Articles | Volume 14, issue 12
https://doi.org/10.5194/amt-14-7959-2021
https://doi.org/10.5194/amt-14-7959-2021
Research article
 | 
21 Dec 2021
Research article |  | 21 Dec 2021

Phosgene distribution derived from MIPAS ESA v8 data: intercomparisons and trends

Paolo Pettinari, Flavio Barbara, Simone Ceccherini, Bianca Maria Dinelli, Marco Gai, Piera Raspollini, Luca Sgheri, Massimo Valeri, Gerald Wetzel, Nicola Zoppetti, and Marco Ridolfi

Data sets

Envisat MIPAS L2 – Temperature, Pressure and Atmospheric Constituents Profiles Product European Space Agency https://doi.org/10.5270/EN1-c8hgqx4

Atmospheric Chemistry Experiment SciSat Level 2 Processed Data, v3.5/v3.6 (http://www.ace.uwaterloo.ca/data.php) P. Bernath, C. Boone, J. Steffen, and J. Crouse https://doi.org/10.20383/102.0495

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Short summary
Phosgene (COCl2) is a toxic gas whose presence is a consequence of human activity. Besides its direct injection in the troposphere, stratospheric COCl2 is produced from the decomposition of CCl4, an anthropogenic gas regulated by the Montreal Protocol. As a consequence, COCl2 negative trends characterize the lower and part of the middle stratosphere. However, we find positive trends in the upper troposphere, demonstrating the non-negligible role of other Cl-containing species not yet regulated.