Articles | Volume 18, issue 23
https://doi.org/10.5194/amt-18-7349-2025
https://doi.org/10.5194/amt-18-7349-2025
Research article
 | 
04 Dec 2025
Research article |  | 04 Dec 2025

Correcting for water vapor diffusion in air bag samples for isotope composition analysis: case study with drone-collected samples

Di Wang, Camille Risi, Lide Tian, Di Yang, Gabriel J. Bowen, Siteng Fan, Yang Su, Hongxi Pang, and Laurent Z. X. Li

Related authors

Vehicle-based in situ observations of the water vapor isotopic composition across China: spatial and seasonal distributions and controls
Di Wang, Lide Tian, Camille Risi, Xuejie Wang, Jiangpeng Cui, Gabriel J. Bowen, Kei Yoshimura, Zhongwang Wei, and Laurent Z. X. Li
Atmos. Chem. Phys., 23, 3409–3433, https://doi.org/10.5194/acp-23-3409-2023,https://doi.org/10.5194/acp-23-3409-2023, 2023
Short summary

Cited articles

Ayliffe, L., Cerling, T., Robinson, T., West, A., Sponheimer, M., Passey, B., Hammer, J., Roeder, B., Dearing, M., and Ehleringer, J.: Turnover of carbon isotopes in tail hair and breath CO2 of horses fed an isotopically varied diet, Oecologia, 139, 11–22, https://doi.org/10.1007/s00442-003-1479-x, 2004. 
Bony, S., Risi, C., and Vimeux, F.: Influence of convective processes on the isotopic composition (δ18O and δD) of precipitation and water vapor in the tropics: 1. Radiative-convective equilibrium and Tropical Ocean–Global Atmosphere–Coupled Ocean-Atmosphere Response Experiment (TOGA-COARE) simulations, Journal of Geophysical Research: Atmospheres, 113, https://doi.org/10.1029/2008jd009942, 2008. 
Bowen, G. J., Cai, Z., Fiorella, R. P., and Putman, A. L.: Isotopes in the Water Cycle: Regional-to Global-Scale Patterns and Applications, Annual Review of Earth and Planetary Sciences, 47, https://doi.org/10.1146/annurev-earth-053018-060220, 2019. 
Brienen, R. J., Schöngart, J., and Zuidema, P. A.: Tree rings in the tropics: insights into the ecology and climate sensitivity of tropical trees, Tropical tree physiology: adaptations and responses in a changing environment, 439–461, https://doi.org/10.1007/978-3-319-27422-5_20, 2016. 
Cerling, T. E., Wittemyer, G., Rasmussen, H. B., Vollrath, F., Cerling, C. E., Robinson, T. J., and Douglas-Hamilton, I.: Stable isotopes in elephant hair document migration patterns and diet changes, Proceedings of the National Academy of Sciences, 103, 371–373, https://doi.org/10.3410/f.1030596.358704, 2006. 
Download
Short summary
We developed and validated a model to correct for water vapor diffusion in sampling bags, enabling reconstruction of the original isotopic composition. We quantified all major sources of error and their uncertainties and introduced permeability experiments as a necessary step before field sampling. This study improves the accuracy, reliability, and standardization of atmospheric isotope observations using air bags.
Share