Articles | Volume 17, issue 9
https://doi.org/10.5194/amt-17-2917-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-17-2917-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 May 2024
Research article |
| 14 May 2024
| 14 May 2024
Field comparison of dual- and single-spot Aethalometers: equivalent black carbon, light absorption, Ångström exponent and secondary brown carbon estimations
Liangbin Wu
Institute of Mass Spectrometry and Atmospheric Environment, Guangdong Provincial Engineering Research Center for Online Source Apportionment System of Air Pollution, Jinan University, Guangzhou 510632, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou 510632, China
Guangdong MS Institute of Scientific Instrument Innovation, Guangzhou 510530, China
Institute of Mass Spectrometry and Atmospheric Environment, Guangdong Provincial Engineering Research Center for Online Source Apportionment System of Air Pollution, Jinan University, Guangzhou 510632, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou 510632, China
Guangdong MS Institute of Scientific Instrument Innovation, Guangzhou 510530, China
Tao Deng
Institute of Tropical and Marine Meteorology, CMA, Guangzhou 510080, China
Institute of Mass Spectrometry and Atmospheric Environment, Guangdong Provincial Engineering Research Center for Online Source Apportionment System of Air Pollution, Jinan University, Guangzhou 510632, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou 510632, China
Guangdong MS Institute of Scientific Instrument Innovation, Guangzhou 510530, China
Mei Li
Institute of Mass Spectrometry and Atmospheric Environment, Guangdong Provincial Engineering Research Center for Online Source Apportionment System of Air Pollution, Jinan University, Guangzhou 510632, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou 510632, China
Guangdong MS Institute of Scientific Instrument Innovation, Guangzhou 510530, China
Yong Jie Li
Department of Civil and Environmental Engineering, Faculty of Science and Technology, University of Macau, Taipa, Macau SAR, China
Department of Ocean Science and Technology, Faculty of Science and Technology, University of Macau, Taipa, Macau SAR, China
Zhen Zhou
Institute of Mass Spectrometry and Atmospheric Environment, Guangdong Provincial Engineering Research Center for Online Source Apportionment System of Air Pollution, Jinan University, Guangzhou 510632, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Guangzhou 510632, China
Guangdong MS Institute of Scientific Instrument Innovation, Guangzhou 510530, China
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Song Liu, Xiaopu Lyu, Fumo Yang, Zongbo Shi, Xin Huang, Tengyu Liu, Hongli Wang, Mei Li, Jian Gao, Nan Chen, Guoliang Shi, Yu Zou, Chenglei Pei, Chengxu Tong, Xinyi Liu, Li Zhou, Alex B. Guenther, and Nan Wang
EGUsphere, https://doi.org/10.5194/egusphere-2025-4644, https://doi.org/10.5194/egusphere-2025-4644, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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We studied the invisible gas isoprene, which trees and vehicles release into the air and which can worsen urban smog. Using advanced computer learning trained on measurements from many cities, we uncovered how temperature, sunlight, and city greening shape isoprene levels. Comparing Hong Kong and London, we found climate warming boosts isoprene and future ozone pollution, but strong cuts in traffic pollution could limit this impact.
Donger Lai, Yanxin Bai, Zijing Zhang, Pui-Kin So, Yong Jie Li, Ying-Lung Steve Tse, Ying-Yeung Yeung, Thomas Schaefer, Hartmut Herrmann, Jian Zhen Yu, Yuchen Wang, and Man Nin Chan
Atmos. Chem. Phys., 25, 12569–12584, https://doi.org/10.5194/acp-25-12569-2025, https://doi.org/10.5194/acp-25-12569-2025, 2025
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Aqueous-phase •OH oxidation can potentially act as an important atmospheric sink for α-pinene-derived organosulfates (OSs). Such oxidation can also generate a variety of new OS products, and can be as a potential source for some atmospheric OSs with previously unknown origins.
Junlin Shen, Ye Kuang, Li Liu, Fengling Yuan, Biao Luo, Hongqing Qiao, Miaomiao Zhai, Gang Zhao, Hanbing Xu, Fei Li, Yu Zou, Tao Deng, and Xuejiao Deng
Atmos. Chem. Phys., 25, 11233–11246, https://doi.org/10.5194/acp-25-11233-2025, https://doi.org/10.5194/acp-25-11233-2025, 2025
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This study provides direct observational evidence that secondary organic aerosol formation enhances the aerosol scattering refractive index and has substantially higher real refractive indices than primary organic aerosols in humid southern China, challenging current model assumptions and offering recommended values that might improve the accuracy of aerosol radiative effect simulations.
Jinwen Zhang, Yongjian Liang, Chenglei Pei, Bo Huang, Yingyan Huang, Xiufeng Lian, Shaojie Song, Chunlei Cheng, Cheng Wu, Zhen Zhou, Junjie Li, and Mei Li
EGUsphere, https://doi.org/10.5194/egusphere-2025-3215, https://doi.org/10.5194/egusphere-2025-3215, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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Inadequate characterization of carbon dioxide (CO2) dynamics limits understanding of coastal megacity carbon cycles. Using a novel framework integrating high-precision observations, this study reveals nonlinear sea–land breeze effects, quantifies urban vegetation’s role in CO2 budgets, and tracks policy-driven combustion efficiency via declining ΔCO/ΔCO2 ratios, offering new insights into coastal CO2 cycling.
Xiufeng Lian, Yongjiang Xu, Fengxian Liu, Long Peng, Xiaodong Hu, Guigang Tang, Xu Dao, Hui Guo, Liwei Wang, Bo Huang, Chunlei Cheng, Lei Li, Guohua Zhang, Xinhui Bi, Xiaofei Wang, Zhen Zhou, and Mei Li
Atmos. Chem. Phys., 25, 8891–8905, https://doi.org/10.5194/acp-25-8891-2025, https://doi.org/10.5194/acp-25-8891-2025, 2025
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In this study, we analyzed the mixing state and atmospheric chemical processes of Pb-rich single particles in Beijing. We focused on analyzing the differences in Pb-rich particles between the heating period and non-heating period, as well as the formation mechanism of lead nitrate after coal-to-gas conversion. Our results highlighted the improvement of Pb levels in the particulate as a result of coal-to-gas conversion.
Xi Chen, Xiaoyang Chen, Long Wang, Shucheng Chang, Minhui Li, Chong Shen, Chenghao Liao, Yongbo Zhang, Mei Li, and Xuemei Wang
EGUsphere, https://doi.org/10.5194/egusphere-2025-2635, https://doi.org/10.5194/egusphere-2025-2635, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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Typhoons moving north near China create ozone pollution in Guangdong by combining strong sunlight with stagnant air. These tyhoons also push ozone-rich air from high altitudes down to ground level. When multiple north-moving typhoons occur back-to-back, they cause widespread and long-lasting ozone pollution. Vertical air currents during these events can contribute up to 16 % of boundary layer ozone.
Qianying Liu, Dan Dan Huang, Andrew T. Lambe, Shengrong Lou, Lulu Zeng, Yuhang Wu, Congyan Huang, Shikang Tao, Xi Cheng, Qi Chen, Ka In Hoi, Hongli Wang, Kai Meng Mok, Cheng Huang, and Yong Jie Li
Atmos. Meas. Tech., 18, 2509–2521, https://doi.org/10.5194/amt-18-2509-2025, https://doi.org/10.5194/amt-18-2509-2025, 2025
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We evaluate the applicability of empirical equations to estimate OH exposure (OHexp) in an oxidative flow reactor (OFR). The fitting parameters obtained within a narrow range of conditions can generally be extended to estimate the OHexp for wide ranges of conditions in the OFR, except for external OH reactivity, which requires new fitting. At least 20–30 data points from SO2 or CO decay with varying conditions are required to fit a set of empirical parameters that can accurately estimate OHexp.
Weichao Huang, Sihang Wang, Peng Cheng, Bingna Chen, Bin Yuan, Pengfei Yu, Haichao Wang, Nan Ma, Mei Li, and Keding Lu
EGUsphere, https://doi.org/10.5194/egusphere-2025-1835, https://doi.org/10.5194/egusphere-2025-1835, 2025
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We studied vehicle emissions from 10 3000-metre tunnels in the Qinghai-Tibet plateau. Since low pressure causes fuel evaporation, emissions of volatile organic compounds rise with elevation, unlike in low-altitude areas where exhaust gas is predominant. This indicates the need for specific emission control measures. Electric vehicles can use renewable energy in Tibet to reduce emissions. The study aims to understand emissions at high altitudes and guide cleaner transport.
Fangbing Li, Dan Dan Huang, Linhui Tian, Bin Yuan, Wen Tan, Liang Zhu, Penglin Ye, Douglas Worsnop, Ka In Hoi, Kai Meng Mok, and Yong Jie Li
Atmos. Meas. Tech., 17, 2415–2427, https://doi.org/10.5194/amt-17-2415-2024, https://doi.org/10.5194/amt-17-2415-2024, 2024
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The responses of protonated, adduct, and fragmented ions of 21 volatile organic compounds (VOCs) were investigated with varying instrument settings and relative humidity (RH) in a Vocus proton-transfer-reaction mass spectrometer (PTR-MS). The protonated ions of most VOCs studied show < 15 % variation in sensitivity, except for some long-chain aldehydes. The relationship between sensitivity and PTR rate constant is complicated by the influences from ion transmission and protonated ion fraction.
Xi Cheng, Yong Jie Li, Yan Zheng, Keren Liao, Theodore K. Koenig, Yanli Ge, Tong Zhu, Chunxiang Ye, Xinghua Qiu, and Qi Chen
Atmos. Chem. Phys., 24, 2099–2112, https://doi.org/10.5194/acp-24-2099-2024, https://doi.org/10.5194/acp-24-2099-2024, 2024
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In this study we conducted laboratory measurements to investigate the formation of gas-phase oxygenated organic molecules (OOMs) from six aromatic volatile organic compounds (VOCs). We provide a thorough analysis on the effects of precursor structure (substituents and ring numbers) on product distribution and highlight from a laboratory perspective that heavy (e.g., double-ring) aromatic VOCs are important in initial particle growth during secondary organic aerosol formation.
Xubing Du, Qinhui Xie, Qing Huang, Xuan Li, Junlin Yang, Zhihui Hou, Jingjing Wang, Xue Li, Zhen Zhou, Zhengxu Huang, Wei Gao, and Lei Li
Atmos. Meas. Tech., 17, 1037–1050, https://doi.org/10.5194/amt-17-1037-2024, https://doi.org/10.5194/amt-17-1037-2024, 2024
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Currently, the limitations of single-particle mass spectrometry detection capabilities render it not yet well suited for analyzing complex aerosol components in low-concentration environments. In this study, a new high-performance single-particle aerosol mass spectrometer (HP-SPAMS) is developed to enhance instrument performance regarding the number of detected particles, transmission efficiency, resolution, and sensitivity, which will help in aerosol science.
Nan Wang, Hongyue Wang, Xin Huang, Xi Chen, Yu Zou, Tao Deng, Tingyuan Li, Xiaopu Lyu, and Fumo Yang
Atmos. Chem. Phys., 24, 1559–1570, https://doi.org/10.5194/acp-24-1559-2024, https://doi.org/10.5194/acp-24-1559-2024, 2024
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This study explores the influence of extreme-weather-induced natural processes on ozone pollution, which is often overlooked. By analyzing meteorological factors, natural emissions, chemistry pathways and atmospheric transport, we discovered that these natural processes could substantially exacerbate ozone pollution. The findings contribute to a deeper understanding of ozone pollution and offer valuable insights for controlling ozone pollution in the context of global warming.
Guowen He, Cheng He, Haofan Wang, Xiao Lu, Chenglei Pei, Xiaonuan Qiu, Chenxi Liu, Yiming Wang, Nanxi Liu, Jinpu Zhang, Lei Lei, Yiming Liu, Haichao Wang, Tao Deng, Qi Fan, and Shaojia Fan
Atmos. Chem. Phys., 23, 13107–13124, https://doi.org/10.5194/acp-23-13107-2023, https://doi.org/10.5194/acp-23-13107-2023, 2023
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We analyze nighttime ozone in the lower boundary layer (up to 500 m) from the 2017–2019 measurements at the Canton Tower and the WRF-CMAQ model. We identify a strong ability of the residual layer to store daytime ozone in the convective mixing layer, investigate the chemical and meteorological factors controlling nighttime ozone in the residual layer, and quantify the contribution of nighttime ozone in the residual layer to both the nighttime and the following day’s surface ozone air quality.
Bojiang Su, Xinhui Bi, Zhou Zhang, Yue Liang, Congbo Song, Tao Wang, Yaohao Hu, Lei Li, Zhen Zhou, Jinpei Yan, Xinming Wang, and Guohua Zhang
Atmos. Chem. Phys., 23, 10697–10711, https://doi.org/10.5194/acp-23-10697-2023, https://doi.org/10.5194/acp-23-10697-2023, 2023
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During the R/V Xuelong cruise observation over the Ross Sea, Antarctica, the mass concentrations of water-soluble Ca2+ and the mass spectra of individual calcareous particles were measured. Our results indicated that lower temperature, lower wind speed, and the presence of sea ice may facilitate Ca2+ enrichment in sea spray aerosols and highlighted the potential contribution of organically complexed calcium to calcium enrichment, which is inaccurate based solely on water-soluble Ca2+ estimation.
Fei Li, Biao Luo, Miaomiao Zhai, Li Liu, Gang Zhao, Hanbing Xu, Tao Deng, Xuejiao Deng, Haobo Tan, Ye Kuang, and Jun Zhao
Atmos. Chem. Phys., 23, 6545–6558, https://doi.org/10.5194/acp-23-6545-2023, https://doi.org/10.5194/acp-23-6545-2023, 2023
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A field campaign was conducted to study black carbon (BC) mass size distributions and mixing states connected to traffic emissions using a system that combines a differential mobility analyzer and single-particle soot photometer. Results showed that the black carbon content of traffic emissions has a considerable influence on both BC mass size distributions and mixing states, which has crucial implications for accurately representing BC from various sources in regional and climate models.
Yifang Gu, Ru-Jin Huang, Jing Duan, Wei Xu, Chunshui Lin, Haobin Zhong, Ying Wang, Haiyan Ni, Quan Liu, Ruiguang Xu, Litao Wang, and Yong Jie Li
Atmos. Chem. Phys., 23, 5419–5433, https://doi.org/10.5194/acp-23-5419-2023, https://doi.org/10.5194/acp-23-5419-2023, 2023
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Secondary organic aerosol (SOA) can be produced by various pathways, but its formation mechanisms are unclear. Observations were conducted in the North China Plain during a highly oxidizing atmosphere in summer. We found that fast photochemistry dominated SOA formation during daytime. Two types of aqueous-phase chemistry (nocturnal and daytime processing) take place at high relative humidity. The potential transformation from primary organic aerosol (POA) to SOA was also an important pathway.
Liyuan Zhou, Zhancong Liang, Brix Raphael Go, Rosemarie Ann Infante Cuevas, Rongzhi Tang, Mei Li, Chunlei Cheng, and Chak K. Chan
Atmos. Chem. Phys., 23, 5251–5261, https://doi.org/10.5194/acp-23-5251-2023, https://doi.org/10.5194/acp-23-5251-2023, 2023
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This study reveals the sulfate formation in photosensitized particles from biomass burning under UV and SO2, of which the relative atmospheric importance in sulfate production was qualitatively compared to nitrate photolysis. On the basis of single-particle aerosol mass spectrometry measurements, the number percentage of sulfate-containing particles and relative peak area of sulfate in single-particle spectra exhibited a descending order of 3,4-dimethoxybenzaldehyde > vanillin > syringaldehyde.
Brix Raphael Go, Yong Jie Li, Dan Dan Huang, Yalin Wang, and Chak K. Chan
Atmos. Chem. Phys., 23, 2859–2875, https://doi.org/10.5194/acp-23-2859-2023, https://doi.org/10.5194/acp-23-2859-2023, 2023
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We compared non-phenolic and phenolic methoxybenzaldehydes as photosensitizers for aqueous secondary organic aerosol (aqSOA) formation under cloud and fog conditions. We showed that the structural features of photosensitizers affect aqSOA formation. We also elucidated potential interactions between photosensitization and ammonium nitrate photolysis. Our findings are useful for evaluating the importance of photosensitized reactions on aqSOA formation, which could improve aqSOA predictive models.
Tingting Feng, Yingkun Wang, Weiwei Hu, Ming Zhu, Wei Song, Wei Chen, Yanyan Sang, Zheng Fang, Wei Deng, Hua Fang, Xu Yu, Cheng Wu, Bin Yuan, Shan Huang, Min Shao, Xiaofeng Huang, Lingyan He, Young Ro Lee, Lewis Gregory Huey, Francesco Canonaco, Andre S. H. Prevot, and Xinming Wang
Atmos. Chem. Phys., 23, 611–636, https://doi.org/10.5194/acp-23-611-2023, https://doi.org/10.5194/acp-23-611-2023, 2023
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To investigate the impact of aging processes on organic aerosols (OA), we conducted a comprehensive field study at a continental remote site using an on-line mass spectrometer. The results show that OA in the Chinese outflows were strongly influenced by upwind anthropogenic emissions. The aging processes can significantly decrease the OA volatility and result in a varied viscosity of OA under different circumstances, signifying the complex physiochemical properties of OA in aged plumes.
Zhancong Liang, Liyuan Zhou, Xinyue Li, Rosemarie Ann Infante Cuevas, Rongzhi Tang, Mei Li, Chunlei Cheng, Yangxi Chu, and Chak Keung Chan
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-838, https://doi.org/10.5194/acp-2022-838, 2022
Preprint withdrawn
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Incense burning is a common religious ritual, especially in Asian and African communities, with massive particles emitted. While previous research mainly focused on the chemical compositions and potential health impacts of fresh incense particles, our work reveals that nitrate, accompanied by SOA, can rapidly form in incense-burning particles upon photochemical oxidation in the atmosphere. This finding could deepen our understanding of air pollution caused by religious activities.
Shanshan Ouyang, Tao Deng, Run Liu, Jingyang Chen, Guowen He, Jeremy Cheuk-Hin Leung, Nan Wang, and Shaw Chen Liu
Atmos. Chem. Phys., 22, 10751–10767, https://doi.org/10.5194/acp-22-10751-2022, https://doi.org/10.5194/acp-22-10751-2022, 2022
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A record-breaking severe O3 pollution episode occurred under the influence of a Pacific subtropical high followed by Typhoon Mitag in the Pearl River Delta (PRD) in early Autumn 2019. Through WRF-CMAQ model simulations, we propose that the enhanced photochemical production of O3 during the episode is a major cause of the most severe O3 pollution year since the official O3 observation started in the PRD in 2006.
Xuan Li, Lei Li, Zeming Zhuo, Guohua Zhang, Xubing Du, Xue Li, Zhengxu Huang, Zhen Zhou, and Zhi Cheng
EGUsphere, https://doi.org/10.5194/egusphere-2022-598, https://doi.org/10.5194/egusphere-2022-598, 2022
Preprint archived
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The particle size and chemical composition of bioaerosol were analyzed based on single particle aerosol mass spectrometer. Fungal aerosol of 10 μm was measured for the first time and the characteristic spectrum of bioaerosol was updated. The ion peak ratio method can distinguish bioaerosols from interferers by 97 %. The factors influencing the differentiation of bioaerosols are also discussed. Single particle mass spectrometry can be a new method for real-time identification of bioaerosols.
Mingfu Cai, Shan Huang, Baoling Liang, Qibin Sun, Li Liu, Bin Yuan, Min Shao, Weiwei Hu, Wei Chen, Qicong Song, Wei Li, Yuwen Peng, Zelong Wang, Duohong Chen, Haobo Tan, Hanbin Xu, Fei Li, Xuejiao Deng, Tao Deng, Jiaren Sun, and Jun Zhao
Atmos. Chem. Phys., 22, 8117–8136, https://doi.org/10.5194/acp-22-8117-2022, https://doi.org/10.5194/acp-22-8117-2022, 2022
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This study investigated the size dependence and diurnal variation in organic aerosol hygroscopicity, volatility, and cloud condensation nuclei (CCN) activity. We found that the physical properties of OA could vary in a large range at different particle sizes and affected the number concentration of CCN (NCCN) at all supersaturations. Our results highlight the importance of evaluating the atmospheric evolution processes of OA at different size ranges and their impact on climate effects.
Li Liu, Ye Kuang, Miaomiao Zhai, Biao Xue, Yao He, Jun Tao, Biao Luo, Wanyun Xu, Jiangchuan Tao, Changqin Yin, Fei Li, Hanbing Xu, Tao Deng, Xuejiao Deng, Haobo Tan, and Min Shao
Atmos. Chem. Phys., 22, 7713–7726, https://doi.org/10.5194/acp-22-7713-2022, https://doi.org/10.5194/acp-22-7713-2022, 2022
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Using simultaneous measurements of a humidified nephelometer system and an aerosol chemical speciation monitor in winter in Guangzhou, the strongest scattering ability of more oxidized oxygenated organic aerosol (MOOA) among aerosol components considering their dry-state scattering ability and water uptake ability was revealed, leading to large impacts of MOOA on visibility degradation. This has important implications for visibility improvement in China and aerosol radiative effect simulation.
Jiaxing Sun, Zhe Wang, Wei Zhou, Conghui Xie, Cheng Wu, Chun Chen, Tingting Han, Qingqing Wang, Zhijie Li, Jie Li, Pingqing Fu, Zifa Wang, and Yele Sun
Atmos. Chem. Phys., 22, 561–575, https://doi.org/10.5194/acp-22-561-2022, https://doi.org/10.5194/acp-22-561-2022, 2022
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We analyzed 9-year measurements of BC and aerosol optical properties from 2012 to 2020 in Beijing, China. Our results showed large reductions in BC and light extinction coefficient due to the Clean Air Action Plan. As a response, both SSA and mass extinction efficiency (MEE) showed considerable increases, demonstrating a future challenge in visibility improvement. The primary and secondary BrC was also separated and quantified, and the changes in radiative forcing of BC and BrC were estimated.
Brix Raphael Go, Yan Lyu, Yan Ji, Yong Jie Li, Dan Dan Huang, Xue Li, Theodora Nah, Chun Ho Lam, and Chak K. Chan
Atmos. Chem. Phys., 22, 273–293, https://doi.org/10.5194/acp-22-273-2022, https://doi.org/10.5194/acp-22-273-2022, 2022
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Biomass burning (BB) is a global phenomenon that releases large quantities of pollutants such as phenols and aromatic carbonyls into the atmosphere. These compounds can form secondary organic aerosols (SOAs) which play an important role in the Earth’s energy budget. In this work, we demonstrated that the direct irradiation of vanillin (VL) could generate aqueous SOA (aqSOA) such as oligomers. In the presence of nitrate, VL photo-oxidation can also form nitrated compounds.
Qi En Zhong, Chunlei Cheng, Zaihua Wang, Lei Li, Mei Li, Dafeng Ge, Lei Wang, Yuanyuan Li, Wei Nie, Xuguang Chi, Aijun Ding, Suxia Yang, Duohong Chen, and Zhen Zhou
Atmos. Chem. Phys., 21, 17953–17967, https://doi.org/10.5194/acp-21-17953-2021, https://doi.org/10.5194/acp-21-17953-2021, 2021
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Particulate amines play important roles in new particle formation, aerosol acidity, and hygroscopicity. Most of the field observations did not distinguish the different behavior of each type amine under the same ambient influencing factors. In this study, two amine-containing single particles exhibited different mixing states and disparate enrichment of secondary organics, which provide insight into the discriminated fates of organics during the formation and evolution processes.
Xi Cheng, Qi Chen, Yong Jie Li, Yan Zheng, Keren Liao, and Guancong Huang
Atmos. Chem. Phys., 21, 12005–12019, https://doi.org/10.5194/acp-21-12005-2021, https://doi.org/10.5194/acp-21-12005-2021, 2021
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In this study, we conducted laboratory studies to investigate the formation of gas-phase highly oxygenated organic molecules (HOMs). We provide a thorough analysis on the importance of multistep auto-oxidation and multigeneration OH reactions. We also give an intensive investigation on the roles of high-NO2 conditions that represent a wide range of anthropogenically influenced environments.
Johannes Passig, Julian Schade, Robert Irsig, Lei Li, Xue Li, Zhen Zhou, Thomas Adam, and Ralf Zimmermann
Atmos. Meas. Tech., 14, 4171–4185, https://doi.org/10.5194/amt-14-4171-2021, https://doi.org/10.5194/amt-14-4171-2021, 2021
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Ships are major sources of air pollution; however, monitoring of ship emissions outside harbours is a challenging task. We optimized single-particle mass spectrometry (SPMS) for the detection of bunker fuel emissions and demonstrate the detection of individual ship plumes from more than 10 km in distance. The approach works independently of background air pollution and also when ships use exhaust-cleaning scrubbers. We discuss the potential and limits of SPMS-based monitoring of ship plumes.
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Short summary
Field comparison of dual-spot (AE33) and single-spot (AE31) Aethalometers by full-year collocated measurements suggests that site-specific correction factors are needed to ensure the long-term data continuity for AE31-to-AE33 transition in black carbon monitoring networks; babs agrees well between AE33 and AE31, with slight variations by wavelength (slope: 0.87–1.04; R2: 0.95–0.97). A ~ 20 % difference in secondary brown carbon light absorption was found between AE33 and AE31.
Field comparison of dual-spot (AE33) and single-spot (AE31) Aethalometers by full-year...
