SO2 measured from biomass burning in wildfires and agricultural fires P. Rickly et al. 10.5194/acp-22-15603-2022
- Influences of sources and weather dynamics on atmospheric deposition of Se species and other trace elements E. Breuninger et al. 10.5194/acp-24-2491-2024
- Contribution of hydroxymethanesulfonate (HMS) to severe winter haze in the North China Plain T. Ma et al. 10.5194/acp-20-5887-2020
- Aerosol high water contents favor sulfate and secondary organic aerosol formation from fossil fuel combustion emissions X. Huang et al. 10.1038/s41612-023-00504-1
- Multi-year, high-time resolution aerosol chemical composition and mass measurements from Fairbanks, Alaska E. Robinson et al. 10.1039/D4EA00008K
- Source and Chemistry of Hydroxymethanesulfonate (HMS) in Fairbanks, Alaska J. Campbell et al. 10.1021/acs.est.2c00410
- Hydroxymethanesulfonate and Sulfur(IV) in Fairbanks Winter During the ALPACA Study K. Dingilian et al. 10.1021/acsestair.4c00012
- Global Importance of Hydroxymethanesulfonate in Ambient Particulate Matter: Implications for Air Quality J. Moch et al. 10.1029/2020JD032706
- Universal ion chromatography method for anions in active pharmaceutical ingredients enabled by computer-assisted separation modeling T. Yuan et al. 10.1016/j.jpba.2023.115923
- Aerosol pH indicator and organosulfate detectability from aerosol mass spectrometry measurements M. Schueneman et al. 10.5194/amt-14-2237-2021
- Stability assessment of organic sulfur and organosulfate compounds in filter samples for quantification by Fourier- transform infrared spectroscopy M. Anunciado et al. 10.5194/amt-16-3515-2023
- A Detailed Reaction Mechanism for Thiosulfate Oxidation by Ozone in Aqueous Environments A. Deal et al. 10.1021/acs.est.4c06188
- Hydroxymethanesulfonate formation accelerated at the air-water interface by synergistic enthalpy-entropy effects J. Li et al. 10.1038/s41467-025-59712-3
- Towards a chemical mechanism of the oxidation of aqueous sulfur dioxide via isoprene hydroxyl hydroperoxides (ISOPOOH) E. Dovrou et al. 10.5194/acp-21-8999-2021
- Year-round modeling of sulfate aerosol over Asia through updates of aqueous-phase oxidation and gas-phase reactions with stabilized Criegee intermediates S. Itahashi et al. 10.1016/j.aeaoa.2021.100123
- Quantitative Determination of Hydroxymethanesulfonate (HMS) Using Ion Chromatography and UHPLC-LTQ-Orbitrap Mass Spectrometry: A Missing Source of Sulfur during Haze Episodes in Beijing L. Wei et al. 10.1021/acs.estlett.0c00528
- Hygroscopicity and cloud condensation nucleation activities of hydroxyalkylsulfonates C. Peng et al. 10.1016/j.scitotenv.2022.154767
- Predicted impacts of heterogeneous chemical pathways on particulate sulfur over Fairbanks (Alaska), the Northern Hemisphere, and the Contiguous United States S. Farrell et al. 10.5194/acp-25-3287-2025
- Overview of the Alaskan Layered Pollution and Chemical Analysis (ALPACA) Field Experiment W. Simpson et al. 10.1021/acsestair.3c00076
- Catalytic role of formaldehyde in particulate matter formation E. Dovrou et al. 10.1073/pnas.2113265119
- Detection of hydroxymethanesulfonate (HMS) by transition metal-anchored fullerene nanoclusters H. Louis et al. 10.1007/s13738-022-02707-4
- The acidity of atmospheric particles and clouds H. Pye et al. 10.5194/acp-20-4809-2020
Latest update: 19 Jun 2025
Short summary
Measurement techniques commonly used to analyze particulate matter composition can result in the possible misidentification of sulfur-containing species, especially for the case of sulfate and hydroxymethanesulfonate (HMS). The efficiency and limitations of these techniques, along with a method that enables further studies of the contribution of sulfur-containing species, S(IV) versus S(VI), to particulate matter under low-light atmospheric conditions, are described in this work.
Measurement techniques commonly used to analyze particulate matter composition can result in the...
