Articles | Volume 14, issue 10
https://doi.org/10.5194/amt-14-6835-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-14-6835-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
25 Oct 2021
Research article |
| 25 Oct 2021
| 25 Oct 2021
Quantification of isomer-resolved iodide chemical ionization mass spectrometry sensitivity and uncertainty using a voltage-scanning approach
Chenyang Bi
Department of Civil and Environmental Engineering, Virginia Tech,
Blacksburg, Virginia 24060, USA
Jordan E. Krechmer
Aerodyne Research Inc, Billerica, Massachusetts 01821, USA
Graham O. Frazier
Department of Civil and Environmental Engineering, Virginia Tech,
Blacksburg, Virginia 24060, USA
Aerodyne Research Inc, Billerica, Massachusetts 01821, USA
Andrew T. Lambe
Aerodyne Research Inc, Billerica, Massachusetts 01821, USA
Megan S. Claflin
Aerodyne Research Inc, Billerica, Massachusetts 01821, USA
Brian M. Lerner
Aerodyne Research Inc, Billerica, Massachusetts 01821, USA
John T. Jayne
Aerodyne Research Inc, Billerica, Massachusetts 01821, USA
Douglas R. Worsnop
Aerodyne Research Inc, Billerica, Massachusetts 01821, USA
Manjula R. Canagaratna
Aerodyne Research Inc, Billerica, Massachusetts 01821, USA
Department of Civil and Environmental Engineering, Virginia Tech,
Blacksburg, Virginia 24060, USA
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Cited
15 citations as recorded by crossref.
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- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- Tracking indoor volatile organic compounds with online mass spectrometry W. Liu et al. 10.1016/j.trac.2023.117514
- Formation of Highly Oxidized Organic Compounds and Secondary Organic Aerosol from α-Thujene Ozonolysis M. Dam et al. 10.1021/acs.jpca.3c02584
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Empirical Approach to Quantifying Sensitivity in Different Chemical Ionization Techniques for Organonitrates and Nitroaromatics Constrained by Ion–Molecule Reaction and Transmission Efficiency S. He et al. 10.1021/acs.analchem.4c03751
- Quantification of primary and secondary organic aerosol sources by combined factor analysis of extractive electrospray ionisation and aerosol mass spectrometer measurements (EESI-TOF and AMS) Y. Tong et al. 10.5194/amt-15-7265-2022
- Closing the Reactive Carbon Flux Budget: Observations From Dual Mass Spectrometers Over a Coniferous Forest M. Vermeuel et al. 10.1029/2023JD038753
- Isomer analysis by mass spectrometry in clinical science T. Furuhashi & W. Weckwerth 10.1016/j.trac.2022.116907
- Investigation of Gas-Phase Products from the NO3 Radical Oxidation of Δ-3-Carene O. Jenks et al. 10.1021/acsearthspacechem.3c00020
- Decomposition of Clusters of Oxygenated Compounds with NO3– by Applying Voltage Scanning to Chemical Ionization Mass Spectrometry in Steady-State Experiments H. Wang et al. 10.1021/acs.estlett.4c00276
- In-Canopy Chemistry, Emissions, Deposition, and Surface Reactivity Compete to Drive Bidirectional Forest-Atmosphere Exchange of VOC Oxidation Products M. Link et al. 10.1021/acsestair.3c00074
- Ammonium adduct chemical ionization to investigate anthropogenic oxygenated gas-phase organic compounds in urban air P. Khare et al. 10.5194/acp-22-14377-2022
- Optimizing the iodide-adduct chemical ionization mass spectrometry (CIMS) quantitative method for toluene oxidation intermediates: experimental insights into functional-group differences M. Song et al. 10.5194/amt-17-5113-2024
15 citations as recorded by crossref.
- Molecular composition of organic aerosols in urban and marine atmosphere: A comparison study using FIGAERO-I-CIMS, ESI-FT-ICR MS, and GC × GC-EI-ToF-MS X. Xin et al. 10.1080/02786826.2024.2377394
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- Tracking indoor volatile organic compounds with online mass spectrometry W. Liu et al. 10.1016/j.trac.2023.117514
- Formation of Highly Oxidized Organic Compounds and Secondary Organic Aerosol from α-Thujene Ozonolysis M. Dam et al. 10.1021/acs.jpca.3c02584
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Empirical Approach to Quantifying Sensitivity in Different Chemical Ionization Techniques for Organonitrates and Nitroaromatics Constrained by Ion–Molecule Reaction and Transmission Efficiency S. He et al. 10.1021/acs.analchem.4c03751
- Quantification of primary and secondary organic aerosol sources by combined factor analysis of extractive electrospray ionisation and aerosol mass spectrometer measurements (EESI-TOF and AMS) Y. Tong et al. 10.5194/amt-15-7265-2022
- Closing the Reactive Carbon Flux Budget: Observations From Dual Mass Spectrometers Over a Coniferous Forest M. Vermeuel et al. 10.1029/2023JD038753
- Isomer analysis by mass spectrometry in clinical science T. Furuhashi & W. Weckwerth 10.1016/j.trac.2022.116907
- Investigation of Gas-Phase Products from the NO3 Radical Oxidation of Δ-3-Carene O. Jenks et al. 10.1021/acsearthspacechem.3c00020
- Decomposition of Clusters of Oxygenated Compounds with NO3– by Applying Voltage Scanning to Chemical Ionization Mass Spectrometry in Steady-State Experiments H. Wang et al. 10.1021/acs.estlett.4c00276
- In-Canopy Chemistry, Emissions, Deposition, and Surface Reactivity Compete to Drive Bidirectional Forest-Atmosphere Exchange of VOC Oxidation Products M. Link et al. 10.1021/acsestair.3c00074
- Ammonium adduct chemical ionization to investigate anthropogenic oxygenated gas-phase organic compounds in urban air P. Khare et al. 10.5194/acp-22-14377-2022
- Optimizing the iodide-adduct chemical ionization mass spectrometry (CIMS) quantitative method for toluene oxidation intermediates: experimental insights into functional-group differences M. Song et al. 10.5194/amt-17-5113-2024
Latest update: 20 Nov 2024
Short summary
Iodide-adduct chemical ionization mass spectrometry (I-CIMS) has been widely used to analyze airborne organics. In this study, I-CIMS sensitivities of isomers within a formula are found to generally vary by 1 and up to 2 orders of magnitude. Comparisons between measured and predicted moles, obtained using a voltage-scanning calibration approach, show that predictions for individual compounds or formulas might carry high uncertainty, yet the summed moles of analytes agree reasonably well.
Iodide-adduct chemical ionization mass spectrometry (I-CIMS) has been widely used to analyze...
