Articles | Volume 13, issue 11
https://doi.org/10.5194/amt-13-6325-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-13-6325-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
25 Nov 2020
Research article |
| 25 Nov 2020
| 25 Nov 2020
An interlaboratory comparison of aerosol inorganic ion measurements by ion chromatography: implications for aerosol pH estimate
Jingsha Xu
School of Geography Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
Shaojie Song
School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA
Roy M. Harrison
School of Geography Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
Department of Environmental Sciences/Center of Excellence in Environmental Studies, King Abdulaziz University, P.O. Box 80203, Jeddah, 21589, Saudi Arabia
Congbo Song
School of Geography Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
Lianfang Wei
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
Qiang Zhang
Institute of Surface-Earth System Science, Tianjin University, Tianjin, 300072, China
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
Lu Lei
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
Chao Zhang
Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, and Frontiers Science Center for Deep Ocean Multispheres and Earth System, Ocean University of China, Qingdao 266100, China
Xiaohong Yao
Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, and Frontiers Science Center for Deep Ocean Multispheres and Earth System, Ocean University of China, Qingdao 266100, China
Laboratory for Marine Ecology and Environmental Sciences, Qingdao National Laboratory for Marine Science and Technology, Qingdao, 266071, China
Dihui Chen
Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, and Frontiers Science Center for Deep Ocean Multispheres and Earth System, Ocean University of China, Qingdao 266100, China
Weijun Li
Department of Atmospheric Sciences, School of Earth Sciences, Zhejiang University, Hangzhou, 310027, China
Miaomiao Wu
Department of Atmospheric Sciences, School of Earth Sciences, Zhejiang University, Hangzhou, 310027, China
Hezhong Tian
State Key Laboratory of Environmental Simulation and Pollution Control & Center for Atmospheric Environmental Studies, School of Environment, Beijing Normal University, Beijing 100875, China
Lining Luo
State Key Laboratory of Environmental Simulation and Pollution Control & Center for Atmospheric Environmental Studies, School of Environment, Beijing Normal University, Beijing 100875, China
Shengrui Tong
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China
Weiran Li
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China
Junling Wang
School of Environment, Tsinghua University, Beijing, 100084, China
Guoliang Shi
State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control, Centre of Urban Transport Emission Research, College of Environmental Science and Engineering, Nankai University, Tianjin, 300350, China
Yanqi Huangfu
State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control, Centre of Urban Transport Emission Research, College of Environmental Science and Engineering, Nankai University, Tianjin, 300350, China
Yingze Tian
State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control, Centre of Urban Transport Emission Research, College of Environmental Science and Engineering, Nankai University, Tianjin, 300350, China
Baozhu Ge
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
Shaoli Su
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing, 400714, China
Chao Peng
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing, 400714, China
Yang Chen
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing, 400714, China
Fumo Yang
Department of Environmental Science and Engineering, Sichuan University, Chengdu, 610065, China
Aleksandra Mihajlidi-Zelić
Centre of Excellence in Environmental Chemistry and Engineering – ICTM, University of Belgrade, Njegoševa 12 (Studentski trg 14–16), Belgrade, Serbia
Dragana Đorđević
Centre of Excellence in Environmental Chemistry and Engineering – ICTM, University of Belgrade, Njegoševa 12 (Studentski trg 14–16), Belgrade, Serbia
Stefan J. Swift
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, YO10 5DD, UK
Imogen Andrews
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, YO10 5DD, UK
Jacqueline F. Hamilton
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, YO10 5DD, UK
Ye Sun
School of Space and Environment, Beihang University, Beijing, 100191, China
Agung Kramawijaya
School of Geography Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
Jinxiu Han
School of Geography Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
Supattarachai Saksakulkrai
School of Geography Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
Clarissa Baldo
School of Geography Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
Siqi Hou
School of Geography Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
Feixue Zheng
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, China
Kaspar R. Daellenbach
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, China
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, China
Yongchun Liu
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, China
Markku Kulmala
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, China
Pingqing Fu
Institute of Surface-Earth System Science, Tianjin University, Tianjin, 300072, China
School of Geography Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
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Cited
19 citations as recorded by crossref.
- Enhanced Nitrate Fraction: Enabling Urban Aerosol Particles to Remain in a Liquid State at Reduced Relative Humidity Y. Liu et al. 10.1029/2023GL105505
- Dust emission reduction enhanced gas-to-particle conversion of ammonia in the North China Plain Y. Liu et al. 10.1038/s41467-022-34733-4
- Source apportionment of fine organic carbon at an urban site of Beijing using a chemical mass balance model J. Xu et al. 10.5194/acp-21-7321-2021
- Importance of Oxidants and Temperature in the Formation of Biogenic Organosulfates and Nitrooxy Organosulfates D. Bryant et al. 10.1021/acsearthspacechem.1c00204
- Size-dependent aerosol iron solubility in an urban atmosphere L. Liu et al. 10.1038/s41612-022-00277-z
- Direct measurement of aerosol acidity using pH testing paper and hygroscopic equilibrium under high relative humidity Q. Song & K. Osada 10.1016/j.atmosenv.2021.118605
- Biogenic and anthropogenic sources of isoprene and monoterpenes and their secondary organic aerosol in Delhi, India D. Bryant et al. 10.5194/acp-23-61-2023
- Aerosol physical characterization: A review on the current state of aerosol documentary standards and calibration strategies K. Vasilatou et al. 10.1016/j.jaerosci.2024.106483
- Elucidating the present-day chemical composition, seasonality and source regions of climate-relevant aerosols across the Arctic land surface V. Moschos et al. 10.1088/1748-9326/ac444b
- Chemical characteristics and source apportionment of particulate matter (PM2.5) in Dammam, Saudi Arabia: Impact of dust storms M. Alwadei et al. 10.1016/j.aeaoa.2022.100164
- Estimation of aerosol acidity at a suburban site of Nanjing using machine learning method M. Tao et al. 10.1007/s10874-022-09433-4
- Fine Aerosol Acidity and Water during Summer in the Eastern North Atlantic T. Nah et al. 10.3390/atmos12081040
- Source apportionment of carbonaceous aerosols in Beijing with radiocarbon and organic tracers: insight into the differences between urban and rural sites S. Hou et al. 10.5194/acp-21-8273-2021
- PM2.5-bound silicon-containing secondary organic aerosols (Si-SOA) in Beijing ambient air J. Xu et al. 10.1016/j.chemosphere.2021.132377
- Temporal Variation and Potential Sources of Water-Soluble Inorganic Ions in PM2.5 in Two Sites of Mexico City F. Millán-Vázquez et al. 10.3390/atmos14101585
- Pan-Arctic methanesulfonic acid aerosol: source regions, atmospheric drivers, and future projections J. Pernov et al. 10.1038/s41612-024-00712-3
- Sources of Aerosol Acidity at a Suburban Site of Nanjing and Their Associations with Chlorophyll Depletion J. Gong et al. 10.1021/acsearthspacechem.1c00273
- Comparison of acidity and chemical composition of summertime cloud water and aerosol at an alpine site in Northwest China: Implications for the neutral property of clouds in the free troposphere M. Shen et al. 10.1016/j.scitotenv.2024.171775
- Insights into air pollution chemistry and sulphate formation from nitrous acid (HONO) measurements during haze events in Beijing W. Bloss et al. 10.1039/D0FD00100G
18 citations as recorded by crossref.
- Enhanced Nitrate Fraction: Enabling Urban Aerosol Particles to Remain in a Liquid State at Reduced Relative Humidity Y. Liu et al. 10.1029/2023GL105505
- Dust emission reduction enhanced gas-to-particle conversion of ammonia in the North China Plain Y. Liu et al. 10.1038/s41467-022-34733-4
- Source apportionment of fine organic carbon at an urban site of Beijing using a chemical mass balance model J. Xu et al. 10.5194/acp-21-7321-2021
- Importance of Oxidants and Temperature in the Formation of Biogenic Organosulfates and Nitrooxy Organosulfates D. Bryant et al. 10.1021/acsearthspacechem.1c00204
- Size-dependent aerosol iron solubility in an urban atmosphere L. Liu et al. 10.1038/s41612-022-00277-z
- Direct measurement of aerosol acidity using pH testing paper and hygroscopic equilibrium under high relative humidity Q. Song & K. Osada 10.1016/j.atmosenv.2021.118605
- Biogenic and anthropogenic sources of isoprene and monoterpenes and their secondary organic aerosol in Delhi, India D. Bryant et al. 10.5194/acp-23-61-2023
- Aerosol physical characterization: A review on the current state of aerosol documentary standards and calibration strategies K. Vasilatou et al. 10.1016/j.jaerosci.2024.106483
- Elucidating the present-day chemical composition, seasonality and source regions of climate-relevant aerosols across the Arctic land surface V. Moschos et al. 10.1088/1748-9326/ac444b
- Chemical characteristics and source apportionment of particulate matter (PM2.5) in Dammam, Saudi Arabia: Impact of dust storms M. Alwadei et al. 10.1016/j.aeaoa.2022.100164
- Estimation of aerosol acidity at a suburban site of Nanjing using machine learning method M. Tao et al. 10.1007/s10874-022-09433-4
- Fine Aerosol Acidity and Water during Summer in the Eastern North Atlantic T. Nah et al. 10.3390/atmos12081040
- Source apportionment of carbonaceous aerosols in Beijing with radiocarbon and organic tracers: insight into the differences between urban and rural sites S. Hou et al. 10.5194/acp-21-8273-2021
- PM2.5-bound silicon-containing secondary organic aerosols (Si-SOA) in Beijing ambient air J. Xu et al. 10.1016/j.chemosphere.2021.132377
- Temporal Variation and Potential Sources of Water-Soluble Inorganic Ions in PM2.5 in Two Sites of Mexico City F. Millán-Vázquez et al. 10.3390/atmos14101585
- Pan-Arctic methanesulfonic acid aerosol: source regions, atmospheric drivers, and future projections J. Pernov et al. 10.1038/s41612-024-00712-3
- Sources of Aerosol Acidity at a Suburban Site of Nanjing and Their Associations with Chlorophyll Depletion J. Gong et al. 10.1021/acsearthspacechem.1c00273
- Comparison of acidity and chemical composition of summertime cloud water and aerosol at an alpine site in Northwest China: Implications for the neutral property of clouds in the free troposphere M. Shen et al. 10.1016/j.scitotenv.2024.171775
Latest update: 20 Nov 2024
Short summary
An interlaboratory comparison was conducted for the first time to examine differences in water-soluble inorganic ions (WSIIs) measured by 10 labs using ion chromatography (IC) and by two online aerosol chemical speciation monitor (ACSM) methods. Major ions including SO42−, NO3− and NH4+ agreed well in 10 IC labs and correlated well with ACSM data. WSII interlab variability strongly affected aerosol acidity results based on ion balance, but aerosol pH computed by ISORROPIA II was very similar.
An interlaboratory comparison was conducted for the first time to examine differences in...
