Articles | Volume 18, issue 20
https://doi.org/10.5194/amt-18-5435-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-18-5435-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
16 Oct 2025
Research article |
| 16 Oct 2025
| 16 Oct 2025
Interlaboratory comparison of continuous flow analysis (CFA) systems for high-resolution water isotope measurements in ice cores
Ca' Foscari of Venice, Department of Environmental Sciences, Informatics and Statistics, Mestre (Venice), Italy
LSCE/IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
Elise Fourré
LSCE/IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
Elsa Gautier
Université Grenoble Alpes, CNRS, IRD, Grenoble INP, INRAE, IGE, 38000 Grenoble, France
Azzurra Spagnesi
Institute of Polar Sciences, National Research Council of Italy, Venice, Italy
Ca' Foscari of Venice, Department of Environmental Sciences, Informatics and Statistics, Mestre (Venice), Italy
Roxanne Jacob
LSCE/IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
Pete D. Akers
Université Grenoble Alpes, CNRS, IRD, Grenoble INP, INRAE, IGE, 38000 Grenoble, France
Geography, School of Natural Sciences, Trinity College Dublin, Dublin, Ireland
Daniele Zannoni
Ca' Foscari of Venice, Department of Environmental Sciences, Informatics and Statistics, Mestre (Venice), Italy
Jacopo Gabrieli
Institute of Polar Sciences, National Research Council of Italy, Venice, Italy
Olivier Jossoud
LSCE/IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
Frédéric Prié
LSCE/IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
Amaëlle Landais
LSCE/IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
Titouan Tcheng
LSCE/IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
Barbara Stenni
Ca' Foscari of Venice, Department of Environmental Sciences, Informatics and Statistics, Mestre (Venice), Italy
Joel Savarino
Université Grenoble Alpes, CNRS, IRD, Grenoble INP, INRAE, IGE, 38000 Grenoble, France
Patrick Ginot
Université Grenoble Alpes, CNRS, IRD, Grenoble INP, INRAE, IGE, 38000 Grenoble, France
Mathieu Casado
LSCE/IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
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Revised manuscript accepted for AR
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Brice Barret, Patrice Medina, Natalie Brett, Roman Pohorsky, Kathy S. Law, Slimane Bekki, Gilberto J. Fochesatto, Julia Schmale, Steve R. Arnold, Andrea Baccarini, Maurizio Busetto, Meeta Cesler-Maloney, Barbara D'Anna, Stefano Decesari, Jingqiu Mao, Gianluca Pappaccogli, Joel Savarino, Federico Scoto, and William R. Simpson
Atmos. Meas. Tech., 18, 1163–1184, https://doi.org/10.5194/amt-18-1163-2025, https://doi.org/10.5194/amt-18-1163-2025, 2025
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Thomas Lauwers, Elise Fourré, Olivier Jossoud, Daniele Romanini, Frédéric Prié, Giordano Nitti, Mathieu Casado, Kévin Jaulin, Markus Miltner, Morgane Farradèche, Valérie Masson-Delmotte, and Amaëlle Landais
Atmos. Meas. Tech., 18, 1135–1147, https://doi.org/10.5194/amt-18-1135-2025, https://doi.org/10.5194/amt-18-1135-2025, 2025
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Natalie Brett, Kathy S. Law, Steve R. Arnold, Javier G. Fochesatto, Jean-Christophe Raut, Tatsuo Onishi, Robert Gilliam, Kathleen Fahey, Deanna Huff, George Pouliot, Brice Barret, Elsa Dieudonné, Roman Pohorsky, Julia Schmale, Andrea Baccarini, Slimane Bekki, Gianluca Pappaccogli, Federico Scoto, Stefano Decesari, Antonio Donateo, Meeta Cesler-Maloney, William Simpson, Patrice Medina, Barbara D'Anna, Brice Temime-Roussel, Joel Savarino, Sarah Albertin, Jingqiu Mao, Becky Alexander, Allison Moon, Peter F. DeCarlo, Vanessa Selimovic, Robert Yokelson, and Ellis S. Robinson
Atmos. Chem. Phys., 25, 1063–1104, https://doi.org/10.5194/acp-25-1063-2025, https://doi.org/10.5194/acp-25-1063-2025, 2025
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Inès Ollivier, Hans Christian Steen-Larsen, Barbara Stenni, Laurent Arnaud, Mathieu Casado, Alexandre Cauquoin, Giuliano Dreossi, Christophe Genthon, Bénédicte Minster, Ghislain Picard, Martin Werner, and Amaëlle Landais
The Cryosphere, 19, 173–200, https://doi.org/10.5194/tc-19-173-2025, https://doi.org/10.5194/tc-19-173-2025, 2025
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The role of post-depositional processes taking place at the ice sheet's surface on the water stable isotope signal measured in polar ice cores is not fully understood. Using field observations and modelling results, we show that the original precipitation isotopic signal at Dome C, East Antarctica, is modified by post-depositional processes and provide the first quantitative estimation of their mean impact on the isotopic signal observed in the snow.
Frédéric Parrenin, Marie Bouchet, Christo Buizert, Emilie Capron, Ellen Corrick, Russell Drysdale, Kenji Kawamura, Amaëlle Landais, Robert Mulvaney, Ikumi Oyabu, and Sune Olander Rasmussen
Geosci. Model Dev., 17, 8735–8750, https://doi.org/10.5194/gmd-17-8735-2024, https://doi.org/10.5194/gmd-17-8735-2024, 2024
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Clément Piel, Daniele Romanini, Morgane Farradèche, Justin Chaillot, Clémence Paul, Nicolas Bienville, Thomas Lauwers, Joana Sauze, Kévin Jaulin, Frédéric Prié, and Amaëlle Landais
Atmos. Meas. Tech., 17, 6647–6658, https://doi.org/10.5194/amt-17-6647-2024, https://doi.org/10.5194/amt-17-6647-2024, 2024
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Valeria Mardoñez-Balderrama, Griša Močnik, Marco Pandolfi, Robin L. Modini, Fernando Velarde, Laura Renzi, Angela Marinoni, Jean-Luc Jaffrezo, Isabel Moreno R., Diego Aliaga, Federico Bianchi, Claudia Mohr, Martin Gysel-Beer, Patrick Ginot, Radovan Krejci, Alfred Wiedensohler, Gaëlle Uzu, Marcos Andrade, and Paolo Laj
Atmos. Chem. Phys., 24, 12055–12077, https://doi.org/10.5194/acp-24-12055-2024, https://doi.org/10.5194/acp-24-12055-2024, 2024
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Levels of black carbon (BC) are scarcely reported in the Southern Hemisphere, especially in high-altitude conditions. This study provides insight into the concentration level, variability, and optical properties of BC in La Paz and El Alto and at the Chacaltaya Global Atmosphere Watch Station. Two methods of source apportionment of absorption were tested and compared showing traffic as the main contributor to absorption in the urban area, in addition to biomass and open waste burning.
Giuliano Dreossi, Mauro Masiol, Barbara Stenni, Daniele Zannoni, Claudio Scarchilli, Virginia Ciardini, Mathieu Casado, Amaëlle Landais, Martin Werner, Alexandre Cauquoin, Giampietro Casasanta, Massimo Del Guasta, Vittoria Posocco, and Carlo Barbante
The Cryosphere, 18, 3911–3931, https://doi.org/10.5194/tc-18-3911-2024, https://doi.org/10.5194/tc-18-3911-2024, 2024
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Oxygen and hydrogen stable isotopes have been extensively used to reconstruct past temperatures, with precipitation representing the input signal of the isotopic records in ice cores. We present a 10-year record of stable isotopes in daily precipitation at Concordia Station: this is the longest record for inland Antarctica and represents a benchmark for quantifying post-depositional processes and improving the paleoclimate interpretation of ice cores.
Romilly Harris Stuart, Amaëlle Landais, Laurent Arnaud, Christo Buizert, Emilie Capron, Marie Dumont, Quentin Libois, Robert Mulvaney, Anaïs Orsi, Ghislain Picard, Frédéric Prié, Jeffrey Severinghaus, Barbara Stenni, and Patricia Martinerie
The Cryosphere, 18, 3741–3763, https://doi.org/10.5194/tc-18-3741-2024, https://doi.org/10.5194/tc-18-3741-2024, 2024
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Ice core δO2/N2 records are useful dating tools due to their local insolation pacing. A precise understanding of the physical mechanism driving this relationship, however, remain ambiguous. By compiling data from 15 polar sites, we find a strong dependence of mean δO2/N2 on accumulation rate and temperature in addition to the well-documented insolation dependence. Snowpack modelling is used to investigate which physical properties drive the mechanistic dependence on these local parameters.
Mathieu Casado, Amaelle Landais, Tim Stoltmann, Justin Chaillot, Mathieu Daëron, Fréderic Prié, Baptiste Bordet, and Samir Kassi
Atmos. Meas. Tech., 17, 4599–4612, https://doi.org/10.5194/amt-17-4599-2024, https://doi.org/10.5194/amt-17-4599-2024, 2024
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Measuring water isotopic composition in Antarctica is difficult because of the extremely cold temperature in winter. Here, we designed a new infrared spectrometer able to measure the vapour isotopic composition during more than 95 % of the year in the coldest locations of Antarctica, whereas current commercial instruments are only able to measure during the warm summer months in the interior.
Hans Christian Steen-Larsen and Daniele Zannoni
Atmos. Meas. Tech., 17, 4391–4409, https://doi.org/10.5194/amt-17-4391-2024, https://doi.org/10.5194/amt-17-4391-2024, 2024
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The water vapor generation module is completely scalable, allowing autonomous calibrations to use N standards and providing integration times only restricted by sample availability. We document improved reproducibility in 17O-excess liquid measurements. This module makes spectroscopy measurements comparable to mass spectrometry. We document that the vapor generation module can be used to analyze instrument performance and for vapor isotope calibration during field campaign measurements.
Azzurra Spagnesi, Elena Barbaro, Matteo Feltracco, Federico Scoto, Marco Vecchiato, Massimiliano Vardè, Mauro Mazzola, François Yves Burgay, Federica Bruschi, Clara Jule Marie Hoppe, Allison Bailey, Andrea Gambaro, Carlo Barbante, and Andrea Spolaor
EGUsphere, https://doi.org/10.5194/egusphere-2024-1393, https://doi.org/10.5194/egusphere-2024-1393, 2024
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Svalbard is a relevant area to evaluate changes in local environmental processes induced by Arctic Amplification (AA). By comparing the snow chemical composition of the 2019–20 season with 2018–19 and 2020–21, we provide an overview of the potential impacts of AA on the Svalbard snowpack, and associated changes in aerosol production process, influenced by a complex interplay between atmospheric patterns, local and oceanic conditions that jointly drive snowpack impurity amounts and composition.
V. Holly L. Winton, Robert Mulvaney, Joel Savarino, Kyle R. Clem, and Markus M. Frey
Clim. Past, 20, 1213–1232, https://doi.org/10.5194/cp-20-1213-2024, https://doi.org/10.5194/cp-20-1213-2024, 2024
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In 2018, a new 120 m ice core was drilled in a region located under the Antarctic ozone hole. We present the first results including a 1300-year record of snow accumulation and aerosol chemistry. We investigate the aerosol and moisture source regions and atmospheric processes related to the ice core record and discuss what this means for developing a record of past ultraviolet radiation and ozone depletion using the stable isotopic composition of nitrate measured in the same ice core.
Zhuang Jiang, Becky Alexander, Joel Savarino, and Lei Geng
Atmos. Chem. Phys., 24, 4895–4914, https://doi.org/10.5194/acp-24-4895-2024, https://doi.org/10.5194/acp-24-4895-2024, 2024
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Ice-core nitrate could track the past atmospheric NOx and oxidant level, but its interpretation is hampered by the post-depositional processing. In this work, an inverse model was developed and tested against two polar sites and was shown to well reproduce the observed nitrate signals in snow and atmosphere, suggesting that the model can properly correct for the effect of post-depositional processing. This model offers a very useful tool for future studies on ice-core nitrate records.
Amaelle Landais, Cécile Agosta, Françoise Vimeux, Olivier Magand, Cyrielle Solis, Alexandre Cauquoin, Niels Dutrievoz, Camille Risi, Christophe Leroy-Dos Santos, Elise Fourré, Olivier Cattani, Olivier Jossoud, Bénédicte Minster, Frédéric Prié, Mathieu Casado, Aurélien Dommergue, Yann Bertrand, and Martin Werner
Atmos. Chem. Phys., 24, 4611–4634, https://doi.org/10.5194/acp-24-4611-2024, https://doi.org/10.5194/acp-24-4611-2024, 2024
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We have monitored water vapor isotopes since January 2020 on Amsterdam Island in the Indian Ocean. We show 11 periods associated with abrupt negative excursions of water vapor δ18Ο. Six of these events show a decrease in gaseous elemental mercury, suggesting subsidence of air from a higher altitude. Accurately representing the water isotopic signal during these cold fronts is a real challenge for the atmospheric components of Earth system models equipped with water isotopes.
C. Isabel Moreno, Radovan Krejci, Jean-Luc Jaffrezo, Gaëlle Uzu, Andrés Alastuey, Marcos F. Andrade, Valeria Mardóñez, Alkuin Maximilian Koenig, Diego Aliaga, Claudia Mohr, Laura Ticona, Fernando Velarde, Luis Blacutt, Ricardo Forno, David N. Whiteman, Alfred Wiedensohler, Patrick Ginot, and Paolo Laj
Atmos. Chem. Phys., 24, 2837–2860, https://doi.org/10.5194/acp-24-2837-2024, https://doi.org/10.5194/acp-24-2837-2024, 2024
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Aerosol chemical composition (ions, sugars, carbonaceous matter) from 2011 to 2020 was studied at Mt. Chacaltaya (5380 m a.s.l., Bolivian Andes). Minimum concentrations occur in the rainy season with maxima in the dry and transition seasons. The origins of the aerosol are located in a radius of hundreds of kilometers: nearby urban and rural areas, natural biogenic emissions, vegetation burning from Amazonia and Chaco, Pacific Ocean emissions, soil dust, and Peruvian volcanism.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, Roberto Grilli, Quentin Fournier, Irène Ventrillard, Nicolas Caillon, and Kathy Law
Atmos. Chem. Phys., 24, 1361–1388, https://doi.org/10.5194/acp-24-1361-2024, https://doi.org/10.5194/acp-24-1361-2024, 2024
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This study reports the first simultaneous records of oxygen (Δ17O) and nitrogen (δ15N) isotopes in nitrogen dioxide (NO2) and nitrate (NO3−). These data are combined with atmospheric observations to explore sub-daily N reactive chemistry and quantify N fractionation effects in an Alpine winter city. The results highlight the necessity of using Δ17O and δ15N in both NO2 and NO3− to avoid biased estimations of NOx sources and fates from NO3− isotopic records in urban winter environments.
Andrea Spolaor, Federico Scoto, Catherine Larose, Elena Barbaro, Francois Burgay, Mats P. Bjorkman, David Cappelletti, Federico Dallo, Fabrizio de Blasi, Dmitry Divine, Giuliano Dreossi, Jacopo Gabrieli, Elisabeth Isaksson, Jack Kohler, Tonu Martma, Louise S. Schmidt, Thomas V. Schuler, Barbara Stenni, Clara Turetta, Bartłomiej Luks, Mathieu Casado, and Jean-Charles Gallet
The Cryosphere, 18, 307–320, https://doi.org/10.5194/tc-18-307-2024, https://doi.org/10.5194/tc-18-307-2024, 2024
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We evaluate the impact of the increased snowmelt on the preservation of the oxygen isotope (δ18O) signal in firn records recovered from the top of the Holtedahlfonna ice field located in the Svalbard archipelago. Thanks to a multidisciplinary approach we demonstrate a progressive deterioration of the isotope signal in the firn core. We link the degradation of the δ18O signal to the increased occurrence and intensity of melt events associated with the rapid warming occurring in the archipelago.
Christophe Leroy-Dos Santos, Elise Fourré, Cécile Agosta, Mathieu Casado, Alexandre Cauquoin, Martin Werner, Benedicte Minster, Frédéric Prié, Olivier Jossoud, Leila Petit, and Amaëlle Landais
The Cryosphere, 17, 5241–5254, https://doi.org/10.5194/tc-17-5241-2023, https://doi.org/10.5194/tc-17-5241-2023, 2023
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In the face of global warming, understanding the changing water cycle and temperatures in polar regions is crucial. These factors directly impact the balance of ice sheets in the Arctic and Antarctic. By studying the composition of water vapor, we gain insights into climate variations. Our 2-year study at Dumont d’Urville station, Adélie Land, offers valuable data to refine models. Additionally, we demonstrate how modeling aids in interpreting signals from ice core samples in the region.
Tobias Erhardt, Camilla Marie Jensen, Florian Adolphi, Helle Astrid Kjær, Remi Dallmayr, Birthe Twarloh, Melanie Behrens, Motohiro Hirabayashi, Kaori Fukuda, Jun Ogata, François Burgay, Federico Scoto, Ilaria Crotti, Azzurra Spagnesi, Niccoló Maffezzoli, Delia Segato, Chiara Paleari, Florian Mekhaldi, Raimund Muscheler, Sophie Darfeuil, and Hubertus Fischer
Earth Syst. Sci. Data, 15, 5079–5091, https://doi.org/10.5194/essd-15-5079-2023, https://doi.org/10.5194/essd-15-5079-2023, 2023
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The presented paper provides a 3.8 kyr long dataset of aerosol concentrations from the East Greenland Ice coring Project (EGRIP) ice core. The data consists of 1 mm depth-resolution profiles of calcium, sodium, ammonium, nitrate, and electrolytic conductivity as well as decadal averages of these profiles. Alongside the data a detailed description of the measurement setup as well as a discussion of the uncertainties are given.
Marie Bouchet, Amaëlle Landais, Antoine Grisart, Frédéric Parrenin, Frédéric Prié, Roxanne Jacob, Elise Fourré, Emilie Capron, Dominique Raynaud, Vladimir Ya Lipenkov, Marie-France Loutre, Thomas Extier, Anders Svensson, Etienne Legrain, Patricia Martinerie, Markus Leuenberger, Wei Jiang, Florian Ritterbusch, Zheng-Tian Lu, and Guo-Min Yang
Clim. Past, 19, 2257–2286, https://doi.org/10.5194/cp-19-2257-2023, https://doi.org/10.5194/cp-19-2257-2023, 2023
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A new federative chronology for five deep polar ice cores retrieves 800 000 years of past climate variations with improved accuracy. Precise ice core timescales are key to studying the mechanisms linking changes in the Earth’s orbit to the diverse climatic responses (temperature and atmospheric greenhouse gas concentrations). To construct the chronology, new measurements from the oldest continuous ice core as well as glaciological modeling estimates were combined in a statistical model.
Valeria Mardoñez, Marco Pandolfi, Lucille Joanna S. Borlaza, Jean-Luc Jaffrezo, Andrés Alastuey, Jean-Luc Besombes, Isabel Moreno R., Noemi Perez, Griša Močnik, Patrick Ginot, Radovan Krejci, Vladislav Chrastny, Alfred Wiedensohler, Paolo Laj, Marcos Andrade, and Gaëlle Uzu
Atmos. Chem. Phys., 23, 10325–10347, https://doi.org/10.5194/acp-23-10325-2023, https://doi.org/10.5194/acp-23-10325-2023, 2023
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La Paz and El Alto are two fast-growing, high-altitude Bolivian cities forming the second-largest metropolitan area in the country. The sources of particulate matter (PM) in this conurbation were not previously investigated. This study identified 11 main sources of PM, of which dust and vehicular emissions stand out as the main ones. The influence of regional biomass combustion and local waste combustion was also observed, with the latter being a major source of hazardous compounds.
Alexis Lamothe, Joel Savarino, Patrick Ginot, Lison Soussaintjean, Elsa Gautier, Pete D. Akers, Nicolas Caillon, and Joseph Erbland
Atmos. Meas. Tech., 16, 4015–4030, https://doi.org/10.5194/amt-16-4015-2023, https://doi.org/10.5194/amt-16-4015-2023, 2023
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Ammonia is a reactive gas in our atmosphere that is key in air quality issues. Assessing its emissions and how it reacts is a hot topic that can be addressed from the past. Stable isotopes (the mass of the molecule) measured in ice cores (glacial archives) can teach us a lot. However, the concentrations in ice cores are very small. We propose a protocol to limit the contamination and apply it to one ice core drilled in Mont Blanc, describing the opportunities our method brings.
Azzurra Spagnesi, Pascal Bohleber, Elena Barbaro, Matteo Feltracco, Fabrizio De Blasi, Giuliano Dreossi, Martin Stocker-Waldhuber, Daniela Festi, Jacopo Gabrieli, Andrea Gambaro, Andrea Fischer, and Carlo Barbante
EGUsphere, https://doi.org/10.5194/egusphere-2023-1625, https://doi.org/10.5194/egusphere-2023-1625, 2023
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We present new data from a 10 m ice core drilled in 2019 and a 8.4 m parallel ice core drilled in 2021 at the summit of Weißseespitze glacier. In a new combination of proxies, we discuss profiles of stable water isotopes, major ion chemistry as well as a full profile of microcharcoal and levoglucosan. We find that the chemical and isotopic signals are preserved, despite the ongoing surface mass loss. This is not be to expected considering what has been found at other glaciers at similar locations.
Aymeric P. M. Servettaz, Anaïs J. Orsi, Mark A. J. Curran, Andrew D. Moy, Amaelle Landais, Joseph R. McConnell, Trevor J. Popp, Emmanuel Le Meur, Xavier Faïn, and Jérôme Chappellaz
Clim. Past, 19, 1125–1152, https://doi.org/10.5194/cp-19-1125-2023, https://doi.org/10.5194/cp-19-1125-2023, 2023
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The temperature of the past 2000 years is still poorly known in vast parts of the East Antarctic plateau. In this study, we present temperature reconstructions based on water and gas stable isotopes from the Aurora Basin North ice core. Spatial and temporal significance of each proxy differs, and we can identify some cold periods in the snow temperature up to 2°C cooler in the 1000–1400 CE period, which could not be determined with water isotopes only.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
Clim. Past, 19, 851–864, https://doi.org/10.5194/cp-19-851-2023, https://doi.org/10.5194/cp-19-851-2023, 2023
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We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
Simone Ventisette, Samuele Baldini, Claudio Artoni, Silvia Becagli, Laura Caiazzo, Barbara Delmonte, Massimo Frezzotti, Raffaello Nardin, Joel Savarino, Mirko Severi, Andrea Spolaor, Barbara Stenni, and Rita Traversi
EGUsphere, https://doi.org/10.5194/egusphere-2023-393, https://doi.org/10.5194/egusphere-2023-393, 2023
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The paper reports the spatial variability of concentration and fluxes of chemical impurities in superficial snow over unexplored area of the East Antarctic ice sheet. Pinatubo and Puyehue-Cordón Caulle volcanic eruptions in non-sea salt sulfate and dust snow pits record were used to achieve the accumulation rates. Deposition (wet, dry and uptake from snow surface) and post deposition processes are constrained. These knowledges are fundamental in Antarctic ice cores stratigraphies interpretation.
Clémence Paul, Clément Piel, Joana Sauze, Nicolas Pasquier, Frédéric Prié, Sébastien Devidal, Roxanne Jacob, Arnaud Dapoigny, Olivier Jossoud, Alexandru Milcu, and Amaëlle Landais
Biogeosciences, 20, 1047–1062, https://doi.org/10.5194/bg-20-1047-2023, https://doi.org/10.5194/bg-20-1047-2023, 2023
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To improve the interpretation of the δ18Oatm and Δ17O of O2 in air bubbles in ice cores, we need to better quantify the oxygen fractionation coefficients associated with biological processes. We performed a simplified analogue of the terrestrial biosphere in a closed chamber. We found a respiration fractionation in agreement with the previous estimates at the microorganism scale, and a terrestrial photosynthetic fractionation was found. This has an impact on the estimation of the Dole effect.
Wiebke Scholz, Jiali Shen, Diego Aliaga, Cheng Wu, Samara Carbone, Isabel Moreno, Qiaozhi Zha, Wei Huang, Liine Heikkinen, Jean Luc Jaffrezo, Gaelle Uzu, Eva Partoll, Markus Leiminger, Fernando Velarde, Paolo Laj, Patrick Ginot, Paolo Artaxo, Alfred Wiedensohler, Markku Kulmala, Claudia Mohr, Marcos Andrade, Victoria Sinclair, Federico Bianchi, and Armin Hansel
Atmos. Chem. Phys., 23, 895–920, https://doi.org/10.5194/acp-23-895-2023, https://doi.org/10.5194/acp-23-895-2023, 2023
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Dimethyl sulfide (DMS), emitted from the ocean, is the most abundant biogenic sulfur emission into the atmosphere. OH radicals, among others, can oxidize DMS to sulfuric and methanesulfonic acid, which are relevant for aerosol formation. We quantified DMS and nearly all DMS oxidation products with novel mass spectrometric instruments for gas and particle phase at the high mountain station Chacaltaya (5240 m a.s.l.) in the Bolivian Andes in free tropospheric air after long-range transport.
Pete D. Akers, Joël Savarino, Nicolas Caillon, Olivier Magand, and Emmanuel Le Meur
Atmos. Chem. Phys., 22, 15637–15657, https://doi.org/10.5194/acp-22-15637-2022, https://doi.org/10.5194/acp-22-15637-2022, 2022
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Nitrate isotopes in Antarctic ice do not preserve the seasonal isotopic cycles of the atmosphere, which limits their use to study the past. We studied nitrate along an 850 km Antarctic transect to learn how these cycles are changed by sunlight-driven chemistry in the snow. Our findings suggest that the snow accumulation rate and other environmental signals can be extracted from nitrate with the right sampling and analytical approaches.
Mirko Pavoni, Jacopo Boaga, Alberto Carrera, Stefano Urbini, Fabrizio de Blasi, and Jacopo Gabrieli
The Cryosphere Discuss., https://doi.org/10.5194/tc-2022-190, https://doi.org/10.5194/tc-2022-190, 2022
Revised manuscript not accepted
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The Ice Memory project aims to extract, analyze, and store ice cores from worldwide retreating glaciers. One of the selected sites is the last remaining ice body in the Apennines, the Calderone Glacier. To assess the most suitable drilling position, geophysical surveys were performed. Reliable ground penetrating radar measurements have been positively combined with a geophysical technique rarely applied in glacier environments, the Frequency Domain Electro-Magnetic prospection.
Yanzhi Cao, Zhuang Jiang, Becky Alexander, Jihong Cole-Dai, Joel Savarino, Joseph Erbland, and Lei Geng
Atmos. Chem. Phys., 22, 13407–13422, https://doi.org/10.5194/acp-22-13407-2022, https://doi.org/10.5194/acp-22-13407-2022, 2022
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We investigate the potential of ice-core preserved nitrate isotopes as proxies of stratospheric ozone variability by measuring nitrate isotopes in a shallow ice core from the South Pole. The large variability in the snow accumulation rate and its slight increase after the 1970s masked any signals caused by the ozone hole. Moreover, the nitrate oxygen isotope decrease may reflect changes in the atmospheric oxidation environment in the Southern Ocean.
Antoine Grisart, Mathieu Casado, Vasileios Gkinis, Bo Vinther, Philippe Naveau, Mathieu Vrac, Thomas Laepple, Bénédicte Minster, Frederic Prié, Barbara Stenni, Elise Fourré, Hans Christian Steen-Larsen, Jean Jouzel, Martin Werner, Katy Pol, Valérie Masson-Delmotte, Maria Hoerhold, Trevor Popp, and Amaelle Landais
Clim. Past, 18, 2289–2301, https://doi.org/10.5194/cp-18-2289-2022, https://doi.org/10.5194/cp-18-2289-2022, 2022
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This paper presents a compilation of high-resolution (11 cm) water isotopic records, including published and new measurements, for the last 800 000 years from the EPICA Dome C ice core, Antarctica. Using this new combined water isotopes (δ18O and δD) dataset, we study the variability and possible influence of diffusion at the multi-decadal to multi-centennial scale. We observe a stronger variability at the onset of the interglacial interval corresponding to a warm period.
Albane Barbero, Roberto Grilli, Markus M. Frey, Camille Blouzon, Detlev Helmig, Nicolas Caillon, and Joël Savarino
Atmos. Chem. Phys., 22, 12025–12054, https://doi.org/10.5194/acp-22-12025-2022, https://doi.org/10.5194/acp-22-12025-2022, 2022
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The high reactivity of the summer Antarctic boundary layer results in part from the emissions of nitrogen oxides produced during photo-denitrification of the snowpack, but its underlying mechanisms are not yet fully understood. The results of this study suggest that more NO2 is produced from the snowpack early in the photolytic season, possibly due to stronger UV irradiance caused by a smaller solar zenith angle near the solstice.
Zhuang Jiang, Joel Savarino, Becky Alexander, Joseph Erbland, Jean-Luc Jaffrezo, and Lei Geng
The Cryosphere, 16, 2709–2724, https://doi.org/10.5194/tc-16-2709-2022, https://doi.org/10.5194/tc-16-2709-2022, 2022
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A record of year-round atmospheric nitrate isotopic composition along with snow nitrate isotopic data from Summit, Greenland, revealed apparent enrichments in nitrogen isotopes in snow nitrate compared to atmospheric nitrate, in addition to a relatively smaller degree of changes in oxygen isotopes. The results suggest that at this site post-depositional processing takes effect, which should be taken into account when interpreting ice-core nitrate isotope records.
Saehee Lim, Meehye Lee, Joel Savarino, and Paolo Laj
Atmos. Chem. Phys., 22, 5099–5115, https://doi.org/10.5194/acp-22-5099-2022, https://doi.org/10.5194/acp-22-5099-2022, 2022
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We determined δ15N(NO3−) and Δ17O(NO3−) of PM2.5 in Seoul during 2018–2019 and estimated quantitatively the contribution of oxidation pathways to NO3− formation and NOx emission sources. The nighttime pathway played a significant role in NO3− formation during the winter, and its contribution further increased up to 70 % on haze days when PM2.5 was greater than 75 µg m−3. Vehicle emissions were confirmed as a main NO3− source with an increasing contribution from coal combustion in winter.
Paolo Gabrielli, Theo Manuel Jenk, Michele Bertó, Giuliano Dreossi, Daniela Festi, Werner Kofler, Mai Winstrup, Klaus Oeggl, Margit Schwikowski, Barbara Stenni, and Carlo Barbante
Clim. Past Discuss., https://doi.org/10.5194/cp-2022-20, https://doi.org/10.5194/cp-2022-20, 2022
Revised manuscript not accepted
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We present a methodology that reduces the chronological uncertainty of an Alpine ice core record from the glacier Alto dell’Ortles, Italy. This chronology will allow the constraint of the Holocene climatic and environmental histories emerging from this archive of Central Europe. This method will allow to obtain accurate chronologies also from other ice cores from-low latitude/high-altitude glaciers that typically suffer from larger dating uncertainties compared with well dated polar records.
Laura Crick, Andrea Burke, William Hutchison, Mika Kohno, Kathryn A. Moore, Joel Savarino, Emily A. Doyle, Sue Mahony, Sepp Kipfstuhl, James W. B. Rae, Robert C. J. Steele, R. Stephen J. Sparks, and Eric W. Wolff
Clim. Past, 17, 2119–2137, https://doi.org/10.5194/cp-17-2119-2021, https://doi.org/10.5194/cp-17-2119-2021, 2021
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The ~ 74 ka eruption of Toba was one of the largest eruptions of the last 100 ka. We have measured the sulfur isotopic composition for 11 Toba eruption candidates in two Antarctic ice cores. Sulfur isotopes allow us to distinguish between large eruptions that have erupted material into the stratosphere and smaller ones that reach lower altitudes. Using this we have identified the events most likely to be Toba and place the eruption on the transition into a cold period in the Northern Hemisphere.
Raffaello Nardin, Mirko Severi, Alessandra Amore, Silvia Becagli, Francois Burgay, Laura Caiazzo, Virginia Ciardini, Giuliano Dreossi, Massimo Frezzotti, Sang-Bum Hong, Ishaq Khan, Bianca Maria Narcisi, Marco Proposito, Claudio Scarchilli, Enricomaria Selmo, Andrea Spolaor, Barbara Stenni, and Rita Traversi
Clim. Past, 17, 2073–2089, https://doi.org/10.5194/cp-17-2073-2021, https://doi.org/10.5194/cp-17-2073-2021, 2021
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The first step to exploit all the potential information buried in ice cores is to produce a reliable age scale. Based on chemical and isotopic records from the 197 m Antarctic GV7(B) ice core, accurate dating was achieved and showed that the archive spans roughly the last 830 years. The relatively high accumulation rate allowed us to use the non-sea-salt sulfate seasonal pattern to count annual layers. The accumulation rate reconstruction exhibited a slight increase since the 18th century.
Clément Outrequin, Anne Alexandre, Christine Vallet-Coulomb, Clément Piel, Sébastien Devidal, Amaelle Landais, Martine Couapel, Jean-Charles Mazur, Christophe Peugeot, Monique Pierre, Frédéric Prié, Jacques Roy, Corinne Sonzogni, and Claudia Voigt
Clim. Past, 17, 1881–1902, https://doi.org/10.5194/cp-17-1881-2021, https://doi.org/10.5194/cp-17-1881-2021, 2021
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Continental atmospheric humidity is a key climate parameter poorly captured by global climate models. Model–data comparison approaches that are applicable beyond the instrumental period are essential to progress on this issue but face a lack of quantitative relative humidity proxies. Here, we calibrate the triple oxygen isotope composition of phytoliths as a new quantitative proxy of continental relative humidity suitable for past climate reconstructions.
Federico Dallo, Daniele Zannoni, Jacopo Gabrieli, Paolo Cristofanelli, Francescopiero Calzolari, Fabrizio de Blasi, Andrea Spolaor, Dario Battistel, Rachele Lodi, Warren Raymond Lee Cairns, Ann Mari Fjæraa, Paolo Bonasoni, and Carlo Barbante
Atmos. Meas. Tech., 14, 6005–6021, https://doi.org/10.5194/amt-14-6005-2021, https://doi.org/10.5194/amt-14-6005-2021, 2021
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Our work showed how the adoption of low-cost technology could be useful in environmental research and monitoring. We focused our work on tropospheric ozone, but we also showed how to make a general purpose low-cost sensing system which may be adapted and optimised to be used in many other case studies. Given the importance of providing quality data, we put a lot of effort in the sensor's calibration, and we believe that our results show how to exploit the potential of the low-cost technology.
Zhuang Jiang, Becky Alexander, Joel Savarino, Joseph Erbland, and Lei Geng
The Cryosphere, 15, 4207–4220, https://doi.org/10.5194/tc-15-4207-2021, https://doi.org/10.5194/tc-15-4207-2021, 2021
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We used a snow photochemistry model (TRANSITS) to simulate the seasonal nitrate snow profile at Summit, Greenland. Comparisons between model outputs and observations suggest that at Summit post-depositional processing is active and probably dominates the snowpack δ15N seasonality. We also used the model to assess the degree of snow nitrate loss and the consequences in its isotopes at present and in the past, which helps for quantitative interpretations of ice-core nitrate records.
Pascal Bohleber, Marco Roman, Martin Šala, Barbara Delmonte, Barbara Stenni, and Carlo Barbante
The Cryosphere, 15, 3523–3538, https://doi.org/10.5194/tc-15-3523-2021, https://doi.org/10.5194/tc-15-3523-2021, 2021
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Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) offers micro-destructive, micrometer-scale impurity analysis of ice cores. For improved understanding of the LA-ICP-MS signals, novel 2D impurity imaging is applied to selected glacial and interglacial samples of Antarctic deep ice cores. This allows evaluating the 2D impurity distribution in relation to ice crystal features and assessing implications for investigating highly thinned climate proxy signals in deep polar ice.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, and Nicolas Caillon
Atmos. Chem. Phys., 21, 10477–10497, https://doi.org/10.5194/acp-21-10477-2021, https://doi.org/10.5194/acp-21-10477-2021, 2021
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We report an efficient method to collect atmospheric NO2 adapted for multi-isotopic analysis and present the first NO2 triple oxygen and double nitrogen isotope measurements. Atmospheric samplings carried out in Grenoble, France, highlight the NO2 isotopic signature sensitivity to the local NOx emissions and chemical regimes. These preliminary results are very promising for using the combination of Δ17O and δ15N of NO2 as a probe of the atmospheric NOx emissions and chemistry.
Christophe Leroy-Dos Santos, Mathieu Casado, Frédéric Prié, Olivier Jossoud, Erik Kerstel, Morgane Farradèche, Samir Kassi, Elise Fourré, and Amaëlle Landais
Atmos. Meas. Tech., 14, 2907–2918, https://doi.org/10.5194/amt-14-2907-2021, https://doi.org/10.5194/amt-14-2907-2021, 2021
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We developed an instrument that can generate water vapor at low humidity at a very stable level. This instrument was conceived to calibrate water vapor isotopic records obtained in very dry places such as central Antarctica. Here, we provide details on the instrument as well as results obtained for correcting water isotopic records for diurnal variability during a long field season at the Concordia station in East Antarctica.
Filipe G. L. Lindau, Jefferson C. Simões, Barbara Delmonte, Patrick Ginot, Giovanni Baccolo, Chiara I. Paleari, Elena Di Stefano, Elena Korotkikh, Douglas S. Introne, Valter Maggi, Eduardo Garzanti, and Sergio Andò
The Cryosphere, 15, 1383–1397, https://doi.org/10.5194/tc-15-1383-2021, https://doi.org/10.5194/tc-15-1383-2021, 2021
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Information about the past climate variability in tropical South America is stored in the snow layers of the tropical Andean glaciers. Here we show evidence that the presence of very large aeolian mineral dust particles at Nevado Illimani (Bolivia) is strictly controlled by the occurrence of summer storms in the Bolivian Altiplano. Therefore, based on the snow dust content and its composition of stable water isotopes, we propose a new proxy for information on previous summer storms.
Pete D. Akers, Ben G. Kopec, Kyle S. Mattingly, Eric S. Klein, Douglas Causey, and Jeffrey M. Welker
Atmos. Chem. Phys., 20, 13929–13955, https://doi.org/10.5194/acp-20-13929-2020, https://doi.org/10.5194/acp-20-13929-2020, 2020
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Water vapor isotopes recorded for 2 years in coastal northern Greenland largely reflect changes in sea ice cover, with distinct values when Baffin Bay is ice covered in winter vs. open in summer. Resulting changes in moisture transport, surface winds, and air temperature also modify the isotopes. Local glacial ice may thus preserve past changes in the Baffin Bay sea ice extent, and this will help us better understand how the Arctic environment and water cycle responds to global climate change.
Jinhwa Shin, Christoph Nehrbass-Ahles, Roberto Grilli, Jai Chowdhry Beeman, Frédéric Parrenin, Grégory Teste, Amaelle Landais, Loïc Schmidely, Lucas Silva, Jochen Schmitt, Bernhard Bereiter, Thomas F. Stocker, Hubertus Fischer, and Jérôme Chappellaz
Clim. Past, 16, 2203–2219, https://doi.org/10.5194/cp-16-2203-2020, https://doi.org/10.5194/cp-16-2203-2020, 2020
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We reconstruct atmospheric CO2 from the EPICA Dome C ice core during Marine Isotope Stage 6 (185–135 ka) to understand carbon mechanisms under the different boundary conditions of the climate system. The amplitude of CO2 is highly determined by the Northern Hemisphere stadial duration. Carbon dioxide maxima show different lags with respect to the corresponding abrupt CH4 jumps, the latter reflecting rapid warming in the Northern Hemisphere.
Ben G. Kopec, Pete D. Akers, Eric S. Klein, and Jeffery M. Welker
The Cryosphere Discuss., https://doi.org/10.5194/tc-2020-276, https://doi.org/10.5194/tc-2020-276, 2020
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Significant mass loss to the Greenland Ice Sheet has occurred over recent decades, marked by a record summer melt season in 2019. Water vapor fluxes from the ice sheet surface, including sublimation and meltwater evaporation, are a growing component of the mass balance. Using water vapor isotope measurements in northwest Greenland, we identify the signal of these fluxes and show how they correspond with melt extent. These vapor fluxes contribute ~20 % of water vapor advected off the ice sheet.
Cited articles
Allan, D. W.: Statistics of atomic frequency standards, Proc. IEEE, 54, 221–230, https://doi.org/10.1109/PROC.1966.4634, 1966.
Alley, R. B.: Ice-core evidence of abrupt climate changes, Proc. Natl. Acad. Sci. USA, 97, 1331–1334, https://doi.org/10.1073/pnas.97.4.1331, 2000.
Barbaro, E., Feltracco, M., Spagnesi, A., Dallo, F., Gabrieli, J., De Blasi, F., Zannoni, D., Cairns, W. R. L., Gambaro, A., and Barbante, C.: Fast liquid chromatography coupled with tandem mass spectrometry for the analysis of vanillic and syringic acids in ice cores, Anal. Chem., 94, 5344–5351, https://doi.org/10.1021/acs.analchem.1c05412, 2022.
Bigler, M., Svensson, A., Kettner, E., Vallelonga, P., Nielsen, M. E., and Steffensen, J. P.: Optimization of high-resolution continuous flow analysis for transient climate signals in ice cores, Environ. Sci. Technol., 45, 4483–4489, https://doi.org/10.1021/es1033252, 2011.
Casado, M., Münch, T., and Laepple, T.: Climatic information archived in ice cores: impact of intermittency and diffusion on the recorded isotopic signal in Antarctica, Clim. Past, 16, 1581–1598, https://doi.org/10.5194/cp-16-1581-2020, 2020.
Casado, M., Landais, A., Picard, G., Arnaud, L., Dreossi, G., Stenni, B., and Prié, F.: Water isotopic signature of surface snow metamorphism in Antarctica, Geophys. Res. Lett., 48, e2021GL093382, https://doi.org/10.1029/2021GL093382, 2021.
Casado, M., Landais, A., Stoltmann, T., Chaillot, J., Daëron, M., Prié, F., Bordet, B., and Kassi, S.: Reliable water vapour isotopic composition measurements at low humidity using frequency-stabilised cavity ring-down spectroscopy, Atmos. Meas. Tech., 17, 4599–4612, https://doi.org/10.5194/amt-17-4599-2024, 2024.
Craig, H.: Isotopic exchange effects in the evaporation of water: 1. Low-temperature experimental results, J. Geophys. Res., 68, 5079–5087, https://doi.org/10.1029/jz068i017p05079, 1963.
Crotti, I., Landais, A., Stenni, B., Bazin, L., Parrenin, F., Frezzotti, M., Ritterbusch, F., Lu, Z.-T., Jiang, W., Yang, G.-M., Masson-Delmotte, V., Jouzel, J., and Arnaud, L.: An extension of the TALDICE ice core age scale reaching back to MIS 10.1, Quaternary Sci. Rev., 266, 107078, https://doi.org/10.1016/j.quascirev.2021.107078, 2021.
Dallmayr, R., Meyer, H., Gkinis, V., Laepple, T., Behrens, M., Wilhelms, F., and Hörhold, M.: Assessment of continuous flow analysis (CFA) for high-precision profiles of water isotopes in snow cores, The Cryosphere, 19, 1067–1083, https://doi.org/10.5194/tc-19-1067-2025, 2025.
Dansgaard, W.: Stable isotopes in precipitation, Tellus B, 16, 436–468, 1964.
Davidge, L., Steig, E. J., and Schauer, A. J.: Improving continuous-flow analysis of triple oxygen isotopes in ice cores: insights from replicate measurements, Atmos. Meas. Tech., 15, 7337–7351, https://doi.org/10.5194/amt-15-7337-2022, 2022.
Emanuelsson, B. D., Baisden, W. T., Bertler, N. A. N., Keller, E. D., and Gkinis, V.: High-resolution continuous-flow analysis setup for water isotopic measurement from ice cores using laser spectroscopy, Atmos. Meas. Tech., 8, 2869–2883, https://doi.org/10.5194/amt-8-2869-2015, 2015.
Genthon, C., Piard, L., Vignon, E., Madeleine, J.-B., Casado, M., and Gallée, H.: Atmospheric moisture supersaturation in the near-surface atmosphere at Dome C, Antarctic Plateau, Atmos. Chem. Phys., 17, 691–704, https://doi.org/10.5194/acp-17-691-2017, 2017.
Gkinis, V., Popp, T. J., Johnsen, S. J., and Blunier, T.: A continuous stream flash evaporator for the calibration of an IR cavity ring-down spectrometer for the isotopic analysis of water, Isot. Environ. Health Stud., 46, 463–475, https://doi.org/10.1080/10256016.2010.538052, 2010.
Gkinis, V., Popp, T. J., Blunier, T., Bigler, M., Schüpbach, S., Kettner, E., and Johnsen, S. J.: Water isotopic ratios from a continuously melted ice core sample, Atmos. Meas. Tech., 4, 2531–2542, https://doi.org/10.5194/amt-4-2531-2011, 2011.
Gkinis, V., Holme, C., Kahle, E. C., Stevens, M. C., Steig, E. J., and Vinther, B. M.: Numerical experiments on firn isotope diffusion with the Community Firn Model, J. Glaciol., 67, 450–472, https://doi.org/10.1017/jog.2021.1, 2021.
Goursaud, S., Masson-Delmotte, V., Favier, V., Preunkert, S., Fily, M., Gallée, H., Jourdain, B., Legrand, M., Magand, O., Minster, B., and Werner, M.: A 60-year ice-core record of regional climate from Adélie Land, coastal Antarctica, The Cryosphere, 11, 343–362, https://doi.org/10.5194/tc-11-343-2017, 2017.
Grisart, A., Casado, M., Gkinis, V., Vinther, B., Naveau, P., Vrac, M., Laepple, T., Minster, B., Prié, F., Stenni, B., Fourré, E., Steen-Larsen, H. C., Jouzel, J., Werner, M., Pol, K., Masson-Delmotte, V., Hoerhold, M., Popp, T., and Landais, A.: Sub-millennial climate variability from high-resolution water isotopes in the EPICA Dome C ice core, Clim. Past, 18, 2289–2301, https://doi.org/10.5194/cp-18-2289-2022, 2022.
Huybrechts, P., Rybak, O., Pattyn, F., Ruth, U., and Steinhage, D.: Ice thinning, upstream advection, and non-climatic biases for the upper 89 % of the EDML ice core from a nested model of the Antarctic ice sheet, Clim. Past, 3, 577–589, https://doi.org/10.5194/cp-3-577-2007, 2007.
Johnsen, S. J., Clausen, H. B., Cuffey, K. M., Hoffmann, G., and Creyts, T. T.: Diffusion of stable isotopes in polar firn and ice: the isotope effect in firn diffusion, in: Physics of Ice Core Records, edited by: Hondoh, T., Hokkaido University Press, 121–140, https://doi.org/10.7916/D8KW5D4X, 2000.
Jones, T. R., White, J. W. C., Steig, E. J., Vaughn, B. H., Morris, V., Gkinis, V., Markle, B. R., and Schoenemann, S. W.: Improved methodologies for continuous-flow analysis of stable water isotopes in ice cores, Atmos. Meas. Tech., 10, 617–632, https://doi.org/10.5194/amt-10-617-2017, 2017a.
Jones, T. R., Cuffey, K. M., White, J. W. C., Steig, E. J., Buizert, C., Markle, B. R., McConnell, J. R., and Sigl, M.: Water isotope diffusion in the WAIS Divide ice core during the Holocene and last glacial, J. Geophys. Res. Earth Surf., 122, 290–309, https://doi.org/10.1002/2016JF003938, 2017b.
Kruskal, W. H. and Wallis, W. A.: Use of ranks in one-criterion variance analysis, J. Am. Stat. Assoc., 47, 583–621, 1952.
Laepple, T., Werner, M., and Lohmann, G.: Synchronicity of Antarctic temperatures and local solar insolation on orbital timescales, Nature, 471, 91–94, https://doi.org/10.1038/nature09825, 2011.
Laepple, T., Münch, T., Casado, M., Hoerhold, M., Landais, A., and Kipfstuhl, S.: On the similarity and apparent cycles of isotopic variations in East Antarctic snow pits, The Cryosphere, 12, 169–187, https://doi.org/10.5194/tc-12-169-2018, 2018.
Landais, A. and Stenni, B.: Water stable isotopes (dD, d18O) from EPICA Dome C ice core (Antarctica) (0–800 ka), PANGAEA [data set], https://doi.org/10.1594/PANGAEA.934094, 2021.
Landais, A., Casado, M., Prié, F., Magand, O., Arnaud, L., Ekaykin, A., Petit, J.-R., Picard, G., Fily, M., Minster, B., Touzeau, A., Masson-Delmotte, V., and Jouzel, J.: Surface studies of water isotopes in Antarctica for quantitative interpretation of deep ice core data, C. R. Geosci., 349, 139–150, https://doi.org/10.1016/j.crte.2017.05.003, 2017.
Lilien, D. A., Steinhage, D., Taylor, D., Parrenin, F., Ritz, C., Mulvaney, R., Martín, C., Yan, J.-B., O'Neill, C., Frezzotti, M., Miller, H., Gogineni, P., Dahl-Jensen, D., and Eisen, O.: Brief communication: New radar constraints support presence of ice older than 1.5 Myr at Little Dome C, The Cryosphere, 15, 1881–1888, https://doi.org/10.5194/tc-15-1881-2021, 2021.
Markle, B. R., Steig, E. J., Buizert, C., Schoenemann, S. W., Bitz, C. M., Fudge, T. J., Pedro, J. B., Ding, Q., Jones, T. R., White, J. W. C., Sowers, T., McConnell, J. R., Edwards, J. S., Schauer, A. J., Vaughn, B. H., Dennis, K. J., and Brook, E. J.: Global atmospheric teleconnections during Dansgaard–Oeschger events, Nat. Geosci., 10, 36–40, https://doi.org/10.1038/ngeo2848, 2017.
Münch, T. and Laepple, T.: What climate signal is contained in decadal- to centennial-scale isotope variations from Antarctic ice cores?, Clim. Past, 14, 2053–2070, https://doi.org/10.5194/cp-14-2053-2018, 2018.
Parrenin, F., Cavitte, M. G. P., Blankenship, D. D., Chappellaz, J., Fischer, H., Gagliardini, O., Masson-Delmotte, V., Passalacqua, O., Ritz, C., Roberts, J., Siegert, M. J., and Young, D. A.: Is there 1.5-million-year-old ice near Dome C, Antarctica?, The Cryosphere, 11, 2427–2437, https://doi.org/10.5194/tc-11-2427-2017, 2017.
Petit, J. R.: A detailed study of snow accumulation and stable isotope content in Dome C (Antarctica), J. Geophys. Res.-Oceans, 87, 4301–4312, https://doi.org/10.1029/JC087iC06p04301, 1982.
Petit, J. R., Jouzel, J., Raynaud, D., Barkov, N. I., Barnola, J.-M., Basile, I., Bender, M., Chappellaz, J., Davis, M., Delaygue, G., Delmotte, M., Kotlyakov, V. M., Legrand, M., Lipenkov, V. Y., Lorius, C., Pépin, L., Ritz, C., Saltzman, E., and Stievenard, M.: Climate and atmospheric history of the past 420 000 years from the Vostok ice core, Antarctica, Nature, 399, 429–436, https://doi.org/10.1038/20859, 1999.
Petteni, A., Fourre, E., Gautier, E., Akers, P. D., Stenni, B., and Casado, M.: Interlaboratory Comparison of Water Isotope Measurements: Continuous Flow Analysis and Discrete Data from an Ice Core Section, Zenodo [data set], https://doi.org/10.5281/zenodo.17294693, 2025.
Picard, G., Arnaud, L., Caneill, R., Lefebvre, E., and Lamare, M.: Observation of the process of snow accumulation on the Antarctic Plateau by time lapse laser scanning, The Cryosphere, 13, 1983–1999, https://doi.org/10.5194/tc-13-1983-2019, 2019.
Sigl, M., Fudge, T. J., Winstrup, M., Cole-Dai, J., Ferris, D., McConnell, J. R., Taylor, K. C., Welten, K. C., Woodruff, T. E., Adolphi, F., Bisiaux, M., Brook, E. J., Buizert, C., Caffee, M. W., Dunbar, N. W., Edwards, R., Geng, L., Iverson, N., Koffman, B., Layman, L., Maselli, O. J., McGwire, K., Muscheler, R., Nishiizumi, K., Pasteris, D. R., Rhodes, R. H., and Sowers, T. A.: The WAIS Divide deep ice core WD2014 chronology – Part 2: Annual-layer counting (0–31 ka BP), Clim. Past, 12, 769–786, https://doi.org/10.5194/cp-12-769-2016, 2016.
Spagnesi, A., Barbaro, E., Feltracco, M., De Blasi, F., Zannoni, D., Dreossi, G., Petteni, A., Notø, H., Lodi, R., Gabrieli, J., Holzinger, R., Gambaro, A., and Barbante, C.: An upgraded CFA – FLC – MS/MS system for the semi-continuous detection of levoglucosan in ice cores, Talanta, 265, 124799, https://doi.org/10.1016/j.talanta.2023.124799, 2023.
Steig, E. J.: Seasonal precipitation timing and ice core records, Science, 266, 1885–1886, https://doi.org/10.1126/science.266.5192.1885, 1994.
Traversa, G., Fugazza, D., and Frezzotti, M.: Megadunes in Antarctica: migration and characterization from remote and in situ observations, The Cryosphere, 17, 427–444, https://doi.org/10.5194/tc-17-427-2023, 2023.
Wahl, S., Steen-Larsen, H. C., Hughes, A. G., Dietrich, L. J., Zuhr, A., Behrens, M., Faber, A. K., and Hörhold, M.: Atmosphere–snow exchange explains surface snow isotope variability, Geophys. Res. Lett., 49, e2022GL099529, https://doi.org/10.1029/2022GL099529, 2022.
Wasserman, L.: All of Nonparametric Statistics, Springer New York, New York, NY, https://doi.org/10.1007/0-387-30623-4, 2006.
Wesche, C., Weller, R., König-Langlo, G., Fromm, T., Eckstaller, A., Nixdorf, U., and Kohlberg, E.: Neumayer III and Kohnen Station in Antarctica operated by the Alfred Wegener Institute, J. Large-Scale Res. Facil., 2, A85, https://doi.org/10.17815/jlsrf-2-152, 2016.
Whillans, I. M. and Grootes, P. M.: Isotopic diffusion in cold snow and firn, J. Geophys. Res.-Atmos., 90, 3910–3918, https://doi.org/10.1029/JD090iD02p03910, 1985.
Wille, J. D., Favier, V., Jourdain, N. C., Kittel, C., Turton, J. V., Agosta, C., Gorodetskaya, I. V., Picard, G., Codron, F., Leroy-Dos Santos, C., and Lenaerts, J. T. M.: Intense atmospheric rivers can weaken ice shelf stability at the Antarctic Peninsula, Commun. Earth Environ., 3, 90, https://doi.org/10.1038/s43247-022-00422-9, 2022.
Short summary
Our research compares three systems of continuous flow analysis coupled with cavity ring-down spectrometry (CFA-CRD) from Venice, Paris, and Grenoble laboratories for measuring water isotopes in ice cores, crucial for reconstructing past climate. We quantify each system’s mixing and measurement noise effects, which impact the achievable resolution of isotope continuous records. Our findings reveal specific configurations and procedures to enhance measurement accuracy, providing a framework to optimise water isotope analysis.
Our research compares three systems of continuous flow analysis coupled with cavity ring-down...
