Articles | Volume 9, issue 5
https://doi.org/10.5194/amt-9-2195-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-9-2195-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
18 May 2016
Research article |
| 18 May 2016
Detection and quantification of gas-phase oxidized mercury compounds by GC/MS
Colleen P. Jones
Bingham Research Center, Utah State University, Vernal, UT 84078, USA
Bingham Research Center, Utah State University, Vernal, UT 84078, USA
Daniel A. Jaffe
University of Washington-Bothell, Bothell, WA 98011, USA
Tanner Allen
Bingham Research Center, Utah State University, Vernal, UT 84078, USA
Trevor L. O'Neil
Bingham Research Center, Utah State University, Vernal, UT 84078, USA
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Cited
37 citations as recorded by crossref.
- Quantum Chemical Investigation of Snow–Mercury Interactions and Their Implication of Mercury Deposition in the Arctic E. Ali et al. 10.1021/acs.jpca.2c08551
- Improvements to the Accuracy of Atmospheric Oxidized Mercury Measurements S. Lyman et al. 10.1021/acs.est.0c02747
- Measurement of Atmospheric Mercury: Current Limitations and Suggestions for Paths Forward M. Gustin et al. 10.1021/acs.est.4c06011
- A potential route for photolytic reduction of HgCl2 and HgBr2 in dry air and analysis about the impacts from Ozone Y. Tong et al. 10.1016/j.atmosres.2020.105310
- Mercury biogeochemical cycling: A synthesis of recent scientific advances M. Gustin et al. 10.1016/j.scitotenv.2020.139619
- Colorimetric detection of Hg2+ and CH3Hg+ by a novel spirooxazine derivative as a highly sensitive and selective probe S. Pattaweepaiboon et al. 10.1016/j.dyepig.2020.108996
- A new mechanism for atmospheric mercury redox chemistry: implications for the global mercury budget H. Horowitz et al. 10.5194/acp-17-6353-2017
- Chemical cycling and deposition of atmospheric mercury in polar regions: review of recent measurements and comparison with models H. Angot et al. 10.5194/acp-16-10735-2016
- Mercury fractionation in gypsum using temperature desorption and mass spectrometric detection M. Pavlin et al. 10.1515/chem-2018-0046
- Automated Calibration of Atmospheric Oxidized Mercury Measurements S. Lyman et al. 10.1021/acs.est.6b04211
- Elemental mercury: Its unique properties affect its behavior and fate in the environment H. Gonzalez-Raymat et al. 10.1016/j.envpol.2017.04.101
- The Existence of Airborne Mercury Nanoparticles A. Ghoshdastidar & P. Ariya 10.1038/s41598-019-47086-8
- Simple approaches to on-line and off-line speciation analysis of mercury in flue gases with detection by atomic absorption spectrometry: A pilot study J. Švehla et al. 10.1016/j.sab.2019.05.002
- Calibration Sources for Gaseous Oxidized Mercury: A Review of Source Design, Performance, and Operational Parameters M. Davis & J. Lu 10.1080/10408347.2022.2131373
- A pilot study of different materials applied for active sampling of gaseous oxidized mercury in the atmospheric air A. Urba et al. 10.1016/j.apr.2017.01.012
- Atomic spectrometry update – a review of advances in environmental analysis O. Butler et al. 10.1039/C6JA90058E
- An updated review of atmospheric mercury S. Lyman et al. 10.1016/j.scitotenv.2019.135575
- WITHDRAWN: Evaluating the performance of oxidized Hg reference gas generators in the range ng m−3 to μg m−3 by improved coupling with ICP-MS P. Petrov et al. 10.1016/j.atmosenv.2020.117899
- The reaction between HgBr and O3: kinetic study and atmospheric implications J. Gómez Martín et al. 10.1039/D2CP00754A
- Uncertainty Assessment of Gaseous Oxidized Mercury Measurements Collected by Atmospheric Mercury Network I. Cheng & L. Zhang 10.1021/acs.est.6b04926
- Fractionation of mercury in aerosols of the southern Baltic coastal zone E. Korejwo et al. 10.1016/j.atmosenv.2020.117623
- Limitations and insights regarding atmospheric mercury sampling using gold J. Gačnik et al. 10.1016/j.aca.2024.342956
- Evaluating the performance of oxidized Hg reference gas generators in the range ng m−3 to μg m−3 by improved coupling with ICP-MS P. Petrov et al. 10.1016/j.aeaoa.2020.100090
- Traceable Calibration of Atmospheric Oxidized Mercury Measurements T. Elgiar et al. 10.1021/acs.est.4c02209
- Alternate materials for the capture and quantification of gaseous oxidized mercury in the atmosphere L. Lown et al. 10.5194/amt-17-6397-2024
- Comparison and calibration of methods for ambient reactive mercury quantification S. Dunham-Cheatham et al. 10.1016/j.scitotenv.2022.159219
- Development of an Understanding of Reactive Mercury in Ambient Air: A Review M. Gustin et al. 10.3390/atmos12010073
- Determining sources of reactive mercury compounds in Reno, Nevada, United States M. Gustin et al. 10.3389/fenvc.2023.1202957
- Interaction of reactive mercury with surfaces and implications for atmospheric mercury speciation measurements N. Allen et al. 10.1016/j.atmosenv.2023.120240
- A synthesis of research needs for improving the understanding of atmospheric mercury cycling L. Zhang et al. 10.5194/acp-17-9133-2017
- Exchange Reactions Alter Molecular Speciation of Gaseous Oxidized Mercury N. Mao & A. Khalizov 10.1021/acsearthspacechem.1c00178
- Evaluation of CMAQ Coupled With a State‐of‐the‐Art Mercury Chemical Mechanism (CMAQ‐newHg‐Br) Z. Ye et al. 10.1002/2017MS001161
- Improved atmospheric mercury simulation using updated gas-particle partition and organic aerosol concentrations K. Liu et al. 10.1016/j.jes.2022.04.007
- Calibration Approach for Gaseous Oxidized Mercury Based on Nonthermal Plasma Oxidation of Elemental Mercury J. Gačnik et al. 10.1021/acs.analchem.2c00260
- SERS based monitoring of toluene vapors at ambient and elevated temperatures by using a ruffled silver nanolayer as a substrate L. Ramanauskaite et al. 10.1007/s00604-018-3013-1
- Direct detection of gas-phase mercuric chloride by ion drift - Chemical ionization mass spectrometry A. Khalizov et al. 10.1016/j.atmosenv.2020.117687
- Structural, energetic and vibrational properties of oxidized mercury in the gas and aqueous phases S. Amin et al. 10.1016/j.comptc.2021.113186
37 citations as recorded by crossref.
- Quantum Chemical Investigation of Snow–Mercury Interactions and Their Implication of Mercury Deposition in the Arctic E. Ali et al. 10.1021/acs.jpca.2c08551
- Improvements to the Accuracy of Atmospheric Oxidized Mercury Measurements S. Lyman et al. 10.1021/acs.est.0c02747
- Measurement of Atmospheric Mercury: Current Limitations and Suggestions for Paths Forward M. Gustin et al. 10.1021/acs.est.4c06011
- A potential route for photolytic reduction of HgCl2 and HgBr2 in dry air and analysis about the impacts from Ozone Y. Tong et al. 10.1016/j.atmosres.2020.105310
- Mercury biogeochemical cycling: A synthesis of recent scientific advances M. Gustin et al. 10.1016/j.scitotenv.2020.139619
- Colorimetric detection of Hg2+ and CH3Hg+ by a novel spirooxazine derivative as a highly sensitive and selective probe S. Pattaweepaiboon et al. 10.1016/j.dyepig.2020.108996
- A new mechanism for atmospheric mercury redox chemistry: implications for the global mercury budget H. Horowitz et al. 10.5194/acp-17-6353-2017
- Chemical cycling and deposition of atmospheric mercury in polar regions: review of recent measurements and comparison with models H. Angot et al. 10.5194/acp-16-10735-2016
- Mercury fractionation in gypsum using temperature desorption and mass spectrometric detection M. Pavlin et al. 10.1515/chem-2018-0046
- Automated Calibration of Atmospheric Oxidized Mercury Measurements S. Lyman et al. 10.1021/acs.est.6b04211
- Elemental mercury: Its unique properties affect its behavior and fate in the environment H. Gonzalez-Raymat et al. 10.1016/j.envpol.2017.04.101
- The Existence of Airborne Mercury Nanoparticles A. Ghoshdastidar & P. Ariya 10.1038/s41598-019-47086-8
- Simple approaches to on-line and off-line speciation analysis of mercury in flue gases with detection by atomic absorption spectrometry: A pilot study J. Švehla et al. 10.1016/j.sab.2019.05.002
- Calibration Sources for Gaseous Oxidized Mercury: A Review of Source Design, Performance, and Operational Parameters M. Davis & J. Lu 10.1080/10408347.2022.2131373
- A pilot study of different materials applied for active sampling of gaseous oxidized mercury in the atmospheric air A. Urba et al. 10.1016/j.apr.2017.01.012
- Atomic spectrometry update – a review of advances in environmental analysis O. Butler et al. 10.1039/C6JA90058E
- An updated review of atmospheric mercury S. Lyman et al. 10.1016/j.scitotenv.2019.135575
- WITHDRAWN: Evaluating the performance of oxidized Hg reference gas generators in the range ng m−3 to μg m−3 by improved coupling with ICP-MS P. Petrov et al. 10.1016/j.atmosenv.2020.117899
- The reaction between HgBr and O3: kinetic study and atmospheric implications J. Gómez Martín et al. 10.1039/D2CP00754A
- Uncertainty Assessment of Gaseous Oxidized Mercury Measurements Collected by Atmospheric Mercury Network I. Cheng & L. Zhang 10.1021/acs.est.6b04926
- Fractionation of mercury in aerosols of the southern Baltic coastal zone E. Korejwo et al. 10.1016/j.atmosenv.2020.117623
- Limitations and insights regarding atmospheric mercury sampling using gold J. Gačnik et al. 10.1016/j.aca.2024.342956
- Evaluating the performance of oxidized Hg reference gas generators in the range ng m−3 to μg m−3 by improved coupling with ICP-MS P. Petrov et al. 10.1016/j.aeaoa.2020.100090
- Traceable Calibration of Atmospheric Oxidized Mercury Measurements T. Elgiar et al. 10.1021/acs.est.4c02209
- Alternate materials for the capture and quantification of gaseous oxidized mercury in the atmosphere L. Lown et al. 10.5194/amt-17-6397-2024
- Comparison and calibration of methods for ambient reactive mercury quantification S. Dunham-Cheatham et al. 10.1016/j.scitotenv.2022.159219
- Development of an Understanding of Reactive Mercury in Ambient Air: A Review M. Gustin et al. 10.3390/atmos12010073
- Determining sources of reactive mercury compounds in Reno, Nevada, United States M. Gustin et al. 10.3389/fenvc.2023.1202957
- Interaction of reactive mercury with surfaces and implications for atmospheric mercury speciation measurements N. Allen et al. 10.1016/j.atmosenv.2023.120240
- A synthesis of research needs for improving the understanding of atmospheric mercury cycling L. Zhang et al. 10.5194/acp-17-9133-2017
- Exchange Reactions Alter Molecular Speciation of Gaseous Oxidized Mercury N. Mao & A. Khalizov 10.1021/acsearthspacechem.1c00178
- Evaluation of CMAQ Coupled With a State‐of‐the‐Art Mercury Chemical Mechanism (CMAQ‐newHg‐Br) Z. Ye et al. 10.1002/2017MS001161
- Improved atmospheric mercury simulation using updated gas-particle partition and organic aerosol concentrations K. Liu et al. 10.1016/j.jes.2022.04.007
- Calibration Approach for Gaseous Oxidized Mercury Based on Nonthermal Plasma Oxidation of Elemental Mercury J. Gačnik et al. 10.1021/acs.analchem.2c00260
- SERS based monitoring of toluene vapors at ambient and elevated temperatures by using a ruffled silver nanolayer as a substrate L. Ramanauskaite et al. 10.1007/s00604-018-3013-1
- Direct detection of gas-phase mercuric chloride by ion drift - Chemical ionization mass spectrometry A. Khalizov et al. 10.1016/j.atmosenv.2020.117687
- Structural, energetic and vibrational properties of oxidized mercury in the gas and aqueous phases S. Amin et al. 10.1016/j.comptc.2021.113186
Latest update: 20 Nov 2024
Short summary
Current measurement methods do not provide information about the speciation of oxidized mercury compounds in the atmosphere, leading to uncertainty about which mercury compounds exist and how oxidized mercury is formed. We have developed a gas chromatography/mass spectrometry-based system for identification of oxidized mercury compounds. We discuss the main features and performance of this system.
Current measurement methods do not provide information about the speciation of oxidized mercury...
