Articles | Volume 14, issue 4
https://doi.org/10.5194/amt-14-2907-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-14-2907-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
A dedicated robust instrument for water vapor generation at low humidity for use with a laser water isotope analyzer in cold and dry polar regions
Christophe Leroy-Dos Santos
Laboratoire des Sciences du Climat et de l'Environnement,
CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
Mathieu Casado
Laboratoire des Sciences du Climat et de l'Environnement,
CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
Alfred Wegener Institute, Helmholtz Center for Polar and Marine
Research, Potsdam, Germany
Frédéric Prié
Laboratoire des Sciences du Climat et de l'Environnement,
CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
Olivier Jossoud
Laboratoire des Sciences du Climat et de l'Environnement,
CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
Erik Kerstel
Laboratoire Interdisciplinaire de Physique, CNRS – Université
Grenoble Alpes, Grenoble, France
Morgane Farradèche
Laboratoire des Sciences du Climat et de l'Environnement,
CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
Samir Kassi
Laboratoire Interdisciplinaire de Physique, CNRS – Université
Grenoble Alpes, Grenoble, France
Elise Fourré
Laboratoire des Sciences du Climat et de l'Environnement,
CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
Amaëlle Landais
CORRESPONDING AUTHOR
Laboratoire des Sciences du Climat et de l'Environnement,
CEA–CNRS–UVSQ–Paris-Saclay–IPSL, Gif-sur-Yvette, France
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We have monitored water vapor isotopes since January 2020 on Amsterdam Island in the Indian Ocean. We show 11 periods associated with abrupt negative excursions of water vapor δ18Ο. Six of these events show a decrease in gaseous elemental mercury, suggesting subsidence of air from a higher altitude. Accurately representing the water isotopic signal during these cold fronts is a real challenge for the atmospheric components of Earth system models equipped with water isotopes.
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In the face of global warming, understanding the changing water cycle and temperatures in polar regions is crucial. These factors directly impact the balance of ice sheets in the Arctic and Antarctic. By studying the composition of water vapor, we gain insights into climate variations. Our 2-year study at Dumont d’Urville station, Adélie Land, offers valuable data to refine models. Additionally, we demonstrate how modeling aids in interpreting signals from ice core samples in the region.
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In December 2018, an atmospheric river event from the Atlantic reached Dome C, East Antarctica, causing a +18 °C warming, tripled water vapour, and a strong isotopic anomaly in water vapour (+ 17 ‰ for δ18O) at the surface. During the peak of the event, we found 70 % of the water vapour came from local snow sublimation, and 30 % from the atmospheric river itself, highlighting both large-scale advection and local interactions at the surface.
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Studying Antarctic ice cores is crucial to assess past climate changes, as they hold historical climate data. This study examines multiple ice cores from three sites in coastal Adélie Land to see if combining cores improves data interpretability. It does at two sites, but at a third, wind-driven snow layer mixing limited benefits. We show that using multiple ice cores from one location can better uncover climate history, especially in areas with less wind disturbance.
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Geosci. Instrum. Method. Data Syst., 14, 91–101, https://doi.org/10.5194/gi-14-91-2025, https://doi.org/10.5194/gi-14-91-2025, 2025
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We present a novel 2.5-month record of the atmospheric water vapour isotopic composition during the austral summer 2023–2024 at Concordia Station on the Antarctic Plateau. We show that two independent laser spectrometers accurately record the diurnal variability of the atmospheric water vapour 𝛿18O, 𝛿D, and d-excess. We compare the measurements against outputs of the isotope-enabled general circulation model LMDZ6-iso to show how the data can be used to evaluate such models.
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Water vapour isotopes are important tools to better understand processes governing the atmospheric hydrological cycle. In polar regions, their measurement helps to improve the interpretation of water isotopic records in ice cores. However, in situ water vapour isotopic monitoring is an important challenge, especially in dry places of East Antarctica. We present here an alternative laser spectroscopy technique adapted for such measurements, with a limit of detection down to 10 ppm humidity.
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Our research compares three CFA-CRDS systems from Venice, Paris, and Grenoble for measuring water isotopes in ice cores, crucial for reconstructing past climate. We quantify each system’s mixing and measurement noise effects, which impact the achievable resolution of isotope continuous records. Our findings reveal specific configurations and procedures to enhance measurement accuracy, providing a framework to optimise water isotope analysis.
Inès Ollivier, Hans Christian Steen-Larsen, Barbara Stenni, Laurent Arnaud, Mathieu Casado, Alexandre Cauquoin, Giuliano Dreossi, Christophe Genthon, Bénédicte Minster, Ghislain Picard, Martin Werner, and Amaëlle Landais
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The role of post-depositional processes taking place at the ice sheet's surface on the water stable isotope signal measured in polar ice cores is not fully understood. Using field observations and modelling results, we show that the original precipitation isotopic signal at Dome C, East Antarctica, is modified by post-depositional processes and provide the first quantitative estimation of their mean impact on the isotopic signal observed in the snow.
Frédéric Parrenin, Marie Bouchet, Christo Buizert, Emilie Capron, Ellen Corrick, Russell Drysdale, Kenji Kawamura, Amaëlle Landais, Robert Mulvaney, Ikumi Oyabu, and Sune Olander Rasmussen
Geosci. Model Dev., 17, 8735–8750, https://doi.org/10.5194/gmd-17-8735-2024, https://doi.org/10.5194/gmd-17-8735-2024, 2024
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The Paleochrono-1.1 probabilistic dating model allows users to derive a common and optimized chronology for several paleoclimatic sites from various archives (ice cores, speleothems, marine cores, lake cores, etc.). It combines prior sedimentation scenarios with chronological information such as dated horizons, dated intervals, stratigraphic links and (for ice cores) Δdepth observations. Paleochrono-1.1 is available under an open-source license.
Clément Piel, Daniele Romanini, Morgane Farradèche, Justin Chaillot, Clémence Paul, Nicolas Bienville, Thomas Lauwers, Joana Sauze, Kévin Jaulin, Frédéric Prié, and Amaëlle Landais
Atmos. Meas. Tech., 17, 6647–6658, https://doi.org/10.5194/amt-17-6647-2024, https://doi.org/10.5194/amt-17-6647-2024, 2024
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This paper introduces a new optical gas analyzer based on an optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS) technique enabling high-temporal-resolution and high-precision measurements of oxygen isotopes (δ18O) and dioxygen (O2) concentration of atmospheric O2 (respectively 0.06 ‰ and 0.002 % over 10 min integration). The results underscore the good agreement with isotope ratio mass spectrometry measurements and the ability of the instrument to monitor biological processes.
Giuliano Dreossi, Mauro Masiol, Barbara Stenni, Daniele Zannoni, Claudio Scarchilli, Virginia Ciardini, Mathieu Casado, Amaëlle Landais, Martin Werner, Alexandre Cauquoin, Giampietro Casasanta, Massimo Del Guasta, Vittoria Posocco, and Carlo Barbante
The Cryosphere, 18, 3911–3931, https://doi.org/10.5194/tc-18-3911-2024, https://doi.org/10.5194/tc-18-3911-2024, 2024
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Oxygen and hydrogen stable isotopes have been extensively used to reconstruct past temperatures, with precipitation representing the input signal of the isotopic records in ice cores. We present a 10-year record of stable isotopes in daily precipitation at Concordia Station: this is the longest record for inland Antarctica and represents a benchmark for quantifying post-depositional processes and improving the paleoclimate interpretation of ice cores.
Romilly Harris Stuart, Amaëlle Landais, Laurent Arnaud, Christo Buizert, Emilie Capron, Marie Dumont, Quentin Libois, Robert Mulvaney, Anaïs Orsi, Ghislain Picard, Frédéric Prié, Jeffrey Severinghaus, Barbara Stenni, and Patricia Martinerie
The Cryosphere, 18, 3741–3763, https://doi.org/10.5194/tc-18-3741-2024, https://doi.org/10.5194/tc-18-3741-2024, 2024
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Ice core δO2/N2 records are useful dating tools due to their local insolation pacing. A precise understanding of the physical mechanism driving this relationship, however, remain ambiguous. By compiling data from 15 polar sites, we find a strong dependence of mean δO2/N2 on accumulation rate and temperature in addition to the well-documented insolation dependence. Snowpack modelling is used to investigate which physical properties drive the mechanistic dependence on these local parameters.
Mathieu Casado, Amaelle Landais, Tim Stoltmann, Justin Chaillot, Mathieu Daëron, Fréderic Prié, Baptiste Bordet, and Samir Kassi
Atmos. Meas. Tech., 17, 4599–4612, https://doi.org/10.5194/amt-17-4599-2024, https://doi.org/10.5194/amt-17-4599-2024, 2024
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Measuring water isotopic composition in Antarctica is difficult because of the extremely cold temperature in winter. Here, we designed a new infrared spectrometer able to measure the vapour isotopic composition during more than 95 % of the year in the coldest locations of Antarctica, whereas current commercial instruments are only able to measure during the warm summer months in the interior.
Amaelle Landais, Cécile Agosta, Françoise Vimeux, Olivier Magand, Cyrielle Solis, Alexandre Cauquoin, Niels Dutrievoz, Camille Risi, Christophe Leroy-Dos Santos, Elise Fourré, Olivier Cattani, Olivier Jossoud, Bénédicte Minster, Frédéric Prié, Mathieu Casado, Aurélien Dommergue, Yann Bertrand, and Martin Werner
Atmos. Chem. Phys., 24, 4611–4634, https://doi.org/10.5194/acp-24-4611-2024, https://doi.org/10.5194/acp-24-4611-2024, 2024
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We have monitored water vapor isotopes since January 2020 on Amsterdam Island in the Indian Ocean. We show 11 periods associated with abrupt negative excursions of water vapor δ18Ο. Six of these events show a decrease in gaseous elemental mercury, suggesting subsidence of air from a higher altitude. Accurately representing the water isotopic signal during these cold fronts is a real challenge for the atmospheric components of Earth system models equipped with water isotopes.
Andrea Spolaor, Federico Scoto, Catherine Larose, Elena Barbaro, Francois Burgay, Mats P. Bjorkman, David Cappelletti, Federico Dallo, Fabrizio de Blasi, Dmitry Divine, Giuliano Dreossi, Jacopo Gabrieli, Elisabeth Isaksson, Jack Kohler, Tonu Martma, Louise S. Schmidt, Thomas V. Schuler, Barbara Stenni, Clara Turetta, Bartłomiej Luks, Mathieu Casado, and Jean-Charles Gallet
The Cryosphere, 18, 307–320, https://doi.org/10.5194/tc-18-307-2024, https://doi.org/10.5194/tc-18-307-2024, 2024
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We evaluate the impact of the increased snowmelt on the preservation of the oxygen isotope (δ18O) signal in firn records recovered from the top of the Holtedahlfonna ice field located in the Svalbard archipelago. Thanks to a multidisciplinary approach we demonstrate a progressive deterioration of the isotope signal in the firn core. We link the degradation of the δ18O signal to the increased occurrence and intensity of melt events associated with the rapid warming occurring in the archipelago.
Christophe Leroy-Dos Santos, Elise Fourré, Cécile Agosta, Mathieu Casado, Alexandre Cauquoin, Martin Werner, Benedicte Minster, Frédéric Prié, Olivier Jossoud, Leila Petit, and Amaëlle Landais
The Cryosphere, 17, 5241–5254, https://doi.org/10.5194/tc-17-5241-2023, https://doi.org/10.5194/tc-17-5241-2023, 2023
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In the face of global warming, understanding the changing water cycle and temperatures in polar regions is crucial. These factors directly impact the balance of ice sheets in the Arctic and Antarctic. By studying the composition of water vapor, we gain insights into climate variations. Our 2-year study at Dumont d’Urville station, Adélie Land, offers valuable data to refine models. Additionally, we demonstrate how modeling aids in interpreting signals from ice core samples in the region.
Marie Bouchet, Amaëlle Landais, Antoine Grisart, Frédéric Parrenin, Frédéric Prié, Roxanne Jacob, Elise Fourré, Emilie Capron, Dominique Raynaud, Vladimir Ya Lipenkov, Marie-France Loutre, Thomas Extier, Anders Svensson, Etienne Legrain, Patricia Martinerie, Markus Leuenberger, Wei Jiang, Florian Ritterbusch, Zheng-Tian Lu, and Guo-Min Yang
Clim. Past, 19, 2257–2286, https://doi.org/10.5194/cp-19-2257-2023, https://doi.org/10.5194/cp-19-2257-2023, 2023
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A new federative chronology for five deep polar ice cores retrieves 800 000 years of past climate variations with improved accuracy. Precise ice core timescales are key to studying the mechanisms linking changes in the Earth’s orbit to the diverse climatic responses (temperature and atmospheric greenhouse gas concentrations). To construct the chronology, new measurements from the oldest continuous ice core as well as glaciological modeling estimates were combined in a statistical model.
Aymeric P. M. Servettaz, Anaïs J. Orsi, Mark A. J. Curran, Andrew D. Moy, Amaelle Landais, Joseph R. McConnell, Trevor J. Popp, Emmanuel Le Meur, Xavier Faïn, and Jérôme Chappellaz
Clim. Past, 19, 1125–1152, https://doi.org/10.5194/cp-19-1125-2023, https://doi.org/10.5194/cp-19-1125-2023, 2023
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The temperature of the past 2000 years is still poorly known in vast parts of the East Antarctic plateau. In this study, we present temperature reconstructions based on water and gas stable isotopes from the Aurora Basin North ice core. Spatial and temporal significance of each proxy differs, and we can identify some cold periods in the snow temperature up to 2°C cooler in the 1000–1400 CE period, which could not be determined with water isotopes only.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
Clim. Past, 19, 851–864, https://doi.org/10.5194/cp-19-851-2023, https://doi.org/10.5194/cp-19-851-2023, 2023
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We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
Clémence Paul, Clément Piel, Joana Sauze, Nicolas Pasquier, Frédéric Prié, Sébastien Devidal, Roxanne Jacob, Arnaud Dapoigny, Olivier Jossoud, Alexandru Milcu, and Amaëlle Landais
Biogeosciences, 20, 1047–1062, https://doi.org/10.5194/bg-20-1047-2023, https://doi.org/10.5194/bg-20-1047-2023, 2023
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To improve the interpretation of the δ18Oatm and Δ17O of O2 in air bubbles in ice cores, we need to better quantify the oxygen fractionation coefficients associated with biological processes. We performed a simplified analogue of the terrestrial biosphere in a closed chamber. We found a respiration fractionation in agreement with the previous estimates at the microorganism scale, and a terrestrial photosynthetic fractionation was found. This has an impact on the estimation of the Dole effect.
Antoine Grisart, Mathieu Casado, Vasileios Gkinis, Bo Vinther, Philippe Naveau, Mathieu Vrac, Thomas Laepple, Bénédicte Minster, Frederic Prié, Barbara Stenni, Elise Fourré, Hans Christian Steen-Larsen, Jean Jouzel, Martin Werner, Katy Pol, Valérie Masson-Delmotte, Maria Hoerhold, Trevor Popp, and Amaelle Landais
Clim. Past, 18, 2289–2301, https://doi.org/10.5194/cp-18-2289-2022, https://doi.org/10.5194/cp-18-2289-2022, 2022
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This paper presents a compilation of high-resolution (11 cm) water isotopic records, including published and new measurements, for the last 800 000 years from the EPICA Dome C ice core, Antarctica. Using this new combined water isotopes (δ18O and δD) dataset, we study the variability and possible influence of diffusion at the multi-decadal to multi-centennial scale. We observe a stronger variability at the onset of the interglacial interval corresponding to a warm period.
Clément Outrequin, Anne Alexandre, Christine Vallet-Coulomb, Clément Piel, Sébastien Devidal, Amaelle Landais, Martine Couapel, Jean-Charles Mazur, Christophe Peugeot, Monique Pierre, Frédéric Prié, Jacques Roy, Corinne Sonzogni, and Claudia Voigt
Clim. Past, 17, 1881–1902, https://doi.org/10.5194/cp-17-1881-2021, https://doi.org/10.5194/cp-17-1881-2021, 2021
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Continental atmospheric humidity is a key climate parameter poorly captured by global climate models. Model–data comparison approaches that are applicable beyond the instrumental period are essential to progress on this issue but face a lack of quantitative relative humidity proxies. Here, we calibrate the triple oxygen isotope composition of phytoliths as a new quantitative proxy of continental relative humidity suitable for past climate reconstructions.
Erik Kerstel
Atmos. Meas. Tech., 14, 4657–4667, https://doi.org/10.5194/amt-14-4657-2021, https://doi.org/10.5194/amt-14-4657-2021, 2021
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A model was developed to quantitatively describe the dynamics, in terms of vapor-phase water concentration and isotope ratios, of nanoliter-droplet evaporation at the end of a syringe needle. Such a low humidity generator can be used to calibrate laser-based water isotope analyzers, e.g., in Antarctica. We show that modeling of experimental data constrains isotope fractionation factors and the evaporation rate to physically realistic values in good agreement with available literature values.
Jinhwa Shin, Christoph Nehrbass-Ahles, Roberto Grilli, Jai Chowdhry Beeman, Frédéric Parrenin, Grégory Teste, Amaelle Landais, Loïc Schmidely, Lucas Silva, Jochen Schmitt, Bernhard Bereiter, Thomas F. Stocker, Hubertus Fischer, and Jérôme Chappellaz
Clim. Past, 16, 2203–2219, https://doi.org/10.5194/cp-16-2203-2020, https://doi.org/10.5194/cp-16-2203-2020, 2020
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We reconstruct atmospheric CO2 from the EPICA Dome C ice core during Marine Isotope Stage 6 (185–135 ka) to understand carbon mechanisms under the different boundary conditions of the climate system. The amplitude of CO2 is highly determined by the Northern Hemisphere stadial duration. Carbon dioxide maxima show different lags with respect to the corresponding abrupt CH4 jumps, the latter reflecting rapid warming in the Northern Hemisphere.
Mathieu Casado, Thomas Münch, and Thomas Laepple
Clim. Past, 16, 1581–1598, https://doi.org/10.5194/cp-16-1581-2020, https://doi.org/10.5194/cp-16-1581-2020, 2020
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The isotopic composition in ice cores from Antarctica is usually interpreted as a temperature proxy. Using a forward model, we show how different the signal in ice cores and the actual climatic signal are. Precipitation intermittency and diffusion do indeed affect the archived signal, leading to the reshuffling of the signal which limits the ability to reconstruct high-resolution climatic variations with ice cores.
Anders Svensson, Dorthe Dahl-Jensen, Jørgen Peder Steffensen, Thomas Blunier, Sune O. Rasmussen, Bo M. Vinther, Paul Vallelonga, Emilie Capron, Vasileios Gkinis, Eliza Cook, Helle Astrid Kjær, Raimund Muscheler, Sepp Kipfstuhl, Frank Wilhelms, Thomas F. Stocker, Hubertus Fischer, Florian Adolphi, Tobias Erhardt, Michael Sigl, Amaelle Landais, Frédéric Parrenin, Christo Buizert, Joseph R. McConnell, Mirko Severi, Robert Mulvaney, and Matthias Bigler
Clim. Past, 16, 1565–1580, https://doi.org/10.5194/cp-16-1565-2020, https://doi.org/10.5194/cp-16-1565-2020, 2020
Short summary
Short summary
We identify signatures of large bipolar volcanic eruptions in Greenland and Antarctic ice cores during the last glacial period, which allows for a precise temporal alignment of the ice cores. Thereby the exact timing of unexplained, abrupt climatic changes occurring during the last glacial period can be determined in a global context. The study thus provides a step towards a full understanding of elements of the climate system that may also play an important role in the future.
Cited articles
Aemisegger, F., Sturm, P., Graf, P., Sodemann, H., Pfahl, S., Knohl, A., and Wernli, H.: Measuring variations of δ18O and δ2H in atmospheric water vapour using two commercial laser-based spectrometers: an instrument characterisation study, Atmos. Meas. Tech., 5, 1491–1511, https://doi.org/10.5194/amt-5-1491-2012, 2012.
Bailey, H. L., Kaufman, D. S., Henderson, A. C. G., and Leng, M. J.: Synoptic
scale controls on the δ18O in precipitation across Beringia,
Geophys. Res. Lett., 42), 4608–4616, https://doi.org/10.1002/2015GL063983, 2015.
Bastrikov, V., Steen-Larsen, H. C., Masson-Delmotte, V., Gribanov, K., Cattani, O., Jouzel, J., and Zakharov, V.: Continuous measurements of atmospheric water vapour isotopes in western Siberia (Kourovka), Atmos. Meas. Tech., 7, 1763–1776, https://doi.org/10.5194/amt-7-1763-2014, 2014.
Bonne, J.-L., Masson-Delmotte, V., Cattani, O., Delmotte, M., Risi, C., Sodemann, H., and Steen-Larsen, H. C.: The isotopic composition of water vapour and precipitation in Ivittuut, southern Greenland, Atmos. Chem. Phys., 14, 4419–4439, https://doi.org/10.5194/acp-14-4419-2014, 2014.
Bréant, C., Leroy-Dos Santos, C., Agosta, C., Casado, M., Fourré,
E., Goursaud, S., Masson-Delmotte, V., Favier, V., Cattani, O., Prié,
F., Golly, B., Orsi, A., Martinerie, P., and Landais, A.: Coastal water vapor
isotopic composition driven by katabatic wind variability in summer at
Dumont d'Urville, coastal East Antarctica, Earth Planet. Sc. Lett., 514,
37–47, https://doi.org/10.1016/j.epsl.2019.03.004, 2019.
Casado, M.: Water stable isotopic composition on the East Antarctic Plateau: measurements at low temperature of the vapour composition, use as an atmospheric tracer and implication for paleoclimate studies (Doctoral dissertation, Université Paris Saclay; Université Versailles Saint-Quentin-En-Yvelines (UVSQ), 2016.
Casado, M., Landais, A., Masson-Delmotte, V., Genthon, C., Kerstel, E., Kassi, S., Arnaud, L., Picard, G., Prie, F., Cattani, O., Steen-Larsen, H.-C., Vignon, E., and Cermak, P.: Continuous measurements of isotopic composition of water vapour on the East Antarctic Plateau, Atmos. Chem. Phys., 16, 8521–8538, https://doi.org/10.5194/acp-16-8521-2016, 2016.
Casado, M., Landais, A., Picard, G., Münch, T., Laepple, T., Stenni, B., Dreossi, G., Ekaykin, A., Arnaud, L., Genthon, C., Touzeau, A., Masson-Delmotte, V., and Jouzel, J.: Archival processes of the water stable isotope signal in East Antarctic ice cores, The Cryosphere, 12, 1745–1766, https://doi.org/10.5194/tc-12-1745-2018, 2018.
Dong, F. and Baer, D.: Development and Deployment of a Portable Water Isotope
Analyzer for Accurate, Continuous and High-Frequency Oxygen and Hydrogen
Isotope Measurements in Water Vapor and Liquid Water, in: Geophysical
Research Abstracts, 12, EGU2010-5571, 2010.
Ellehoj, M. D., Steen-Larsen, H. C., Johnsen, S. J. and Madsen, M. B.:
Ice-vapor equilibrium fractionation factor of hydrogen and oxygen isotopes:
Experimental investigations and implications for stable water isotope
studies, Rapid Commun. Mass Sp., 27, 2149–2158,
https://doi.org/10.1002/rcm.6668, 2013.
Genthon, C., Piard, L., Vignon, E., Madeleine, J.-B., Casado, M., and Gallée, H.: Atmospheric moisture supersaturation in the near-surface atmosphere at Dome C, Antarctic Plateau, Atmos. Chem. Phys., 17, 691–704, https://doi.org/10.5194/acp-17-691-2017, 2017.
Gkinis, V., Popp, T. J., Johnsen, S. J., and Blunier, T.: A continuous stream
flash evaporator for the calibration of an IR cavity ring-down spectrometer
for the isotopic analysis of water, Isotopes Environ. Health Stud., 46,
463–475, https://doi.org/10.1080/10256016.2010.538052, 2010.
Guilpart, E., Vimeux, F., Evan, S., Brioude, J., Metzger, J., Barthe, C.,
Risi, C., and Cattani, O.: The isotopic composition of near-surface water
vapor at the Maïdo observatory (Reunion Island, southwestern Indian
Ocean) documents the controls of the humidity of the subtropical
troposphere, J. Geophys. Res.-Atmos., 122, 9628–9650,
https://doi.org/10.1002/2017JD026791, 2017.
Iannone, R., Romanini, D., Kassi, S., Meijer, H. A. J., and Kerstel, E.: A
Microdrop Generator for the Calibration of a Water Vapor Isotope Ratio
Spectrometer, J. Atmos. Ocean. Tech., 26, 1275–1288, https://doi.org/10.1175/2008JTECHA1218.1,
2009.
Jouzel, J., Masson-Delmotte, V., Cattani, O., Dreyfus, G., Falourd, S.,
Hoffmann, G., Minster, B., Nouet, J., Barnola, J. M., Chappellaz, J.,
Fischer, H., Gallet, J. C., Johnsen, S., Leuenberger, M., Loulergue, L.,
Luethi, D., Oerter, H., Parrenin, F., Raisbeck, G., Raynaud, D., Schilt, a,
Schwander, J., Selmo, E., Souchez, R., Spahni, R., Stauffer, B., Steffensen,
J. P., Stenni, B., Stocker, T. F., Tison, J. L., Werner, M., and Wolff, E.
W.: Orbital and millennial Antarctic climate variability over the past
800,000 years, Science, 317, 793–796, https://doi.org/10.1126/science.1141038,
2007.
Jossoud, O. and Leroy Dos Santos, C.: Source code for Humidity Generator's control software, available at: https://zenodo.org/record/4003465#.YGv_JT8682x (last access: 6 April 2021), 2020.
Kerstel, E.: Modeling the dynamic behavior of a droplet evaporation device for the delivery of isotopically calibrated low-humidity water vapor, Atmos. Meas. Tech. Discuss. [preprint], https://doi.org/10.5194/amt-2020-428, in review, 2020.
Kopec, B., Lauder, A., Posmentier, E., and Feng, X.: The diel cycle of water
vapor in west Greenland, J. Geophys. Res.-Atmos., 119, 9386–9399, 2014.
Landsberg, J.: Développement d'un spectromètre laser OF-CEAS pour
les mesures des isotopes de la vapeur d'eau aux concentrations de l'eau
basses, available at: https://tel.archives-ouvertes.fr/tel-01369376,
2014.
Landsberg, J., Romanini, D., and Kerstel, E.: Very high finesse
optical-feedback cavity-enhanced absorption spectrometer for low
concentration water vapor isotope analyses, Opt. Lett., 39, 1795–1798,
https://doi.org/10.1364/OL.39.001795, 2014.
Lee, X., Sargent, S., Smith, R., and Tanner, B.: In Situ Measurement of the
Water Vapor 18O/16O Isotope Ratio for Atmospheric and Ecological
Applications, J. Atmos. Ocean. Tech., 22, 555–565,
https://doi.org/10.1175/JTECH1719.1, 2005.
Ritter, F., Steen-larsen, H. C., Werner, M., Masson-Delmotte, V., Orsi, A.,
Behrens, M., Birnbaum, G., Freitag, J., Risi, C., and Kipfstuhl, S.: Isotopic
exchange on the diurnal scale between near-surface snow and lower
atmospheric water vapor at Kohnen station, East Antarctica, J. Geophys.
Res., 10, 1–35, https://doi.org/10.5194/tc-2016-4, 2016.
Sayres, D. S., Moyer, E. J., Hanisco, T. F., St. Clair, T. M., Keutsch, F. N., O'Brien, A., Allen, N. T., Lapson, Demusz, J. N., Rivero, M., Martin, T., Greenberg, M., Tuozzolo, C., Engel, G. S., Kroll, J. H., Paul, J. B., and Anderson, J. G.: A New Cavity Based Absorption Instrument for
Detection of Water Isotopologues in the Upper Troposphere and Lower
Stratosphere, Rev. Sci. Inst., 80, 44102–44114, 2009.
Schmidt, M., Maseyk, K., Lett, C., Biron, P., Richard, P., Bariac, T. and
Seibt, U.: Concentration effects on laser-based δ18O and
δ2H measurements and implications for the calibration of vapour
measurements with liquid standards, Rapid Commun. Mass Sp., 24,
3553–3561, https://doi.org/10.1002/rcm.4813, 2010.
Sodemann, H., Aemisegger, F., Pfahl, S., Bitter, M., Corsmeier, U., Feuerle, T., Graf, P., Hankers, R., Hsiao, G., Schulz, H., Wieser, A., and Wernli, H.: The stable isotopic composition of water vapour above Corsica during the HyMeX SOP1 campaign: insight into vertical mixing processes from lower-tropospheric survey flights, Atmos. Chem. Phys., 17, 6125–6151, https://doi.org/10.5194/acp-17-6125-2017, 2017.
Steen-Larsen, H. C., Masson-Delmotte, V., Hirabayashi, M., Winkler, R., Satow, K., Prié, F., Bayou, N., Brun, E., Cuffey, K. M., Dahl-Jensen, D., Dumont, M., Guillevic, M., Kipfstuhl, S., Landais, A., Popp, T., Risi, C., Steffen, K., Stenni, B., and Sveinbjörnsdottír, A. E.: What controls the isotopic composition of Greenland surface snow?, Clim. Past, 10, 377–392, https://doi.org/10.5194/cp-10-377-2014, 2014.
Sturm, P. and Knohl, A.: Water vapor δ2H and δ18O measurements using off-axis integrated cavity output spectroscopy, Atmos. Meas. Tech., 3, 67–77, https://doi.org/10.5194/amt-3-67-2010, 2010.
Tremoy, G., Vimeux, F., Cattani, O., Mayaki, S., Souley, I., and Favreau, G.:
Measurements of water vapor isotope ratios with wavelength-scanned cavity
ring-down spectroscopy technology: new insights and important caveats for
deuterium excess measurements in tropical areas in comparison with
isotope-ratio mass spectrometry, Rapid Commun. Mass Sp., 25,
3469–3480, https://doi.org/10.1002/rcm.5252, 2011.
Wang, L., Caylor, K., and Dragoni, D.: On the calibration of continuous,
high-precision δ18O and δ2H measurements using an
off-axis integrated cavity output spectrometer, Rapid Commun. Mass Sp., 23, 530–536, https://doi.org/10.1002/rcm.3905, 2009.
Weng, Y., Touzeau, A., and Sodemann, H.: Correcting the impact of the isotope composition on the mixing ratio dependency of water vapour isotope measurements with cavity ring-down spectrometers, Atmos. Meas. Tech., 13, 3167–3190, https://doi.org/10.5194/amt-13-3167-2020, 2020.
Short summary
We developed an instrument that can generate water vapor at low humidity at a very stable level. This instrument was conceived to calibrate water vapor isotopic records obtained in very dry places such as central Antarctica. Here, we provide details on the instrument as well as results obtained for correcting water isotopic records for diurnal variability during a long field season at the Concordia station in East Antarctica.
We developed an instrument that can generate water vapor at low humidity at a very stable level....