Articles | Volume 19, issue 8
https://doi.org/10.5194/amt-19-2715-2026
https://doi.org/10.5194/amt-19-2715-2026
Research article
 | 
22 Apr 2026
Research article |  | 22 Apr 2026

A novel technique for the humidity dependent calibration of hypoiodous acid (HOI) and iodine (I2)

Lewis Marden, Marvin D. Shaw, Stephen J. Andrews, Maya Zmajkovic, Phil Rund, Becky Alexander, Joel Thornton, Andrew Peters, Peter Karadakov, and Lucy J. Carpenter

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Short summary
Hypoiodous acid (HOI) and molecular iodine (I2) are the dominant precursors of reactive gaseous iodine, which plays an important role in the atmospheric oxidative capacity and in aerosol formation. However, difficulties in the quantification of HOI and I2 mean that very few measurements are available. This work describes a novel calibration method for HOI and reports the detection of HOI and I2 in the marine boundary layer using Br- chemical ionisation mass spectrometry.
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