Articles | Volume 8, issue 7
https://doi.org/10.5194/amt-8-2737-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-2737-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
08 Jul 2015
Research article |
| 08 Jul 2015
Efficient photochemical generation of peroxycarboxylic nitric anhydrides with ultraviolet light-emitting diodes
N. D. Rider
Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB T2N 1N4, Canada
Y. M. Taha
Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB T2N 1N4, Canada
C. A. Odame-Ankrah
Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB T2N 1N4, Canada
J. A. Huo
Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB T2N 1N4, Canada
T. W. Tokarek
Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB T2N 1N4, Canada
E. Cairns
Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB T2N 1N4, Canada
S. G. Moussa
Environment Canada, Air Quality Research Division, 4905 Dufferin Street, Toronto, Ontario, M3H 5T4, Canada
J. Liggio
Environment Canada, Air Quality Research Division, 4905 Dufferin Street, Toronto, Ontario, M3H 5T4, Canada
Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB T2N 1N4, Canada
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Cited
10 citations as recorded by crossref.
- Measurement of Henry’s law solubility and liquid-phase loss rate constants for acryloyl peroxynitrate (APAN) in deionized water at room temperature A. Gomez et al. https://doi.org/10.1007/s10874-025-09475-4
- On the photolysis branching ratio of methyl ethyl ketone A. Zborowska et al. https://doi.org/10.1016/j.atmosenv.2021.118383
- Furoyl peroxynitrate (fur-PAN), a product of VOC–NOxphotochemistry from biomass burning emissions: photochemical synthesis, calibration, chemical characterization, and first atmospheric observations J. Roberts et al. https://doi.org/10.1039/D2EA00068G
- Measurement of octanol–air and air–water partition coefficients of isopropyl and isobutyl nitrate A. Buss et al. https://doi.org/10.1039/D5EM00940E
- Design new cyclic imide derivatives with potential antimicrobial properties, molecular docking and toxicological studies E. Fayad et al. https://doi.org/10.1016/j.molstruc.2025.144017
- Measurement of Henry's law and liquid-phase loss rate constants of peroxypropionic nitric anhydride (PPN) in deionized water and in n-octanol K. Easterbrook et al. https://doi.org/10.5194/acp-23-311-2023
- A novel photochemical conversion technique for reliable calibration of peroxyacetyl nitrate (PAN) analyzers X. He et al. https://doi.org/10.1016/j.scitotenv.2023.162164
- Thermal decomposition of peroxyacrylic nitric anhydride (APAN) A. Gomez et al. https://doi.org/10.1039/D5EA00032G
- Leaf Stomatal Control over Acyl Peroxynitrate Dry Deposition to Trees B. Place et al. https://doi.org/10.1021/acsearthspacechem.0c00152
- Influence of ambient NO and NO2 on the quantification of total peroxy nitrates (ΣPNs) and total alkyl nitrates (ΣANs) by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) L. Wüst et al. https://doi.org/10.5194/amt-18-1943-2025
10 citations as recorded by crossref.
- Measurement of Henry’s law solubility and liquid-phase loss rate constants for acryloyl peroxynitrate (APAN) in deionized water at room temperature A. Gomez et al. https://doi.org/10.1007/s10874-025-09475-4
- On the photolysis branching ratio of methyl ethyl ketone A. Zborowska et al. https://doi.org/10.1016/j.atmosenv.2021.118383
- Furoyl peroxynitrate (fur-PAN), a product of VOC–NOxphotochemistry from biomass burning emissions: photochemical synthesis, calibration, chemical characterization, and first atmospheric observations J. Roberts et al. https://doi.org/10.1039/D2EA00068G
- Measurement of octanol–air and air–water partition coefficients of isopropyl and isobutyl nitrate A. Buss et al. https://doi.org/10.1039/D5EM00940E
- Design new cyclic imide derivatives with potential antimicrobial properties, molecular docking and toxicological studies E. Fayad et al. https://doi.org/10.1016/j.molstruc.2025.144017
- Measurement of Henry's law and liquid-phase loss rate constants of peroxypropionic nitric anhydride (PPN) in deionized water and in n-octanol K. Easterbrook et al. https://doi.org/10.5194/acp-23-311-2023
- A novel photochemical conversion technique for reliable calibration of peroxyacetyl nitrate (PAN) analyzers X. He et al. https://doi.org/10.1016/j.scitotenv.2023.162164
- Thermal decomposition of peroxyacrylic nitric anhydride (APAN) A. Gomez et al. https://doi.org/10.1039/D5EA00032G
- Leaf Stomatal Control over Acyl Peroxynitrate Dry Deposition to Trees B. Place et al. https://doi.org/10.1021/acsearthspacechem.0c00152
- Influence of ambient NO and NO2 on the quantification of total peroxy nitrates (ΣPNs) and total alkyl nitrates (ΣANs) by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) L. Wüst et al. https://doi.org/10.5194/amt-18-1943-2025
Saved (final revised paper)
Latest update: 19 Aug 2026
Short summary
A photochemical source of peroxycarboxylic nitric anhydrides (PANs) in which a dialkyl ketone (acetone, diethyl-, di-isopropyl, or di-n-propyl ketone) in the presence of oxygen and nitric oxide is photodissociated by arrays of ultraviolet light-emitting diodes (UV-LEDs) is described. The source output was analyzed by gas chromatography and thermal dissociation cavity ring-down spectroscopy and modeled using the Master Chemical Mechanism.
A photochemical source of peroxycarboxylic nitric anhydrides (PANs) in which a dialkyl ketone...
