Articles | Volume 19, issue 16
https://doi.org/10.5194/amt-19-5491-2026
https://doi.org/10.5194/amt-19-5491-2026
Research article
 | 
26 Aug 2026
Research article |  | 26 Aug 2026

Insufficient mass spectrometric detection of synthesized peroxy acids from α-pinene ozonolysis

Markus Tischberger, Rulan Verma, Johanna Breinsperger, David Schachamayr, Marco Lair, Melanie Opacak, Peter Gärtner, Hinrich Grothe, Maximilian Kaiser, and Dominik Stolzenburg

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Short summary
We investigated how well common measurement approaches capture atmospherically relevant organic molecules formed from plant emissions. By synthesizing reference compounds and comparing different ionization methods, we show that widely used mass spectrometric techniques underestimate the abundance of important peroxide‑containing molecules. This bias influences how particle formation and growth rates are derived from measurements and affects subsequent calculations used in atmospheric science.
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