Articles | Volume 8, issue 12
https://doi.org/10.5194/amt-8-5315-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-5315-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
21 Dec 2015
Research article |
| 21 Dec 2015
An analytical system for stable isotope analysis on carbon monoxide using continuous-flow isotope-ratio mass spectrometry
S. L. Pathirana
CORRESPONDING AUTHOR
Institute for Marine and Atmospheric Research Utrecht, Utrecht University, Princetonplein 5, 3584 CC Utrecht, the Netherlands
C. van der Veen
Institute for Marine and Atmospheric Research Utrecht, Utrecht University, Princetonplein 5, 3584 CC Utrecht, the Netherlands
M. E. Popa
Institute for Marine and Atmospheric Research Utrecht, Utrecht University, Princetonplein 5, 3584 CC Utrecht, the Netherlands
T. Röckmann
Institute for Marine and Atmospheric Research Utrecht, Utrecht University, Princetonplein 5, 3584 CC Utrecht, the Netherlands
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Cited
14 citations as recorded by crossref.
- Stable carbon isotopic composition of biomass burning emissions – implications for estimating the contribution of C3 and C4 plants R. Vernooij et al. 10.5194/acp-22-2871-2022
- Observational Evidence of Large Contribution from Primary Sources for Carbon Monoxide in the South Asian Outflow S. Dasari et al. 10.1021/acs.est.1c05486
- Surprising concentrations of hydrogen and non-geological methane and carbon dioxide in the soil G. Etiope et al. 10.1016/j.scitotenv.2024.174890
- Significant role of physical transport in the marine carbon monoxide (CO) cycle: observations in the East Sea (Sea of Japan), the western North Pacific, and the Bering Sea in summer Y. Kwon et al. 10.5194/bg-21-1847-2024
- Sources and long-term variability of carbon monoxide at Mount Kenya and in Nairobi L. Kirago et al. 10.5194/acp-23-14349-2023
- Atomic spectrometry update – a review of advances in environmental analysis O. Butler et al. 10.1039/C6JA90058E
- Isotopic source signatures of stratospheric CO inferred from in situ vertical profiles J. Hooghiem et al. 10.1038/s41612-025-00986-1
- Amperometric Sensing of Carbon Monoxide: Improved Sensitivity and Selectivity via Nanostructure-Controlled Electrodeposition of Gold T. Kwon et al. 10.3390/bios11090334
- The use of δ 13C in CO to determine removal of CH4 by Cl radicals in the atmosphere * T. Röckmann et al. 10.1088/1748-9326/ad4375
- Wildfire smoke in the lower stratosphere identified by in situ CO observations J. Hooghiem et al. 10.5194/acp-20-13985-2020
- Carbon Emissions From the Edge of the Greenland Ice Sheet Reveal Subglacial Processes of Methane and Carbon Dioxide Turnover J. Christiansen et al. 10.1029/2021JG006308
- Determination of the triple oxygen and carbon isotopic composition of CO2 from atomic ion fragments formed in the ion source of the 253 Ultra high‐resolution isotope ratio mass spectrometer G. Adnew et al. 10.1002/rcm.8478
- The isotopic composition of CO in vehicle exhaust S. Naus et al. 10.1016/j.atmosenv.2018.01.015
- Vehicle emissions of greenhouse gases and related tracers from a tunnel study: CO : CO2, N2O : CO2, CH4 : CO2, O2 : CO2 ratios, and the stable isotopes 13C and 18O in CO2 and CO M. Popa et al. 10.5194/acp-14-2105-2014
12 citations as recorded by crossref.
- Stable carbon isotopic composition of biomass burning emissions – implications for estimating the contribution of C3 and C4 plants R. Vernooij et al. 10.5194/acp-22-2871-2022
- Observational Evidence of Large Contribution from Primary Sources for Carbon Monoxide in the South Asian Outflow S. Dasari et al. 10.1021/acs.est.1c05486
- Surprising concentrations of hydrogen and non-geological methane and carbon dioxide in the soil G. Etiope et al. 10.1016/j.scitotenv.2024.174890
- Significant role of physical transport in the marine carbon monoxide (CO) cycle: observations in the East Sea (Sea of Japan), the western North Pacific, and the Bering Sea in summer Y. Kwon et al. 10.5194/bg-21-1847-2024
- Sources and long-term variability of carbon monoxide at Mount Kenya and in Nairobi L. Kirago et al. 10.5194/acp-23-14349-2023
- Atomic spectrometry update – a review of advances in environmental analysis O. Butler et al. 10.1039/C6JA90058E
- Isotopic source signatures of stratospheric CO inferred from in situ vertical profiles J. Hooghiem et al. 10.1038/s41612-025-00986-1
- Amperometric Sensing of Carbon Monoxide: Improved Sensitivity and Selectivity via Nanostructure-Controlled Electrodeposition of Gold T. Kwon et al. 10.3390/bios11090334
- The use of δ 13C in CO to determine removal of CH4 by Cl radicals in the atmosphere * T. Röckmann et al. 10.1088/1748-9326/ad4375
- Wildfire smoke in the lower stratosphere identified by in situ CO observations J. Hooghiem et al. 10.5194/acp-20-13985-2020
- Carbon Emissions From the Edge of the Greenland Ice Sheet Reveal Subglacial Processes of Methane and Carbon Dioxide Turnover J. Christiansen et al. 10.1029/2021JG006308
- Determination of the triple oxygen and carbon isotopic composition of CO2 from atomic ion fragments formed in the ion source of the 253 Ultra high‐resolution isotope ratio mass spectrometer G. Adnew et al. 10.1002/rcm.8478
2 citations as recorded by crossref.
- The isotopic composition of CO in vehicle exhaust S. Naus et al. 10.1016/j.atmosenv.2018.01.015
- Vehicle emissions of greenhouse gases and related tracers from a tunnel study: CO : CO2, N2O : CO2, CH4 : CO2, O2 : CO2 ratios, and the stable isotopes 13C and 18O in CO2 and CO M. Popa et al. 10.5194/acp-14-2105-2014
Saved (preprint)
Latest update: 31 May 2025
Short summary
CO is established as an important indirect greenhouse gas, as it is the major sink for the OH∙. We have developed a fully automated system for the determination of δ13C and δ18O in atmospheric CO. The blank signal of the Schütze reagent is 1-3 % of the typical sample size. The repeatability is 0.1 ‰ for δ13C and 0.2 ‰ for δ18O. The analytical repeatability for the mole fraction is ~0.7 nmol mol-1 for 100 mL of ambient air (185.4 nmol mol-1 of CO). A single measurement is performed in 18 min.
CO is established as an important indirect greenhouse gas, as it is the major sink for the...
