Articles | Volume 14, issue 1
https://doi.org/10.5194/amt-14-355-2021
https://doi.org/10.5194/amt-14-355-2021
Research article
 | 
15 Jan 2021
Research article |  | 15 Jan 2021

On the calibration of FIGAERO-ToF-CIMS: importance and impact of calibrant delivery for the particle-phase calibration

Arttu Ylisirniö, Luis M. F. Barreira, Iida Pullinen, Angela Buchholz, John Jayne, Jordan E. Krechmer, Douglas R. Worsnop, Annele Virtanen, and Siegfried Schobesberger

Related authors

The saturation vapor pressures of higher-order polyethylene glycols and achieving a wide calibration range for volatility measurements by FIGAERO-CIMS
Arttu Ylisirniö, Noora Hyttinen, Zijun Li, Mitchell Alton, Aki Nissinen, Iida Pullinen, Pasi Miettinen, Taina Yli-Juuti, and Siegfried Schobesberger
EGUsphere, https://doi.org/10.5194/egusphere-2025-2219,https://doi.org/10.5194/egusphere-2025-2219, 2025
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
Short summary
Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions
Zijun Li, Angela Buchholz, Luis M. F. Barreira, Arttu Ylisirniö, Liqing Hao, Iida Pullinen, Siegfried Schobesberger, and Annele Virtanen
Atmos. Chem. Phys., 23, 203–220, https://doi.org/10.5194/acp-23-203-2023,https://doi.org/10.5194/acp-23-203-2023, 2023
Short summary
Evolution of volatility and composition in sesquiterpene-mixed and α-pinene secondary organic aerosol particles during isothermal evaporation
Zijun Li, Angela Buchholz, Arttu Ylisirniö, Luis Barreira, Liqing Hao, Siegfried Schobesberger, Taina Yli-Juuti, and Annele Virtanen
Atmos. Chem. Phys., 21, 18283–18302, https://doi.org/10.5194/acp-21-18283-2021,https://doi.org/10.5194/acp-21-18283-2021, 2021
Short summary
The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest
Luis M. F. Barreira, Arttu Ylisirniö, Iida Pullinen, Angela Buchholz, Zijun Li, Helina Lipp, Heikki Junninen, Urmas Hõrrak, Steffen M. Noe, Alisa Krasnova, Dmitrii Krasnov, Kaia Kask, Eero Talts, Ülo Niinemets, Jose Ruiz-Jimenez, and Siegfried Schobesberger
Atmos. Chem. Phys., 21, 11781–11800, https://doi.org/10.5194/acp-21-11781-2021,https://doi.org/10.5194/acp-21-11781-2021, 2021
Short summary
Comparing secondary organic aerosol (SOA) volatility distributions derived from isothermal SOA particle evaporation data and FIGAERO–CIMS measurements
Olli-Pekka Tikkanen, Angela Buchholz, Arttu Ylisirniö, Siegfried Schobesberger, Annele Virtanen, and Taina Yli-Juuti
Atmos. Chem. Phys., 20, 10441–10458, https://doi.org/10.5194/acp-20-10441-2020,https://doi.org/10.5194/acp-20-10441-2020, 2020
Short summary

Related subject area

Subject: Aerosols | Technique: Laboratory Measurement | Topic: Instruments and Platforms
Design of a wide-particle-size-range aerodynamic injection system with a new pre-focus structure
Junhong Huang, Lei Li, Xue Li, Zhengxu Huang, and Zhi Cheng
Atmos. Meas. Tech., 18, 2739–2749, https://doi.org/10.5194/amt-18-2739-2025,https://doi.org/10.5194/amt-18-2739-2025, 2025
Short summary
A comprehensive characterization of empirical parameterizations for OH exposure in the Aerodyne Potential Aerosol Mass Oxidation Flow Reactor (PAM-OFR)
Qianying Liu, Dan Dan Huang, Andrew T. Lambe, Shengrong Lou, Lulu Zeng, Yuhang Wu, Congyan Huang, Shikang Tao, Xi Cheng, Qi Chen, Ka In Hoi, Hongli Wang, Kai Meng Mok, Cheng Huang, and Yong Jie Li
Atmos. Meas. Tech., 18, 2509–2521, https://doi.org/10.5194/amt-18-2509-2025,https://doi.org/10.5194/amt-18-2509-2025, 2025
Short summary
The UNAM-MARine Aerosol Tank (UNAM-MARAT): an evaluation of the ice-nucleating abilities of seawater from the Gulf of Mexico and the Mexican Pacific
M. Fernanda Córdoba, Rachel Chang, Harry Alvarez-Ospina, Aramis Olivos-Ortiz, Graciela B. Raga, Daniel Rosas-Ramírez, Guadalupe Campos, Isabel Márquez, Telma Castro, and Luis A. Ladino
Atmos. Meas. Tech., 18, 2463–2479, https://doi.org/10.5194/amt-18-2463-2025,https://doi.org/10.5194/amt-18-2463-2025, 2025
Short summary
Characterization of the Newly Designed Wall-Free Particle Evaporator (WALL-E) for Online Measurements of Atmospheric Particles
Linyu Gao, Imad Zgheib, Evangelos Stergiou, Cecilie Carstens, Félix Sari Doré, Michel Dupanloup, Frederic Bourgain, Sebastien Perrier, and Matthieu Riva
EGUsphere, https://doi.org/10.5194/egusphere-2025-1072,https://doi.org/10.5194/egusphere-2025-1072, 2025
Short summary
Determining optimal sampling conditions in the TSI Nanometer Aerosol Sampler 3089
Behnaz Alinaghipour, Sadegh Niazi, Robert Groth, Branka Miljevic, and Zoran Ristovski
Atmos. Meas. Tech., 18, 1063–1071, https://doi.org/10.5194/amt-18-1063-2025,https://doi.org/10.5194/amt-18-1063-2025, 2025
Short summary

Cited articles

Bannan, T. J., Le Breton, M., Priestley, M., Worrall, S. D., Bacak, A., Marsden, N. A., Mehra, A., Hammes, J., Hallquist, M., Alfarra, M. R., Krieger, U. K., Reid, J. P., Jayne, J., Robinson, W., McFiggans, G., Coe, H., Percival, C. J., and Topping, D.: A method for extracting calibrated volatility information from the FIGAERO-HR-ToF-CIMS and its experimental application, Atmos. Meas. Tech., 12, 1429–1439, https://doi.org/10.5194/amt-12-1429-2019, 2019. 
Cappa, C. D., Lovejoy, E. R., and Ravishankara, A. R.: Determination of evaporation rates and vapor pressures of very low volatility compounds: A study of the C4C10 and C12 dicarboxylic acids, J. Phys. Chem. A, 111, 3099–3109, https://doi.org/10.1021/jp068686q, 2007. 
D'Ambro, E. L., Lee, B. H., Liu, J., Shilling, J. E., Gaston, C. J., Lopez-Hilfiker, F. D., Schobesberger, S., Zaveri, R. A., Mohr, C., Lutz, A., Zhang, Z., Gold, A., Surratt, J. D., Rivera-Rios, J. C., Keutsch, F. N., and Thornton, J. A.: Molecular composition and volatility of isoprene photochemical oxidation secondary organic aerosol under low- and high-NOx conditions, Atmos. Chem. Phys., 17, 159–174, https://doi.org/10.5194/acp-17-159-2017, 2017. 
Donahue, N. M., Kroll, J. H., Pandis, S. N., and Robinson, A. L.: A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution, Atmos. Chem. Phys., 12, 615–634, https://doi.org/10.5194/acp-12-615-2012, 2012. 
Eichler, P., Müller, M., D'Anna, B., and Wisthaler, A.: A novel inlet system for online chemical analysis of semi-volatile submicron particulate matter, Atmos. Meas. Tech., 8, 1353–1360, https://doi.org/10.5194/amt-8-1353-2015, 2015. 
Download
Short summary
FIGAERO-ToF-CIMS enables online volatility measurements of chemical compounds in ambient aerosols. Previously published volatility calibration results however differ from each other significantly. In this study we investigate the reason for this discrepancy. We found a major source of error in the widely used syringe deposition method and propose a new method for volatility calibration by using atomized calibration compounds.
Share