Articles | Volume 19, issue 9
https://doi.org/10.5194/amt-19-3063-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/amt-19-3063-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Ground-based monitoring of nitrogen dioxide in Kumasi, Ghana, and its comparison with satellite observations
Royal Netherlands Meteorological Institute (KNMI), De Bilt, 3730 AE, the Netherlands
Benjamin Afotey
Department of Chemical Engineering, Kwame Nkrumah University of Science and Technology (KNUST), Kumasi, 00233, Ghana
Tim Henrik Eckert
Delft University of Technology (TU Delft), Delft, 2600 GA, the Netherlands
Magdalena Mairhofer
Delft University of Technology (TU Delft), Delft, 2600 GA, the Netherlands
Águeda Gil Pascual
Delft University of Technology (TU Delft), Delft, 2600 GA, the Netherlands
Emmanuel Yuorkuu
Department of Chemical Engineering, Kwame Nkrumah University of Science and Technology (KNUST), Kumasi, 00233, Ghana
Philip Darko
Department of Chemical Engineering, Kwame Nkrumah University of Science and Technology (KNUST), Kumasi, 00233, Ghana
Phiona Amakah
Department of Chemical Engineering, Kwame Nkrumah University of Science and Technology (KNUST), Kumasi, 00233, Ghana
Klaas Folkert Boersma
Royal Netherlands Meteorological Institute (KNMI), De Bilt, 3730 AE, the Netherlands
Wageningen University, Meteorology and Air Quality Group, Wageningen, 6700 AA, the Netherlands
Prince Junior Asilevi
Department of Meteorology and Climate Science, Kwame Nkrumah University of Science and Technology (KNUST), Kumasi, 00233, Ghana
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Alba Mols, Klaas Folkert Boersma, Hugo Denier van der Gon, and Maarten Krol
Atmos. Chem. Phys., 26, 1497–1513, https://doi.org/10.5194/acp-26-1497-2026, https://doi.org/10.5194/acp-26-1497-2026, 2026
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Juliëtte C. S. Anema, K. Folkert Boersma, Lieuwe G. Tilstra, Ruben van't Loo, and Olaf N. E. Tuinder
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-561, https://doi.org/10.5194/essd-2025-561, 2025
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The GOME-2 series offers a long solar-induced fluorescence (SIF) record, but sensor-specific instrumental artefacts diverge intersensor observations. We developed a combined GOME-2 SIF record (2007–2023) from GOME-2A and GOME-2B SIF using the SIFTER v3 algorithm, which corrects these artefacts. Both records show strong spatial and temporal coherence. A framework is provided to detect and, if needed, correct intersensor offsets, supporting consistent long-term monitoring of vegetation dynamics.
Bas Mijling, Henk Eskes, Sascha Hofmann, Pau Moreno, David García Falin, and María Encarnación de Vega Pastor
Geosci. Model Dev., 18, 6439–6460, https://doi.org/10.5194/gmd-18-6439-2025, https://doi.org/10.5194/gmd-18-6439-2025, 2025
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Isolde Glissenaar, Klaas Folkert Boersma, Isidora Anglou, Pieter Rijsdijk, Tijl Verhoelst, Steven Compernolle, Gaia Pinardi, Jean-Christopher Lambert, Michel Van Roozendael, and Henk Eskes
Earth Syst. Sci. Data, 17, 4627–4650, https://doi.org/10.5194/essd-17-4627-2025, https://doi.org/10.5194/essd-17-4627-2025, 2025
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We developed a new global dataset of nitrogen dioxide (NO2) levels in the lower atmosphere, using data from TROPOMI for 2018–2021. This dataset offers improved accuracy and detail compared to earlier versions, meeting high international standards for climate data. By refining how measurement errors are calculated and reduced over time and space, we provide clearer insights into pollution patterns. This work supports better air quality monitoring and informs actions to address pollution globally.
Suvarna Fadnavis, Yasin Elshorbany, Jerald Ziemke, Brice Barret, Alexandru Rap, P. R. Satheesh Chandran, Richard J. Pope, Vijay Sagar, Domenico Taraborrelli, Eric Le Flochmoen, Juan Cuesta, Catherine Wespes, Folkert Boersma, Isolde Glissenaar, Isabelle De Smedt, Michel Van Roozendael, Hervé Petetin, and Isidora Anglou
Atmos. Chem. Phys., 25, 8229–8254, https://doi.org/10.5194/acp-25-8229-2025, https://doi.org/10.5194/acp-25-8229-2025, 2025
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Satellites and model simulations show enhancement in tropospheric ozone, which is highly impacted by human-produced nitrous oxides compared to volatile organic compounds. The increased amount of ozone enhances ozone radiative forcing. The ozone enhancement and associated radiative forcing are the highest over South and East Asia. The emissions of nitrous oxides show a higher influence on shifting ozone photochemical regimes than volatile organic compounds.
Juliëtte C. S. Anema, K. Folkert Boersma, Lieuwe G. Tilstra, Olaf N. E. Tuinder, and Willem W. Verstraeten
Atmos. Meas. Tech., 18, 1961–1979, https://doi.org/10.5194/amt-18-1961-2025, https://doi.org/10.5194/amt-18-1961-2025, 2025
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Long-term records of plant fluorescence offer vital insights into changing vegetation activity. The GOME-2A sensor provides extensive global observations but suffers from calibration and instrument degradation, which affects data consistency. This study presents the SIFTER v3 algorithm, which effectively resolves these issues and includes other improvements, resulting in robust, accurate, and consistent GOME-2A fluorescence measurements from 2007 to 2017.
Qianqian Zhang, K. Folkert Boersma, Chiel van der Laan, Alba Mols, Bin Zhao, Shengyue Li, and Yuepeng Pan
Atmos. Chem. Phys., 25, 3313–3326, https://doi.org/10.5194/acp-25-3313-2025, https://doi.org/10.5194/acp-25-3313-2025, 2025
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Accurate NOx emission estimates are required to better understand air pollution. This study investigates and demonstrates the ability of the superposition column model in combination with TROPOMI tropospheric NO2 column data to estimate city-scale NOx emissions and lifetimes and their variabilities. The results of this work nevertheless confirm the strength of the superposition column model in estimating urban NOx emissions with reasonable accuracy.
Felipe Cifuentes, Henk Eskes, Enrico Dammers, Charlotte Bryan, and Folkert Boersma
Geosci. Model Dev., 18, 621–649, https://doi.org/10.5194/gmd-18-621-2025, https://doi.org/10.5194/gmd-18-621-2025, 2025
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We tested the capability of the flux divergence approach (FDA) to reproduce known NOx emissions using synthetic NO2 satellite column retrievals from high-resolution model simulations. The FDA accurately reproduced NOx emissions when column observations were limited to the boundary layer and when the variability of the NO2 lifetime, the NOx : NO2 ratio, and NO2 profile shapes were correctly modeled. This introduces strong model dependency, reducing the simplicity of the original FDA formulation.
Pieter Rijsdijk, Henk Eskes, Arlene Dingemans, K. Folkert Boersma, Takashi Sekiya, Kazuyuki Miyazaki, and Sander Houweling
Geosci. Model Dev., 18, 483–509, https://doi.org/10.5194/gmd-18-483-2025, https://doi.org/10.5194/gmd-18-483-2025, 2025
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Clustering high-resolution satellite observations into superobservations improves model validation and data assimilation applications. In our paper, we derive quantitative uncertainties for satellite NO2 column observations based on knowledge of the retrievals, including a detailed analysis of spatial error correlations and representativity errors. The superobservations and uncertainty estimates are tested in a global chemical data assimilation system and are found to improve the forecasts.
Tong Sha, Siyu Yang, Qingcai Chen, Liangqing Li, Xiaoyan Ma, Yan-Lin Zhang, Zhaozhong Feng, K. Folkert Boersma, and Jun Wang
Atmos. Chem. Phys., 24, 8441–8455, https://doi.org/10.5194/acp-24-8441-2024, https://doi.org/10.5194/acp-24-8441-2024, 2024
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Using an updated soil reactive nitrogen emission scheme in the Unified Inputs for Weather Research and Forecasting coupled with Chemistry (UI-WRF-Chem) model, we investigate the role of soil NO and HONO (Nr) emissions in air quality and temperature in North China. Contributions of soil Nr emissions to O3 and secondary pollutants are revealed, exceeding effects of soil NOx or HONO emission. Soil Nr emissions play an important role in mitigating O3 pollution and addressing climate change.
Maarten Krol, Bart van Stratum, Isidora Anglou, and Klaas Folkert Boersma
Atmos. Chem. Phys., 24, 8243–8262, https://doi.org/10.5194/acp-24-8243-2024, https://doi.org/10.5194/acp-24-8243-2024, 2024
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This paper presents detailed plume simulations of nitrogen oxides and carbon dioxide that are emitted from four large industrial facilities world-wide. Results from the high-resolution simulations that include atmospheric chemistry are compared to nitrogen dioxide observations from satellites. We find good performance of the model and show that common assumptions that are used in simplified models need revision. This work is important for the monitoring of emissions using satellite data.
Juliëtte C. S. Anema, Klaas Folkert Boersma, Piet Stammes, Gerbrand Koren, William Woodgate, Philipp Köhler, Christian Frankenberg, and Jacqui Stol
Biogeosciences, 21, 2297–2311, https://doi.org/10.5194/bg-21-2297-2024, https://doi.org/10.5194/bg-21-2297-2024, 2024
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To keep the Paris agreement goals within reach, negative emissions are necessary. They can be achieved with mitigation techniques, such as reforestation, which remove CO2 from the atmosphere. While governments have pinned their hopes on them, there is not yet a good set of tools to objectively determine whether negative emissions do what they promise. Here we show how satellite measurements of plant fluorescence are useful in detecting carbon uptake due to reforestation and vegetation regrowth.
Tobias Christoph Valentin Werner Riess, Klaas Folkert Boersma, Ward Van Roy, Jos de Laat, Enrico Dammers, and Jasper van Vliet
Atmos. Meas. Tech., 16, 5287–5304, https://doi.org/10.5194/amt-16-5287-2023, https://doi.org/10.5194/amt-16-5287-2023, 2023
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Satellite retrievals of trace gases require prior knowledge of the vertical distribution of the pollutant, which is usually obtained from models. Using aircraft-measured vertical NO2 profiles over the North Sea in summer 2021, we evaluate the Transport Model 5 profiles used in the TROPOMI NO2 retrieval. We conclude that driven by the low horizontal resolution and the overestimated vertical mixing, resulting NO2 columns are 20 % too low. This has important implications for emission estimates.
John Douros, Henk Eskes, Jos van Geffen, K. Folkert Boersma, Steven Compernolle, Gaia Pinardi, Anne-Marlene Blechschmidt, Vincent-Henri Peuch, Augustin Colette, and Pepijn Veefkind
Geosci. Model Dev., 16, 509–534, https://doi.org/10.5194/gmd-16-509-2023, https://doi.org/10.5194/gmd-16-509-2023, 2023
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We focus on the challenges associated with comparing atmospheric composition models with satellite products such as tropospheric NO2 columns. The aim is to highlight the methodological difficulties and propose sound ways of doing such comparisons. Building on the comparisons, a new satellite product is proposed and made available, which takes advantage of higher-resolution, regional atmospheric modelling to improve estimates of troposheric NO2 columns over Europe.
Viral Shah, Daniel J. Jacob, Ruijun Dang, Lok N. Lamsal, Sarah A. Strode, Stephen D. Steenrod, K. Folkert Boersma, Sebastian D. Eastham, Thibaud M. Fritz, Chelsea Thompson, Jeff Peischl, Ilann Bourgeois, Ilana B. Pollack, Benjamin A. Nault, Ronald C. Cohen, Pedro Campuzano-Jost, Jose L. Jimenez, Simone T. Andersen, Lucy J. Carpenter, Tomás Sherwen, and Mat J. Evans
Atmos. Chem. Phys., 23, 1227–1257, https://doi.org/10.5194/acp-23-1227-2023, https://doi.org/10.5194/acp-23-1227-2023, 2023
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NOx in the free troposphere (above 2 km) affects global tropospheric chemistry and the retrieval and interpretation of satellite NO2 measurements. We evaluate free tropospheric NOx in global atmospheric chemistry models and find that recycling NOx from its reservoirs over the oceans is faster than that simulated in the models, resulting in increases in simulated tropospheric ozone and OH. Over the U.S., free tropospheric NO2 contributes the majority of the tropospheric NO2 column in summer.
Qianqian Zhang, K. Folkert Boersma, Bin Zhao, Henk Eskes, Cuihong Chen, Haotian Zheng, and Xingying Zhang
Atmos. Chem. Phys., 23, 551–563, https://doi.org/10.5194/acp-23-551-2023, https://doi.org/10.5194/acp-23-551-2023, 2023
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We developed an improved superposition column model and used the latest released (v2.3.1) TROPOMI satellite NO2 observations to estimate daily city-scale NOx and CO2 emissions. The results are verified against bottom-up emissions and OCO-2 XCO2 observations. We obtained the day-to-day variation of city NOx and CO2 emissions, allowing policymakers to gain real-time information on spatial–temporal emission patterns and the effectiveness of carbon and nitrogen regulation in urban environments.
Srijana Lama, Sander Houweling, K. Folkert Boersma, Ilse Aben, Hugo A. C. Denier van der Gon, and Maarten C. Krol
Atmos. Chem. Phys., 22, 16053–16071, https://doi.org/10.5194/acp-22-16053-2022, https://doi.org/10.5194/acp-22-16053-2022, 2022
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Jos van Geffen, Henk Eskes, Steven Compernolle, Gaia Pinardi, Tijl Verhoelst, Jean-Christopher Lambert, Maarten Sneep, Mark ter Linden, Antje Ludewig, K. Folkert Boersma, and J. Pepijn Veefkind
Atmos. Meas. Tech., 15, 2037–2060, https://doi.org/10.5194/amt-15-2037-2022, https://doi.org/10.5194/amt-15-2037-2022, 2022
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Nitrogen dioxide (NO2) is one of the main data products measured by the Tropospheric Monitoring Instrument (TROPOMI) on the Sentinel-5 Precursor (S5P) satellite. This study describes improvements in the TROPOMI NO2 retrieval leading to version v2.2, operational since 1 July 2021. It compares results with previous versions v1.2–v1.4 and with Ozone Monitoring Instrument (OMI) and ground-based measurements.
Tobias Christoph Valentin Werner Riess, Klaas Folkert Boersma, Jasper van Vliet, Wouter Peters, Maarten Sneep, Henk Eskes, and Jos van Geffen
Atmos. Meas. Tech., 15, 1415–1438, https://doi.org/10.5194/amt-15-1415-2022, https://doi.org/10.5194/amt-15-1415-2022, 2022
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This paper reports on improved monitoring of ship nitrogen oxide emissions by TROPOMI. With its fantastic resolution we can identify lanes of ship nitrogen dioxide (NO2) pollution not detected from space before. The quality of TROPOMI NO2 data over sea is improved further by recent upgrades in cloud retrievals and the use of sun glint scenes. Lastly, we study the impact of COVID-19 on ship NO2 in European seas and compare the found reductions to emission estimates gained from ship-specific data.
Auke J. Visser, Laurens N. Ganzeveld, Ignacio Goded, Maarten C. Krol, Ivan Mammarella, Giovanni Manca, and K. Folkert Boersma
Atmos. Chem. Phys., 21, 18393–18411, https://doi.org/10.5194/acp-21-18393-2021, https://doi.org/10.5194/acp-21-18393-2021, 2021
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Dry deposition is an important sink for tropospheric ozone that affects ecosystem carbon uptake, but process understanding remains incomplete. We apply a common deposition representation in atmospheric chemistry models and a multi-layer canopy model to multi-year ozone deposition observations. The multi-layer canopy model performs better on diurnal timescales compared to the common approach, leading to a substantially improved simulation of ozone deposition and vegetation ozone impact metrics.
Isabelle De Smedt, Gaia Pinardi, Corinne Vigouroux, Steven Compernolle, Alkis Bais, Nuria Benavent, Folkert Boersma, Ka-Lok Chan, Sebastian Donner, Kai-Uwe Eichmann, Pascal Hedelt, François Hendrick, Hitoshi Irie, Vinod Kumar, Jean-Christopher Lambert, Bavo Langerock, Christophe Lerot, Cheng Liu, Diego Loyola, Ankie Piters, Andreas Richter, Claudia Rivera Cárdenas, Fabian Romahn, Robert George Ryan, Vinayak Sinha, Nicolas Theys, Jonas Vlietinck, Thomas Wagner, Ting Wang, Huan Yu, and Michel Van Roozendael
Atmos. Chem. Phys., 21, 12561–12593, https://doi.org/10.5194/acp-21-12561-2021, https://doi.org/10.5194/acp-21-12561-2021, 2021
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This paper assess the performances of the TROPOMI formaldehyde observations compared to its predecessor OMI at different spatial and temporal scales. We also use a global network of MAX-DOAS instruments to validate both satellite datasets for a large range of HCHO columns. The precision obtained with daily TROPOMI observations is comparable to monthly OMI observations. We present clear detection of weak HCHO column enhancements related to shipping emissions in the Indian Ocean.
Jianfeng Li, Yuhang Wang, Ruixiong Zhang, Charles Smeltzer, Andrew Weinheimer, Jay Herman, K. Folkert Boersma, Edward A. Celarier, Russell W. Long, James J. Szykman, Ruben Delgado, Anne M. Thompson, Travis N. Knepp, Lok N. Lamsal, Scott J. Janz, Matthew G. Kowalewski, Xiong Liu, and Caroline R. Nowlan
Atmos. Chem. Phys., 21, 11133–11160, https://doi.org/10.5194/acp-21-11133-2021, https://doi.org/10.5194/acp-21-11133-2021, 2021
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Comprehensive evaluations of simulated diurnal cycles of NO2 and NOy concentrations, vertical profiles, and tropospheric vertical column densities at two different resolutions with various measurements during the DISCOVER-AQ 2011 campaign show potential distribution biases of NOx emissions in the National Emissions Inventory 2011 at both 36 and 4 km resolutions, providing another possible explanation for the overestimation of model results.
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Short summary
We established the first Palmes tube laboratory in Sub-Saharan Africa to monitor urban nitrogen dioxide (NO2) in Kumasi, Ghana. Our measurements reveal high surface NO2 levels that satellites underestimate, showing the importance of local measurements. This low-cost, scalable approach provides continuous local data and improves the interpretation of satellite observations, helping policymakers better understand and manage air quality in tropical cities.
We established the first Palmes tube laboratory in Sub-Saharan Africa to monitor urban nitrogen...