Articles | Volume 8, issue 7
Research article
08 Jul 2015
Research article |  | 08 Jul 2015

Efficient photochemical generation of peroxycarboxylic nitric anhydrides with ultraviolet light-emitting diodes

N. D. Rider, Y. M. Taha, C. A. Odame-Ankrah, J. A. Huo, T. W. Tokarek, E. Cairns, S. G. Moussa, J. Liggio, and H. D. Osthoff

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Cited articles

Blitz, M. A., Heard, D. E., and Pilling, M. J.: OH formation from CH3CO + O2: a convenient experimental marker for the acetyl radical, Chem. Phys. Lett., 365, 374–379, , 2002.
Darley, E. F., Kettner, K. A., and Stephens, E. R.: Analysis of Peroxyacyl Nitrates by Gas Chromatography with Electron Capture Detection, Anal. Chem., 35, 589–591,, 1963.
Day, D. A., Wooldridge, P. J., Dillon, M. B., Thornton, J. A., and Cohen, R. C.: A thermal dissociation laser-induced fluorescence instrument for in situ detection of NO2, peroxy nitrates, alkyl nitrates, and HNO3, J. Geophys. Res., 107, 4046,, 2002.
Fischer, E. V., Jaffe, D. A., Reidmiller, D. R., and Jaegle, L.: Meteorological controls on observed peroxyacetyl nitrate at Mount Bachelor during the spring of 2008, J. Geophys. Res., 115, D03302,, 2010.
Flocke, F. M., Weinheimer, A. J., Swanson, A. L., Roberts, J. M., Schmitt, R., and Shertz, S.: On the measurement of PANs by gas chromatography and electron capture detection, J. Atmos. Chem., 52, 19–43,, 2005.
Short summary
A photochemical source of peroxycarboxylic nitric anhydrides (PANs) in which a dialkyl ketone (acetone, diethyl-, di-isopropyl, or di-n-propyl ketone) in the presence of oxygen and nitric oxide is photodissociated by arrays of ultraviolet light-emitting diodes (UV-LEDs) is described. The source output was analyzed by gas chromatography and thermal dissociation cavity ring-down spectroscopy and modeled using the Master Chemical Mechanism.