Articles | Volume 14, issue 1
https://doi.org/10.5194/amt-14-355-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-14-355-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 Jan 2021
Research article |
| 15 Jan 2021
| 15 Jan 2021
On the calibration of FIGAERO-ToF-CIMS: importance and impact of calibrant delivery for the particle-phase calibration
Department of Applied Physics, University of Eastern Finland, 70211 Kuopio, Finland
Luis M. F. Barreira
Department of Applied Physics, University of Eastern Finland, 70211 Kuopio, Finland
Atmospheric Composition Research, Finnish Meteorological Institute, Helsinki, Finland
Iida Pullinen
Department of Applied Physics, University of Eastern Finland, 70211 Kuopio, Finland
Angela Buchholz
Department of Applied Physics, University of Eastern Finland, 70211 Kuopio, Finland
John Jayne
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, MA, USA
Jordan E. Krechmer
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, MA, USA
Douglas R. Worsnop
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, MA, USA
Annele Virtanen
Department of Applied Physics, University of Eastern Finland, 70211 Kuopio, Finland
Siegfried Schobesberger
CORRESPONDING AUTHOR
Department of Applied Physics, University of Eastern Finland, 70211 Kuopio, Finland
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24 citations as recorded by crossref.
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- Sensitivity Constraints of Extractive Electrospray for a Model System and Secondary Organic Aerosol D. Bell et al. 10.1021/acs.analchem.3c00441
- Gas-to-Particle Partitioning of Products from Ozonolysis of Δ3-Carene and the Effect of Temperature and Relative Humidity L. Li et al. 10.1021/acs.jpca.3c07316
- Volatility Parametrization of Low-Volatile Components of Ambient Organic Aerosols Based on Molecular Formulas X. Yang et al. 10.1021/acs.est.3c02073
- Evaluation of iodide chemical ionization mass spectrometry for gas and aerosol-phase per- and polyfluoroalkyl substances (PFAS) analysis B. Bowers et al. 10.1039/D2EM00275B
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- Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol M. Yao et al. 10.1021/acs.est.2c01297
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
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- Volatility Measurements of Oxygenated Volatile Organics from Fresh and Aged Residential Wood Burning Emissions M. Priestley et al. 10.1021/acsearthspacechem.3c00066
- Comparison of saturation vapor pressures of <i>α</i>-pinene + O<sub>3</sub> oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al. 10.5194/acp-22-1195-2022
- Precursors and Pathways Leading to Enhanced Secondary Organic Aerosol Formation during Severe Haze Episodes Y. Zheng et al. 10.1021/acs.est.1c04255
- Tutorial: Dynamic organic growth modeling with a volatility basis set D. Stolzenburg et al. 10.1016/j.jaerosci.2022.106063
- Atmospheric nanoparticle growth D. Stolzenburg et al. 10.1103/RevModPhys.95.045002
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Saturation vapor pressure characterization of selected low-volatility organic compounds using a residence time chamber Z. Li et al. 10.5194/acp-23-6863-2023
- Evolution of volatility and composition in sesquiterpene-mixed and <i>α</i>-pinene secondary organic aerosol particles during isothermal evaporation Z. Li et al. 10.5194/acp-21-18283-2021
24 citations as recorded by crossref.
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al. 10.1038/s41467-022-35546-1
- Volatility parameterization of ambient organic aerosols at a rural site of the North China Plain S. Ren et al. 10.5194/acp-22-9283-2022
- Sensitivity Constraints of Extractive Electrospray for a Model System and Secondary Organic Aerosol D. Bell et al. 10.1021/acs.analchem.3c00441
- Gas-to-Particle Partitioning of Products from Ozonolysis of Δ3-Carene and the Effect of Temperature and Relative Humidity L. Li et al. 10.1021/acs.jpca.3c07316
- Volatility Parametrization of Low-Volatile Components of Ambient Organic Aerosols Based on Molecular Formulas X. Yang et al. 10.1021/acs.est.3c02073
- Evaluation of iodide chemical ionization mass spectrometry for gas and aerosol-phase per- and polyfluoroalkyl substances (PFAS) analysis B. Bowers et al. 10.1039/D2EM00275B
- Synergetic Effects of Isoprene and HOx on Biogenic New Particle Formation L. Tiszenkel & S. Lee 10.1029/2023GL103545
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol M. Yao et al. 10.1021/acs.est.2c01297
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Characterization of offline analysis of particulate matter with FIGAERO-CIMS J. Cai et al. 10.5194/amt-16-1147-2023
- Volatility Measurements of Oxygenated Volatile Organics from Fresh and Aged Residential Wood Burning Emissions M. Priestley et al. 10.1021/acsearthspacechem.3c00066
- Comparison of saturation vapor pressures of <i>α</i>-pinene + O<sub>3</sub> oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al. 10.5194/acp-22-1195-2022
- Precursors and Pathways Leading to Enhanced Secondary Organic Aerosol Formation during Severe Haze Episodes Y. Zheng et al. 10.1021/acs.est.1c04255
- Tutorial: Dynamic organic growth modeling with a volatility basis set D. Stolzenburg et al. 10.1016/j.jaerosci.2022.106063
- Atmospheric nanoparticle growth D. Stolzenburg et al. 10.1103/RevModPhys.95.045002
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Saturation vapor pressure characterization of selected low-volatility organic compounds using a residence time chamber Z. Li et al. 10.5194/acp-23-6863-2023
- Evolution of volatility and composition in sesquiterpene-mixed and <i>α</i>-pinene secondary organic aerosol particles during isothermal evaporation Z. Li et al. 10.5194/acp-21-18283-2021
Latest update: 19 Apr 2024
Short summary
FIGAERO-ToF-CIMS enables online volatility measurements of chemical compounds in ambient aerosols. Previously published volatility calibration results however differ from each other significantly. In this study we investigate the reason for this discrepancy. We found a major source of error in the widely used syringe deposition method and propose a new method for volatility calibration by using atomized calibration compounds.
FIGAERO-ToF-CIMS enables online volatility measurements of chemical compounds in ambient...
