Articles | Volume 15, issue 12
https://doi.org/10.5194/amt-15-3747-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-15-3747-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
High-frequency gaseous and particulate chemical characterization using extractive electrospray ionization mass spectrometry (Dual-Phase-EESI-TOF)
Chuan Ping Lee
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Mihnea Surdu
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
David M. Bell
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Josef Dommen
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Mao Xiao
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Xueqin Zhou
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Andrea Baccarini
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Extreme Environments Research Laboratory, École Polytechnique Fédérale de Lausanne, 1951 Sion, Switzerland
Stamatios Giannoukos
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Laboratory of Organic Chemistry, Department of Chemistry and Applied Bioscience, ETH Zurich, 8093 Zurich, Switzerland
Günther Wehrle
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Pascal André Schneider
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Andre S. H. Prevot
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Jay G. Slowik
CORRESPONDING AUTHOR
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Houssni Lamkaddam
CORRESPONDING AUTHOR
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Urs Baltensperger
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI),
5232 Villigen, Switzerland
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Cited
13 citations as recorded by crossref.
- A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis J. Zhao et al. 10.5194/acp-23-3707-2023
- Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al. 10.1021/acsestair.4c00121
- An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles L. Caudillo et al. 10.5194/acp-23-6613-2023
- Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities X. Li et al. 10.1016/j.trac.2023.117195
- Effects of Relative Humidity and Phase on the Molecular Detection of Nascent Sea Spray Aerosol Using Extractive Electrospray Ionization S. Kruse et al. 10.1021/acs.analchem.4c02871
- Insights into the formation of secondary organic aerosols from agricultural residue burning emissions: A review of chamber-based studies S. Joshi et al. 10.1016/j.scitotenv.2024.175932
- Molecular identification of organic acid molecules from α-pinene ozonolysis J. Gao et al. 10.1016/j.atmosenv.2023.120052
- Sensitivity Constraints of Extractive Electrospray for a Model System and Secondary Organic Aerosol D. Bell et al. 10.1021/acs.analchem.3c00441
- NO3− loss from nitrate adducts of explosives by thermal decomposition in tandem Ion mobility spectrometry and by collision induced dissociation in tandem mass spectrometry A. Haack et al. 10.1016/j.ijms.2024.117235
- Large contribution of in-cloud production of secondary organic aerosol from biomass burning emissions T. Wang et al. 10.1038/s41612-024-00682-6
- Isomer-Resolved Mobility-Mass Analysis of α-Pinene Ozonolysis Products A. Skyttä et al. 10.1021/acs.jpca.2c03366
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
- High-frequency gaseous and particulate chemical characterization using extractive electrospray ionization mass spectrometry (Dual-Phase-EESI-TOF) C. Lee et al. 10.5194/amt-15-3747-2022
12 citations as recorded by crossref.
- A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis J. Zhao et al. 10.5194/acp-23-3707-2023
- Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al. 10.1021/acsestair.4c00121
- An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles L. Caudillo et al. 10.5194/acp-23-6613-2023
- Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities X. Li et al. 10.1016/j.trac.2023.117195
- Effects of Relative Humidity and Phase on the Molecular Detection of Nascent Sea Spray Aerosol Using Extractive Electrospray Ionization S. Kruse et al. 10.1021/acs.analchem.4c02871
- Insights into the formation of secondary organic aerosols from agricultural residue burning emissions: A review of chamber-based studies S. Joshi et al. 10.1016/j.scitotenv.2024.175932
- Molecular identification of organic acid molecules from α-pinene ozonolysis J. Gao et al. 10.1016/j.atmosenv.2023.120052
- Sensitivity Constraints of Extractive Electrospray for a Model System and Secondary Organic Aerosol D. Bell et al. 10.1021/acs.analchem.3c00441
- NO3− loss from nitrate adducts of explosives by thermal decomposition in tandem Ion mobility spectrometry and by collision induced dissociation in tandem mass spectrometry A. Haack et al. 10.1016/j.ijms.2024.117235
- Large contribution of in-cloud production of secondary organic aerosol from biomass burning emissions T. Wang et al. 10.1038/s41612-024-00682-6
- Isomer-Resolved Mobility-Mass Analysis of α-Pinene Ozonolysis Products A. Skyttä et al. 10.1021/acs.jpca.2c03366
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
Latest update: 06 Nov 2024
Short summary
Real-time detection of both the gas and particle phase is needed to elucidate the sources and chemical reaction pathways of organic vapors and particulate matter. The Dual-EESI was developed to measure gas- and particle-phase species to provide new insights into aerosol sources or formation mechanisms. After characterizing the relative gas and particle response factors of EESI via organic aerosol uptake experiments, the Dual-EESI is more sensitive toward gas-phase analyes.
Real-time detection of both the gas and particle phase is needed to elucidate the sources and...